中科微点-全球专利检索

  1. Login
  2. Sign Up

Search Results

20 records (took 0.02 seconds)

    Synthesis of a boron-containing zeolite with an MWW framework structure
    12.
    发明授权
    Synthesis of a boron-containing zeolite with an MWW framework structure 有权

    公开(公告)号：US10196276B2

    公开(公告)日：2019-02-05

    申请号：US15316220

    申请日：2015-06-03

    Applicant: BASF SE

    Inventor： Stefan Maurer ,  Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Xiangju Meng ,  Feng-Shou Xiao ,  Yeqing Wang

    IPC: C01B39/48 ,  C01B39/12 ,  B01D15/36 ,  B01D53/86 ,  B01J20/18 ,  B01J29/86

    Abstract: The present invention relates to a process for the production of a boron-containing zeolitic material having an MWW framework structure comprising YO2 and B2O3, wherein Y stands for a tetravalent element, wherein said process comprises (a) providing a mixture comprising one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals, (b) crystallizing the mixture obtained in (a) for obtaining a layered precursor of the boron-containing MWW-type zeolitic material, (c) calcining the layered precursor obtained in (b) for obtaining the boron-containing zeolitic material having an MWW framework structure, wherein the one or more organotemplates have the formula (I): R1R2R3N, wherein R1 is (C5-C8)cycloalkyl, and wherein R2 and R3 are independently from each other H or alkyl, as well as to a synthetic boron-containing zeolite which is obtainable and/or obtained according to the inventive process as well as to its use.

    Organotemplate-free solid-state synthetic method for zeolite molecular sieves
    13.
    发明授权
    Organotemplate-free solid-state synthetic method for zeolite molecular sieves 有权

    公开(公告)号：US10160656B2

    公开(公告)日：2018-12-25

    申请号：US14649637

    申请日：2013-12-05

    Applicant: BASF SE

    Inventor： Stefan Maurer ,  Ulrich Müller ,  Feng-Shou Xiao ,  Xiangju Meng ,  Qinming Wu

    IPC: C01B39/46 ,  C01B39/02 ,  C01B39/38 ,  C01B39/20 ,  C01B39/26 ,  B01J29/08 ,  B01J29/18 ,  B01J29/70 ,  B01J35/00 ,  B01J35/10 ,  B01J29/40 ,  B01J37/00 ,  B01J37/04 ,  C01B39/14

    Abstract: Described is a preparation method for zeolite molecular sieves by means of solid-state reactions without the usage of organic templates. The method comprises the following steps: grinding and mixing the solid raw materials comprising the silicon source, the aluminum source and the alkali source, transferring the obtained mixture into an autoclave, conducting the crystallization for a period of 5 hours-20 days at a temperature of 50-200° C. After filtering and drying the crystallized products, molecular sieves in a powder form can be obtained. The method provides different molecular sieves, including ZSM-5 zeolite, Beta zeolite, FAU zeolite, MOR zeolite, LTA zeolite, and GIS zeolite, with a high crystallinity and an adjustable Si/Al ratio within a certain range. The obtained products exhibit a high crystallinity and a high purity, and the method does not require the use of organic templates and solvents, which avoids unnecessary consumptions during the production, simplifies the synthetic process, and also increases the yield from the autoclave reactor.

    Organotemplate-Free Solid-State Synthetic Method For Zeolite Molecular Sieves
    14.
    发明申请
    Organotemplate-Free Solid-State Synthetic Method For Zeolite Molecular Sieves 审中-公开
    无机固体合成方法用于沸石分子筛

    公开(公告)号：US20150298983A1

    公开(公告)日：2015-10-22

    申请号：US14649637

    申请日：2013-12-05

    Applicant: BASF SE

    Inventor： Stefan Maurer ,  Ulrich Müller ,  Feng-Shou Xiao ,  Xiangju Meng ,  Qinming Wu

    IPC: C01B39/46 ,  C01B39/20 ,  B01J29/40 ,  C01B39/14 ,  B01J37/04 ,  B01J37/00 ,  C01B39/38 ,  C01B39/26

    CPC classification number: C01B39/46 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/70 ,  B01J35/002 ,  B01J35/1023 ,  B01J35/1038 ,  B01J37/009 ,  B01J37/04 ,  C01B39/02 ,  C01B39/14 ,  C01B39/20 ,  C01B39/26 ,  C01B39/38

    Abstract: Described is a preparation method for zeolite molecular sieves by means of solid-state reactions without the usage of organic templates. The method comprises the following steps: grinding and mixing the solid raw materials comprising the silicon source, the aluminum source and the alkali source, transferring the obtained mixture into an autoclave, conducting the crystallization for a period of 5 hours-20 days at a temperature of 50-200° C. After filtering and drying the crystallized products, molecular sieves in a powder form can be obtained. The method provides different molecular sieves, including ZSM-5 zeolite, Beta zeolite, FAU zeolite, MOR zeolite, LTA zeolite, and GIS zeolite, with a high crystallinity and an adjustable Si/Al ratio within a certain range. The obtained products exhibit a high crystallinity and a high purity, and the method does not require the use of organic templates and solvents, which avoids unnecessary consumptions during the production, simplifies the synthetic process, and also increases the yield from the autoclave reactor.

