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公开(公告)号:US20140334027A1
公开(公告)日:2014-11-13
申请号:US14361113
申请日:2012-12-03
Applicant: BASF SE
Inventor: Yuichi Nishimae , Hisatoshi Kura , Kazuhiko Kunimoto , Ryuhei Yamagami , Keita Tanaka
IPC: C07D209/80 , C07D209/86 , G02B5/20 , C07D409/04 , C08F2/50 , G03F7/20 , C07D409/14
CPC classification number: C07D209/80 , C07D209/86 , C07D403/12 , C07D409/04 , C07D409/14 , C08F2/50 , G02B5/201 , G03F7/0007 , G03F7/20
Abstract: Oxime ester compounds of formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 independently of each other are hydrogen, C1-C20alkyl, (A), COR14, NO2, or OR15; provided that at least one of R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 is (A), and provided that at least one of the remaining R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 is COR14 or NO2; R11 is for example C1-C20alkyl, M or (B); X and X1 are for example a direct bond; R12 and R′12 are for example hydrogen or C1-C20alkyl; R13 and R′13 are for example C6-C20aryl or C3-C20heteroaryl; M is (X), (Y) or (Z); X3 is O, S or NR19; R14 and R15 are for example phenyl; R20, R21, R22, R23, R24, or R25 for example are hydrogen, COR14, NO2, or (B); provided that at least two oxime ester groups are present in the molecule; are useful as photoinitiators.
Abstract translation: 式(I)的肟酯化合物,其中R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8,R 9和R 10彼此独立地是氢,C 1 -C 20烷基,(A),COR 14,NO 2或 OR15; 条件是R1,R2,R3,R4,R5,R6,R7,R8,R9和R10中的至少一个是(A),并且条件是剩余的R1,R2,R3,R4,R5, R6,R7,R8,R9和R10是COR14或NO2; R 11例如为C 1 -C 20烷基,M或(B); X和X1例如是直接键; R 12和R 12如氢或C 1 -C 20烷基; R 13和R 13如C 6 -C 20芳基或C 3 -C 20杂芳基; M为(X),(Y)或(Z); X3是O,S或NR19; R 14和R 15例如为苯基; R 20,R 21,R 22,R 23,R 24或R 25例如是氢,COR 14,NO 2或(B); 条件是分子中存在至少两个肟酯基团; 作为光引发剂是有用的。
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公开(公告)号:US11209733B2
公开(公告)日:2021-12-28
申请号:US16563982
申请日:2019-09-09
Applicant: BASF SE
Inventor: Yuichi Nishimae , Hisatoshi Kura , Kazuhiko Kunimoto , Ryuhei Yamagami , Keita Tanaka
IPC: G03F7/031 , G03F7/027 , G03F7/00 , C07D209/88 , G03F7/20 , G03F7/30 , C07D209/86 , C08F122/20 , C09D135/02 , G02B5/20 , G03F7/033 , G03F7/26
Abstract: Oxime ester compounds of the formula I, II, III, IV or V wherein Z is for example Z1 for is NO2, unsubstituted or substituted C7-C20aroyl or unsubstituted or substituted C4-C20heteroaroyl; provided that at least one Z1 is other than NO2; Z2 is for example unsubstituted or substituted C7-C20aroyl; R1, R2, R3, R4, R5 and R6 for example are hydrogen, halogen, or unsubstituted or substituted C1-C20alkyl, unsubstituted or substituted C6-C20aryl, or unsubstituted or substituted C4-C20heteroaryl; R9, R10, R11, R12 and R13 for example are hydrogen, halogen, OR16, unsubstituted or substituted C1-C20alkyl; provided that R9 and R13 are neither hydrogen nor fluorine; R14 is for example unsubstituted or substituted C6-C20aryl or C3-C20heteroaryl Q is for example C6-C20arylene or C3-C20heteroarylene; Q1 is —C1-C20alkylene-CO—; Q2 is naphthoylene; Q3 is for example phenylene; L is for example O-alkylene-O—; R15 is for example hydrogen or C1-C20alkyl; R20 is for example hydrogen, or unsubstituted or substituted C1-C20alkyl; are effective photoinitiators.
