公开(公告)号：US08940933B2

公开(公告)日：2015-01-27

申请号：US13519703

申请日：2010-12-22

申请人： Takeshi Shirasawa ,  Yasuo Amishige ,  Kaoru Omae ,  Akira Matsunaga ,  Akira Sakaguchi

发明人： Takeshi Shirasawa ,  Yasuo Amishige ,  Kaoru Omae ,  Akira Matsunaga ,  Akira Sakaguchi

IPC分类号： C07C51/295 ,  C07C59/305 ,  B01J23/644 ,  C07C51/235

CPC分类号： B01J23/6447 ,  C07C51/235 ,  C07C59/125

摘要： The present invention provides a method for producing polyoxyalkylene alkyl ether carboxylic acid and a salt thereof, including supplying polyoxyalkylene alkyl ether, oxygen, and water to a continuous stirred tank reactor containing a noble metal catalyst to oxidize the polyoxyalkylene alkyl ether with oxygen, in which the molar ratio of the salt of polyoxyalkylene alkyl ether carboxylic acid to the polyoxyalkylene alkyl ether in the continuous stirred tank reactor is controlled to 0.33 to 49.

摘要翻译： 本发明提供了一种生产聚氧化烯烷基醚羧酸及其盐的方法，包括向含有贵金属催化剂的连续搅拌釜反应器中供给聚氧化烯烷基醚，氧和水，以氧化氧化聚氧亚烷基烷基醚，其中 连续搅拌釜式反应器中聚氧化烯烷基醚羧酸盐与聚氧化烯烷基醚的摩尔比控制在0.33〜49。

公开(公告)号：US5545349A

公开(公告)日：1996-08-13

申请号：US210418

申请日：1994-03-18

申请人： Jun Kurii ,  Noboru Nomura ,  Masami Itoh ,  Kozo Ohira ,  Masaki Tsumadori ,  Akira Matsunaga ,  Akio Kimura ,  Shigetoshi Suzue

发明人： Jun Kurii ,  Noboru Nomura ,  Masami Itoh ,  Kozo Ohira ,  Masaki Tsumadori ,  Akira Matsunaga ,  Akio Kimura ,  Shigetoshi Suzue

IPC分类号： C11D3/39 ,  C09K3/00 ,  C01B15/10

CPC分类号： C11D3/391

摘要： A bleaching composition comprising:(a) Hydrogen peroxide or peroxide that produces hydrogen peroxide in aqueous solution; and(b) An organic acid peroxide precursor that produces organic acid peroxide by reacting with said hydrogen peroxide or peroxide that produces hydrogen peroxide in aqueous solution, wherein said organic acid peroxide is represented by general formula (I): ##STR1## wherein R.sup.1 represents a straight chain or branched chain alkyl or alkenyl group having 1-5 carbon atoms, R.sup.2 represents a straight chain or branched chain alkylene group having 1-8 carbon atoms or a phenylene group that may be substituted with a straight chain or branched chain alkyl group having 1-5 carbon atoms, A represent identical or different alkylene groups having from 2 to 4 carbon atoms, and n represents an integer from 0-100.

摘要翻译： 一种漂白组合物，其包含：（a）在水溶液中产生过氧化氢的过氧化氢或过氧化物; （b）通过与在水溶液中产生过氧化氢的所述过氧化氢或过氧化物反应产生有机过氧化氢的有机过氧化氢前体，其中所述有机过氧化物由通式（I）表示： 其中R1表示具有1-5个碳原子的直链或支链烷基或烯基，R2表示具有1-8个碳原子的直链或支链亚烷基或可以被直链或支链取代的亚苯基 具有1-5个碳原子的链烷基，A表示具有2至4个碳原子的相同或不同的亚烷基，n表示0-100的整数。

公开(公告)号：US4747137A

公开(公告)日：1988-05-24

申请号：US880273

申请日：1986-06-30

申请人： Akira Matsunaga

发明人： Akira Matsunaga

IPC分类号： H04K1/04 ,  H04K1/00 ,  H04L9/00

CPC分类号： H04K1/00

摘要： A speech scrambler is disclosed, in which a frequency spectrum obtained by an orthogonal transform of a time domain signal is divided into a plurality of blocks in the frequency domain. One of the blocks which has energy less than a predetermined value is adaptively replaced by a dummy spectrum. The resulting spectrum is rearranged in accordance with a predetermined rule. The frequency spectrum is subjected to an inverse othogonal transform to obtain a time domain signal for transmission. The orthogonal transform is fast Fourier transform or fast Hadamard transform.