    Abstract translation: 描述了通过固相反应而不使用有机模板的沸石分子筛的制备方法。 该方法包括以下步骤：将包含硅源，铝源和碱源的固体原料研磨并混合，将得到的混合物转移到高压釜中，在温度下进行5小时-20天的结晶 50-200℃。过滤并干燥结晶产物后，可获得粉末形式的分子筛。 该方法提供了不同的分子筛，包括ZSM-5沸石，β沸石，FAU沸石，MOR沸石，LTA沸石和GIS沸石，在一定范围内具有高结晶度和可调Si / Al比。 得到的产物具有高结晶度和高纯度，并且该方法不需要使用有机模板和溶剂，这避免了在生产过程中不必要的消耗，简化了合成过程，并且还提高了高压釜反应器的产率。

    AN OXIDIC MATERIAL COMPRISING A ZEOLITE HAVING FRAMEWORK TYPE AEI
    15.
    发明申请
    AN OXIDIC MATERIAL COMPRISING A ZEOLITE HAVING FRAMEWORK TYPE AEI 有权

    公开(公告)号：US20220106192A1

    公开(公告)日：2022-04-07

    申请号：US17423590

    申请日：2020-01-21

    Applicant: BASF SE

    Inventor： Andrei-Nicolae Parvulescu ,  Feng-Shou Xiao ,  Xiangju Meng ,  Qinming Wu ,  Yu Dai ,  Stefan Maurer ,  Ulrich Mueller ,  Hao XU

    IPC: C01B39/48

    Abstract: A process for preparing an oxidic material comprising a zeolitic material having framework type AEI and a framework structure comprising a tetravalent element Y, a trivalent element X, and O, the process comprising preparing a synthesis mixture comprising water, a source of Y, a source of X comprising sodium, an AEI framework structure directing agent, and a source of sodium other than the source of X; and heating the synthesis mixture obtained from (i) to a temperature in the range of from 100 to 180° C. and keeping the synthesis mixture under autogenous pres-sure at a temperature in this range for a time in the range of at least 6 h, obtaining the oxidic material comprising a zeolitic material having framework type AEI and a framework structure comprising a tetravalent element Y, a trivalent element X, and O, comprised in its mother liquor; wherein the AEI framework structure directing agent according to (i) comprises a N, N-diethyl-2,6-dimethylpiperidinium cation.

    Catalyst for the Conversion of Syngas to Olefins and Preparation Thereof
    20.
    发明申请
    Catalyst for the Conversion of Syngas to Olefins and Preparation Thereof 审中-公开
    合成气转化为烯烃及其制备的催化剂

    公开(公告)号：US20140113981A1

    公开(公告)日：2014-04-24

    申请号：US14056002

    申请日：2013-10-17

    Applicant: BASF SE

    Inventor： Bilge Yilmaz ,  Ulrich Müller ,  Xinhe Bao ,  Weiping Zhang ,  Dirk de Vos ,  Takashi Tatsumi ,  Feng-Shou Xiao ,  Hermann Gies ,  Hiroyuki Imai

    IPC: C07C1/04 ,  B01J29/76

    CPC classification number: C07C1/044 ,  B01J29/76 ,  B01J29/89 ,  B01J35/1019 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J2229/186 ,  C10G25/003 ,  C10G25/03

    Abstract: Described is a process for the production of a pillared silicate. The process comprises (i) providing a layered silicate; (ii) interlayer expanding the layered silicate provided in step (i) comprising a step of treating the layered silicate with one or more swelling agents; (iii) treating the interlayer expanded silicate obtained in step (ii) with one or more hydrolyzable silicon containing compounds; (iv) treating the interlayer expanded compound obtained in step (iii) with an aqueous solution to obtain a pillared silicate; (v) removing at least a portion of the one or more swelling agents from the pillared silicate obtained in step (iv); and (vi) impregnating the pillared silicate obtained in step (v) with one or more elements selected from the group consisting of Fe, Ru, Ir, and combinations of two or more thereof. Also described is a pillared silicate optionally obtainable from said process and its use, in particular, in a process for the production of one or more olefins according to the invention.

    Abstract translation: 描述了生产柱状硅酸盐的方法。 该方法包括（i）提供层状硅酸盐; （ii）层间膨胀步骤（i）中提供的层状硅酸盐，包括用一种或多种溶胀剂处理层状硅酸盐的步骤; （iii）用一种或多种可水解含硅化合物处理在步骤（ii）中获得的层间发泡硅酸盐; （iv）用水溶液处理步骤（iii）中得到的层间发泡化合物，得到柱状硅酸盐; （v）从步骤（iv）中获得的柱状硅酸盐中去除至少一部分一种或多种溶胀剂; 和（vi）用步骤（v）中获得的柱状硅酸盐浸渍一种或多种选自Fe，Ru，Ir的元素，以及两种或更多种的组合。 还描述了可任意地从所述方法获得的柱状硅酸盐及其用途，特别是用于生产根据本发明的一种或多种烯烃的方法。

Patent Agency Ranking