Modification of thermoplastic vulcanizates using random propylene copolymers

    公开(公告)号:US06288171B1

    公开(公告)日:2001-09-11

    申请号:US09108492

    申请日:1998-07-01

    IPC分类号: C08J324

    摘要: Random propylene thermoplastic copolymers can be used to increase the elongation to break and toughness of thermoplastic vulcanizates. Semi-crystalline polypropylene is a preferred thermoplastic phase. The rubber can be olefinic rubbers. Random thermoplastic polypropylene copolymers are different from conventional Ziegler-Natta propylene copolymers as the compositional heterogeneity of the copolymer is greater with Ziegler-Natta copolymers. This difference results in substantial differences in properties (elongation to break and toughness) between thermoplastic vulcanizates modified with random thermoplastic propylene copolymers and those modified with conventional Ziegler-Natta propylene copolymers. An increase in elongation to break results in greater extensibility in the articles made from a thermoplastic vulcanizate.

    Use of a silane grafted polyolefin in EPDM/polyolefin thermoplastic vulcanizates to improve compression set
    14.
    发明授权
    Use of a silane grafted polyolefin in EPDM/polyolefin thermoplastic vulcanizates to improve compression set 有权
    在EPDM /聚烯烃热塑性硫化胶中使用硅烷接枝聚烯烃,以改善压缩永久变形

    公开(公告)号:US06476132B1

    公开(公告)日:2002-11-05

    申请号:US09360014

    申请日:1999-07-23

    IPC分类号: C06L8300

    摘要: A thermoplastic vulcanizate (TPV) from a blend of a first thermoplastic polyolefin, a second thermoplastic olefin and a rubber is described. The rubber is crosslinked with a hydrosilylation crosslinking agent. The second polyolefin includes at least one OR group pendant to a Si atom chemically attached via one or more intermediate molecules to said second polyolefin. R can be hydrogen or an alkyl of 1 to 8 carbon atoms. The OR groups can react with the hydrosilylation catalyst to reduce the compression set of the TPV.

    摘要翻译: 描述了来自第一热塑性聚烯烃,第二热塑性烯烃和橡胶的共混物的热塑性硫化橡胶(TPV)。 橡胶与氢化硅烷化交联剂交联。 第二聚烯烃包括通过一个或多个中间分子与所述第二聚烯烃化学连接的Si原子的至少一个OR基团。 R可以是氢或1至8个碳原子的烷基。 OR基团可以与氢化硅烷化催化剂反应以降低TPV的压缩永久变形。

    Thermoplastic vulcanizates from a cyclic olefin rubber, a polyolefin,
and a compatiblizer
    15.
    发明授权
    Thermoplastic vulcanizates from a cyclic olefin rubber, a polyolefin, and a compatiblizer 失效
    来自环烯烃橡胶,聚烯烃和增容剂的热塑性硫化橡胶

    公开(公告)号:US6100334A

    公开(公告)日:2000-08-08

    申请号:US225425

    申请日:1999-01-05

    申请人: Sabet Abdou-Sabet

    发明人: Sabet Abdou-Sabet

    IPC分类号: C08L23/10 C08L23/16 C08F8/00

    摘要: A blend of a semicrystalline polyolefin, a rubbery polymer containing repeat units from norbornene, and a polymeric compatibilizer is disclosed. This composition has reduced oil swell as compared to thermoplastic vulcanizates from a semicrystalline polyolefin and hydrocarbon rubbers.

    摘要翻译: 公开了半结晶聚烯烃,含有来自降冰片烯的重复单元的橡胶状聚合物和聚合物增容剂的共混物。 与来自半结晶聚烯烃和烃橡胶的热塑性硫化橡胶相比,该组合物具有减少的油溶胀。

    Co-cured rubber-thermoplastic elastomer compositions
    16.
    发明授权
    Co-cured rubber-thermoplastic elastomer compositions 失效
    共固化的橡胶 - 热塑性弹性体组合物

    公开(公告)号:US5777033A

    公开(公告)日:1998-07-07

    申请号:US686798

    申请日:1996-07-26

    摘要: A thermoplastic elastomer composition has a plastic phase or matrix of an engineering thermoplastic such as a polyamide and a crosslinked phase of cured acrylic rubbers. The rubbers contain at least two functionalized acrylic rubbers wherein the functional group such as a carboxyl, an epoxy, or a hydroxyl can be the same or different. The curing agents generally react via covalent bonding with the reactive functional groups of the rubbers. The composition can be dynamically vulcanized and when one of the rubbers is a terpolymer of ethylene-alkyl acrylate-unsaturated carboxylic acid, the composition has a single low temperature brittle point.

    摘要翻译: 热塑性弹性体组合物具有工程热塑性塑料的塑料相或基体,例如聚酰胺和固化的丙烯酸橡胶的交联相。 橡胶含有至少两种官能化丙烯酸橡胶,其中官能团如羧基,环氧基或羟基可以相同或不同。 固化剂通常通过共价键与橡胶的反应性官能团反应。 该组合物可以动态硫化,当橡胶之一是乙烯 - 丙烯酸烷基酯 - 不饱和羧酸的三元共聚物时,该组合物具有单一的低温脆性点。

    High temperature, oil resistant thermoplastic vulcanizates made from polar plastics and acrylate or ethylene-acrylate elastomers
    20.
    发明授权
    High temperature, oil resistant thermoplastic vulcanizates made from polar plastics and acrylate or ethylene-acrylate elastomers 有权
    耐高温,耐油的热塑性硫化胶由极性塑料和丙烯酸酯或乙烯 - 丙烯酸酯弹性体制成

    公开(公告)号:US06329463B1

    公开(公告)日:2001-12-11

    申请号:US09618861

    申请日:2000-07-18

    IPC分类号: C08L3502

    摘要: A polar thermoplastic and acrylate or ethylene acrylate based polar rubbers form a useful thermoplastic vulcanizate when the rubber is selectively cured with curatives which do not affect the polar thermoplastic and do not generate volatile organics. Examples of thermoplastics include aromatic polyesters, polycarbonates, poly(phenylene oxide), or combinations thereof. Examples of curatives include compounds with a multifunctional oxazoline, oxazine or imidazoline, which can react with functional groups such as carboxylic acid groups on the rubber.

    摘要翻译: 当使用不影响极性热塑性且不产生挥发性有机物的固化剂选择性地固化橡胶时,极性热塑性和丙烯酸酯或乙烯丙烯酸酯基极性橡胶形成有用的热塑性硫化橡胶。 热塑性塑料的实例包括芳族聚酯,聚碳酸酯,聚(苯醚)或其组合。 固化剂的实例包括具有多官能恶唑啉,恶嗪或咪唑啉的化合物,其可与橡胶上的官能团如羧酸基团反应。