摘要翻译： 公开了一种语音加扰器，其中通过时域信号的正交变换获得的频谱在频域中被划分成多个块。 具有能量小于预定值的块之一被自适应地替换为虚拟频谱。 所得光谱根据预定规则重新排列。 对频谱进行逆正交变换以获得用于传输的时域信号。 正交变换是快速傅立叶变换或快速Hadamard变换。

公开(公告)号：US08663858B2

公开(公告)日：2014-03-04

申请号：US12529798

申请日：2008-06-18

申请人： Yoshitaka Ono ,  Takahiro Fujii ,  Takashi Iimori ,  Akira Matsunaga ,  Ryoichi Shimoi ,  Kazuo Saito ,  Hitoshi Igarashi

发明人： Yoshitaka Ono ,  Takahiro Fujii ,  Takashi Iimori ,  Akira Matsunaga ,  Ryoichi Shimoi ,  Kazuo Saito ,  Hitoshi Igarashi

IPC分类号： H01M8/04

CPC分类号： H01M8/04619 ,  H01M8/04223 ,  H01M8/04228 ,  H01M8/04303 ,  H01M8/0432 ,  H01M8/04559 ,  H01M8/04753 ,  H01M8/04768 ,  H01M8/0491 ,  H01M8/04947 ,  H01M8/04955 ,  H01M2250/20 ,  Y02T90/32

摘要： A fuel cell system which prevents the deterioration of the fuel cell stack when feeding of the oxidant gas is paused under a load to perform a fuel conservation operation. Controller shuts down oxidant gas compressor and cooling water circulating pump to execute fuel conservation operation at a low fuel cell system load. The controller gives a current draw instruction to electric power controller. In the fuel conservation operation, electric power controller draws a current larger than zero from fuel cell stack, and keeps the total charge drawn per unit time constant or substantially constant.

摘要翻译： 在负载下暂停燃料电池堆的劣化的燃料电池系统，进行燃料保持动作。 控制器关闭氧化剂气体压缩机和冷却水循环泵，以在低燃料电池系统负载下执行燃油节约操作。 控制器给电力控制器提供电流绘制指令。 在节油操作中，电力控制器从燃料电池堆抽出大于零的电流，并且使单位时间内的总电荷保持恒定或基本恒定。

公开(公告)号：US20120296115A1

公开(公告)日：2012-11-22

申请号：US13519703

申请日：2010-12-22

申请人： Takeshi Shirasawa ,  Yasuo Amishige ,  Kaoru Omae ,  Akira Matsunaga ,  Akira Sakaguchi

发明人： Takeshi Shirasawa ,  Yasuo Amishige ,  Kaoru Omae ,  Akira Matsunaga ,  Akira Sakaguchi

IPC分类号： C07C51/235

CPC分类号： B01J23/6447 ,  C07C51/235 ,  C07C59/125

摘要： The present invention provides a method for producing polyoxyalkylene alkyl ether carboxylic acid and a salt thereof, including supplying polyoxyalkylene alkyl ether, oxygen, and water to a continuous stirred tank reactor containing a noble metal catalyst to oxidize the polyoxyalkylene alkyl ether with oxygen, in which the molar ratio of the salt of polyoxyalkylene alkyl ether carboxylic acid to the polyoxyalkylene alkyl ether in the continuous stirred tank reactor is controlled to 0.33 to 49.

摘要翻译： 本发明提供了一种生产聚氧化烯烷基醚羧酸及其盐的方法，包括向含有贵金属催化剂的连续搅拌釜反应器中供给聚氧化烯烷基醚，氧和水，以氧化氧化聚氧亚烷基烷基醚，其中 连续搅拌釜式反应器中聚氧化烯烷基醚羧酸盐与聚氧化烯烷基醚的摩尔比控制在0.33〜49。

公开(公告)号：US06407277B1

公开(公告)日：2002-06-18

申请号：US08849211

申请日：1997-06-09

申请人： Akira Matsunaga ,  Akira Fujiu ,  Shinji Tsuyutani ,  Toshio Nozaki ,  Masayuki Ueda

发明人： Akira Matsunaga ,  Akira Fujiu ,  Shinji Tsuyutani ,  Toshio Nozaki ,  Masayuki Ueda

IPC分类号： C07F909

CPC分类号： C07F9/11 ,  C07F9/09

摘要： An organic hydroxyl compound is reacted with a phosphorylating agent comprising phosphorus pentaoxide and at least one compound selected from the group consisting of water, phosphoric acid and polyphosphoric acid and having a value represented by formula (I) of from 0.5 to 1.0, under such a condition that the ratio as defined by formula (II) has a value in the range of from 2.8 to 3.2; or alternatively, an organic hydroxyl compound is reacted with the above phosphorylating agent under such a condition that the ratio as defined by formula (II) has a value in the range of from exceeding 3.2 up to 6.4 and then phosphorus pentaoxide is added to the reaction product in such an amount that the ratio as defined by formula (II) has a value in the range of from 2.8 to 3.2 with respect to the total feeds of the starting materials to conduct further reaction. Said process enables the preparation of a phosphoric ester mixture which is excellent in hue and odor, is reduced in the amount of orthophosphoric acid formed as a by-product and contains a phosphoric monoester useful as the component of detergent in an increased amount.