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公开(公告)号:US10793555B2
公开(公告)日:2020-10-06
申请号:US15918512
申请日:2018-03-12
Applicant: BASF SE
Inventor: Kazuhiko Kunimoto , Hisatoshi Kura , Hiroshi Yamamoto , Yumiko Nakagawa , Toshikage Asakura , Kaori Sameshima
IPC: C07D209/12 , C07D307/80 , C07D333/56 , G02B5/20 , G03F7/031 , C07D409/06 , C07D307/86 , G02B5/22 , G03F7/00 , G03F7/20 , C07D307/83 , G03F7/32 , C07D307/91 , C07D407/12 , C07D307/92 , C07D307/56 , G03F7/038 , G03F7/033
Abstract: Compounds of the formulae (I) or (II) wherein X is A is O, S, NR5 or CR16R17; R1 is for example hydrogen or C1-C20alkyl R2 is for example hydrogen, C1-C20alkyl or C6-C20aryl R5 for example is C1-C20alkyl; R7, R8, R9, R10 and R11 for example independently of each other are hydrogen. C1-C20alkyl, halogen, CN or NO2; Ar1 is for example unsubstituted or substituted C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl, C3-C20heteroarylcarbonyl or or Ar1 is Ar2 is for example phenylene, all of which are unsubstituted or substituted M is for example unsubstituted or substituted C1-C20alkylene Y is a direct bond, O, S, NR5 or CO; Z1 is for example O or S; Z2 is a direct bond, O, S or NR5; and Q is CO or a direct bond.
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公开(公告)号:US20180208583A1
公开(公告)日:2018-07-26
申请号:US15918512
申请日:2018-03-12
Applicant: BASF SE
Inventor: Kazuhiko Kunimoto , Hisatoshi Kura , Hiroshi Yamamoto , Yumiko Nakagawa , Toshikage Asakura , Kaori Sameshima
IPC: C07D409/06 , G03F7/32 , C07D209/12 , G03F7/031 , G03F7/00 , G02B5/22 , G02B5/20 , C07D407/12 , C07D333/56 , C07D307/92 , C07D307/91 , C07D307/86 , C07D307/83 , C07D307/80 , C07D307/56 , G03F7/20
Abstract: Compounds of the formulae (I) or (II) wherein X is A is O, S, NR5 or CR16R17; R1 is for example hydrogen or C1-C20alkyl R2 is for example hydrogen, C1-C20alkyl or C6-C20aryl R5 for example is C1-C20alkyl; R7, R8, R9, R10 and R11 for example independently of each other are hydrogen. C1-C20alkyl, halogen, CN or NO2; Ar1 is for example unsubstituted or substituted C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl, C3-C20heteroarylcarbonyl or or Ar1 is Ar2 is for example phenylene, all of which are unsubstituted or substituted M is for example unsubstituted or substituted C1-C20alkylene Y is a direct bond, O, S, NR5 or CO; Z1 is for example O or S; Z2 is a direct bond, O, S or NR5; and Q is CO or a direct bond.
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公开(公告)号:US09994538B2
公开(公告)日:2018-06-12
申请号:US15546699
申请日:2016-01-29
Applicant: BASF SE
Inventor: Keita Tanaka , Yuki Matsuoka , Kazuhiko Kunimoto , Toshikage Asakura , Hisatoshi Kura
IPC: C07D307/52 , C07D311/16 , G03F7/039 , G03F7/004 , G03F7/038
CPC classification number: C07D307/52 , C07D311/16 , G03F7/0045 , G03F7/0046 , G03F7/038 , G03F7/039
Abstract: Compounds of the formula (I) and (IA) wherein X is —O(CO)—; R1 is C1-C12haloalkyl or C6-C10haloaryl; R2 is located in position 7 of the coumarinyl ring and is OR8; R2a, R2b and R2C independently of each other are hydrogen; R3 is C1-C8haloalkyl or C1-C8haloalkyl; R4 is hydrogen; and R8 is C1-C6alkyI; are suitable as photosensitive acid donors in the preparation of photoresist compositions such as used for example in the preparation of spacers, insulating layers, interlayer dielectric films, insulation layers, planarization layers, protecting layers, overcoat layers, banks for electroluminescence displays and liquid crystal displays (LCD).
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公开(公告)号:US09631048B2
公开(公告)日:2017-04-25
申请号:US14389831
申请日:2013-04-17
Applicant: BASF SE
Inventor: Kazuhiko Kunimoto , Hisatoshi Kura
IPC: B05D3/00 , C07C309/08 , C07C309/10 , C07D307/10 , C07D309/08 , C07D333/46 , C08G59/40 , C08G59/62 , C08L63/00 , C09D11/02 , C09D163/00 , C09J163/00 , G03F7/00 , G03F7/004
CPC classification number: C08G59/62 , B05D3/007 , C07C309/08 , C07C309/10 , C07C2601/08 , C07C2601/14 , C07D307/10 , C07D309/08 , C07D333/46 , C08G59/4064 , C08L63/00 , C09D11/02 , C09D163/00 , C09J163/00 , G03F7/0045
Abstract: Compounds of the formula (I), (Ia) or (Ib) wherein A1, and A− is for example (II) is 1 or 2; X is C1-C4 alkylene or CO; Y is for example O, O(CO), O(CO)O, R1 is for example hydrogen, d-dsalkyl, C3-C30cycloalkyl, phenyl, naphthyl, anthracyl, phenanthryl, biphenylyl, fluorenyl or C3-C20heteroaryl, all of which optionally are substituted; R2 and R3 for example are C1-C10haloalkylene which is optionally substituted, or R2 and R3 are phenylene, which optionally is substituted; R4 is a group (A) or a group (B); R5 and R6 for example are C1-C20alkyl; or R4 and R5 or R4 and R6 together form a straight-chain C2-C6alkylene, R5 and R6 together form a straight-chain C2-C6alkylene; R7, R8, R9 and R10 ifor example are C1-C20alkyl; M for example is C1-C20alkylene, C2-C20alkenylene, C2-C20alkynylene; R25 and R26 are for example hydrogen, C1-C20alkyl; R27, R28, R29, R30 and R31 are for example hydrogen, C1-C20alkyl, C2-C20alkenyl, C3-C20cycloalkyl, or two radicals R27 and R28, R28 and R29, R29 and R30 and/or R30 and R31 together form a straight-chain C2-C6alkylene, or R25 and R27 together form 1,2-phenylene, R33 and R34 for example are hydrogen, C1-C20alkyl; R35, R36 and R37 for example are hydrogen, C1-C20alkyl; are suitable as thermo-acid generators.