摘要翻译： 使有机羟基化合物与包含五氧化二磷和至少一种选自水，磷酸和多磷酸的化合物的磷酸化剂与式（I）表示的值为0.5至1.0的磷酸化剂反应， 条件是由式（II）定义的比例的值在2.8至3.2的范围内; 或者将有机羟基化合物与上述磷酸化剂反应，使得式（II）定义的比例在超过3.2至6.4的范围内，然后向反应中加入五氧化二磷 产物的量使得由式（II）定义的比例相对于进料进一步反应的起始原料的总进料的值在2.8至3.2的范围内。 所述方法能够制备色调和气味优异的磷酸酯混合物，作为副产物形成的正磷酸的量减少，并且含有可用作增加量的洗涤剂组分的磷酸单酯。

公开(公告)号：US6034261A

公开(公告)日：2000-03-07

申请号：US245843

申请日：1999-02-08

申请人： Akira Matsunaga ,  Akira Fujiu ,  Shinji Tsuyutani ,  Toshio Nozaki ,  Masayuki Ueda

发明人： Akira Matsunaga ,  Akira Fujiu ,  Shinji Tsuyutani ,  Toshio Nozaki ,  Masayuki Ueda

IPC分类号： C07F9/09 ,  C07F9/11

CPC分类号： C07F9/11 ,  C07F9/09

摘要： An organic hydroxyl compound is reacted with a phosphorylating agent comprising phosphorus pentaoxide and at least one compound selected from the group consisting of water, phosphoric acid and polyphosphoric acid and having a value represented by formula (I) of from 0.5 to 1.0, under such a condition that the ratio as defined by formula (II) has a value in the range of from 2.8 to 3.2; or alternatively, an organic hydroxyl compound is reacted with the above phosphorylating agent under such a condition that the ratio as defined by formula (II) has a value in the range of from exceeding 3.2 up to 6.4 and then phosphorus pentaoxide is added to the reaction product in such an amount that the ratio as defined by formula (II) has a value in the range of from 2.8 to 3.2 with respect to the total feeds of the starting materials to conduct further reaction: ##EQU1## The above process produces a phosphoric ester mixture that is excellent in hue and odor, is reduced in the amount of orthophosphoric acid and contains a phosphoric monoester useful as a component of a detergent.

摘要翻译： 使有机羟基化合物与包含五氧化二磷和至少一种选自水，磷酸和多磷酸的化合物的磷酸化剂与式（I）表示的值为0.5至1.0的磷酸化剂反应， 条件是由式（II）定义的比例的值在2.8至3.2的范围内; 或者将有机羟基化合物与上述磷酸化剂反应，使得式（II）定义的比例在超过3.2至6.4的范围内，然后向反应中加入五氧化二磷 产物的量使得由式（II）定义的比例相对于进料进一步反应的起始原料的总进料，其值在2.8至3.2的范围内。上述方法产生磷酸酯混合物，其中 具有优异的色调和气味，正磷酸的量减少，并含有可用作洗涤剂组分的磷酸单酯。

公开(公告)号：US5071585A

公开(公告)日：1991-12-10

申请号：US604172

申请日：1990-10-29

申请人： Akira Matsunaga ,  Junya Wakatsuki ,  Nobutaka Horinishi ,  Takashi Imamura ,  Tomihiro Kurosaki

发明人： Akira Matsunaga ,  Junya Wakatsuki ,  Nobutaka Horinishi ,  Takashi Imamura ,  Tomihiro Kurosaki

IPC分类号： A61K8/06 ,  A61K8/00 ,  A61K8/55 ,  A61K8/58 ,  A61Q5/02 ,  A61Q19/10 ,  C07F9/09 ,  C08G65/32 ,  C11D1/78 ,  C11D1/88 ,  C11D3/36