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公开(公告)号:US20150044509A1
公开(公告)日:2015-02-12
申请号:US14389831
申请日:2013-04-17
Applicant: BASF SE
Inventor: Kazuhiko Kunimoto , Hisatoshi Kura
IPC: C08G59/62 , C07D333/46 , C07D307/10 , B05D3/00 , C09D163/00 , C07C309/10 , C08G59/40 , C07C309/08 , C07D309/08
CPC classification number: C08G59/62 , B05D3/007 , C07C309/08 , C07C309/10 , C07C2601/08 , C07C2601/14 , C07D307/10 , C07D309/08 , C07D333/46 , C08G59/4064 , C08L63/00 , C09D11/02 , C09D163/00 , C09J163/00 , G03F7/0045
Abstract: Compounds of the formula (I), (Ia) or (Ib) wherein A1, and A− is for example (II) is 1 or 2; X is C1-C4 alkylene or CO; Y is for example O, O(CO), O(CO)O, R1 is for example hydrogen, d-dsalkyl, C3-C30cycloalkyl, phenyl, naphthyl, anthracyl, phenanthryl, biphenylyl, fluorenyl or C3-C20heteroaryl, all of which optionally are substituted; R2 and R3 for example are C1-C10haloalkylene which is optionally substituted, or R2 and R3 are phenylene, which optionally is substituted; R4 is a group (A) or a group (B); R5 and R6 for example are C1-C20alkyl; or R4 and R5 or R4 and R6 together form a straight-chain C2-C6alkylene, R5 and R6 together form a straight-chain C2-C6alkylene; R7, R8, R9 and R10 ifor example are C1-C20alkyl; M for example is C1-C20alkylene, C2-C20alkenylene, C2-C20alkynylene; R25 and R26 are for example hydrogen, C1-C20alkyl; R27, R28, R29, R30 and R31 are for example hydrogen, C1-C20alkyl, C2-C20alkenyl, C3-C20cycloalkyl, or two radicals R27 and R28, R28 and R29, R29 and R30 and/or R30 and R31 together form a straight-chain C2-C6alkylene, or R25 and R27 together form 1,2-phenylene, R33 and R34 for example are hydrogen, C1-C20alkyl; R35, R36 and R37 for example are hydrogen, C1-C20alkyl; are suitable as thermo-acid generators.
Abstract translation: 其中A1和A-为(II)的式(I),(Ia)或(Ib)的化合物为1或2; X是C 1 -C 4亚烷基或CO; Y是例如O,O(CO),O(CO)O,R 1例如是氢,d-ds烷基,C 3 -C 30环烷基,苯基,萘基,蒽基,菲基,联苯基,芴基或C 3 -C 20杂芳基, 任选被取代; R2和R3例如是任选取代的C1-C10卤代亚烷基,或R2和R3是任选被取代的亚苯基; R4是一组(A)或一组(B); R5和R6例如是C1-C20烷基; 或R 4和R 5或R 4和R 6一起形成直链C 2 -C 6亚烷基,R 5和R 6一起形成直链C 2 -C 6亚烷基; R 7,R 8,R 9和R 10如果为C 1 -C 20烷基; M例如是C 1 -C 20亚烷基,C 2 -C 20亚烯基,C 2 -C 20亚炔基; R 25和R 26是例如氢,C 1 -C 20烷基; R27,R28,R29,R30和R31是例如氢,C1-C20烷基,C2-C20链烯基,C3-C20环烷基或两个基团R27和R28,R28和R29,R29和R30和/或R30和R31一起形成直链 链C 2 -C 6亚烷基或R 25和R 27一起形成1,2-亚苯基,R 33和R 34例如是氢,C 1 -C 20烷基; R 35,R 36和R 37例如是氢,C 1 -C 20烷基; 适合作为热酸发生器。
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