CPC分类号： A61Q19/10 ,  A61K8/55 ,  A61K8/553 ,  A61Q5/02 ,  C07F9/091 ,  C11D1/886

摘要： Phosphoric acid esters represented by the following formulae (I) and (IX) as well as processes for preparing them are disclosed. ##STR1## wherein R.sub.1 represents a linear or branched, alkyl or alkenyl group having a C.sub.1-36 carbon atom content, with or without the hydrogen atom(s) being substituted with fluorine atom(s), or a phenyl group with substituted linear or branched alkyl group(s) having a C.sub.1-15 carbon atom content, R.sub.2 represents an alkylene group having a C.sub.2-3 carbon atom content, R.sub.3 and R.sub.4 independently denote a hydrogen atom or an alkyl group having a C.sub.1-3 carbon atom content, R.sub.5 and R.sub.6 independently denote a hydrogen atom, or an alkyl, alkenyl, or phenyl group with or without the hydrogen atom(s) being substituted with group(s) containing hetero atom(s), excepting for a mercapto group, R.sub.7 and R.sub.8 independently denote a hydrogen atom, or an alkyl, or alkenyl group, m is an integer of 0-30, n is an integer of 0-5, l is an integer of 0-3, M is a hydrogen atom, an alkali metal, an alkali earth metal, an ammonium group, an alkyl amine group, or an alkanol amine group. The phosphoric acid esters have outstanding surface activity and good foaming capability, and imparts only extremely low irritation to the skin. The detergent composition into which they are formulated is particularly useful as, shampoo, baby shampoo, body shampoo.

公开(公告)号：US5043424A

公开(公告)日：1991-08-27

申请号：US260709

申请日：1988-10-21

申请人： Akira Matsunaga ,  Nobutaka Horinishi ,  Junya Wakatsuki ,  Takashi Imamura ,  Tomihiro Kurosaki

发明人： Akira Matsunaga ,  Nobutaka Horinishi ,  Junya Wakatsuki ,  Takashi Imamura ,  Tomihiro Kurosaki

IPC分类号： C07K14/655 ,  C07K1/00 ,  C07K1/02 ,  C07K1/107 ,  C07K1/113 ,  C07K1/14 ,  C07K4/00 ,  C07K5/06 ,  C07K14/00 ,  C07K14/575 ,  C07K14/76 ,  C07K16/00 ,  C12N9/16 ,  C12N9/96

CPC分类号： C07K5/06191 ,  C07K1/1077

摘要： A peptide or protein is modified by reacting a phosphoric acid ester represented by the following general formula (I) with a peptide or protein: ##STR1## wherein R.sub.1 means a linear or branched, C.sub.1-36 alkyl or C.sub.2-36 alkenyl group whose hydrogen atom or atoms may be substituted by the corresponding number of fluorine atom(s) or a phenyl group substituted by at least one linear or branched C.sub.1-15 alkyl group, R.sub.2 denotes a C.sub.2-3 alkylene group, m stands for a number of 0-30, and M is a hydrogen atom, an alkali metal ion, an alkaline earth metal ion, an ammonium ion, an alkylamine residue or an alkanolamine residue.

公开(公告)号：US4148056A

公开(公告)日：1979-04-03

申请号：US809107

申请日：1977-06-22

申请人： Akira Matsunaga ,  Kensuke Suzuki

发明人： Akira Matsunaga ,  Kensuke Suzuki

IPC分类号： H01L23/29 ,  H01L23/31 ,  H01L23/48 ,  H01L25/07 ,  H01L23/30

CPC分类号： H01L25/074 ,  H01L23/296 ,  H01L23/3107 ,  H01L24/01 ,  H01L2924/10253 ,  H01L2924/12036 ,  H01L2924/351

摘要： A glass-encapsulated semiconductor device characterized in that a rectifier unit comprises a lamination of electrically series-connected and mechanically bonded semiconductor pellets and an electric-conductive spacer, and a pair of electrodes with external lead wires which are electrically connected and mechanically bonded with said lamination by means of soldering materials, the peripheral surface of the rectifier unit is covered with a protective glass layer over the entire length from one of the electrodes to the other, said conductive spacer having such a thickness that the thermal expansion coefficient of said spacer may be equal to the average thermal expansion coefficient of a virtual laminated column of said semiconductor pellets alone.

摘要翻译： 一种玻璃封装的半导体器件，其特征在于，整流单元包括电串联连接和机械结合的半导体芯片和导电间隔物的层压体，以及一对具有外部引线的电极，所述外部引线电连接并机械地与所述 通过焊接材料层压，整流单元的外围表面在从一个电极到另一电极的整个长度上被保护性玻璃层覆盖，所述导电间隔物具有这样的厚度，使得所述间隔物的热膨胀系数可以 等于所述半导体颗粒单独的虚拟层压柱的平均热膨胀系数。