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公开(公告)号:US11753355B2
公开(公告)日:2023-09-12
申请号:US16862813
申请日:2020-04-30
Applicant: Chevron U.S.A. Inc.
Inventor: Howard Steven Lacheen , Hye-Kyung Cho Timken
IPC: C07C2/12 , B01J20/10 , B01J20/28 , B01J27/125 , B01J31/02 , C10G7/00 , C10G7/06 , C10G25/00 , C10G50/02 , C10G69/12
CPC classification number: C07C2/12 , B01J20/103 , B01J20/28061 , B01J20/28071 , B01J20/28083 , B01J27/125 , B01J31/0284 , C10G7/003 , C10G7/06 , C10G25/003 , C10G50/02 , C10G69/126 , C10G2300/302 , C10G2300/304 , C10G2300/70
Abstract: Described herein is a base oil synthesis via ionic catalyst oligomerization further utilizing a hydrophobic process for removing an ionic catalyst from a reaction mixture with a silica gel composition, specifically a reaction mixture comprising an oligomerization reaction to produce PAO utilizing an ionic catalyst wherein the ionic catalyst is removed post reaction.
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公开(公告)号:US11643373B1
公开(公告)日:2023-05-09
申请号:US17954438
申请日:2022-09-28
Applicant: CHEVRON U.S.A. INC.
Inventor: Huping Luo , Hye-Kyung Cho Timken , Bong-Kyu Chang
CPC classification number: C07C2/60 , B01J31/0277 , B01J31/0284 , C07C2/58 , C07C2/62 , C07C2531/02
Abstract: An alkylation process is described. The process involves alkylation of isobutane and ethylene in a loop reactor using an ionic liquid catalyst as a continuous phase. The alkylate typically has a research octane number of at least about 93, and the olefin conversion is typically at least about 95%.
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13.
公开(公告)号:US11621059B2
公开(公告)日:2023-04-04
申请号:US17325310
申请日:2021-05-20
Applicant: CHEVRON U.S.A. INC.
Inventor: Toni Zhang Miao , Huping Luo , Hye-Kyung Cho Timken , Eddy Lee , Bong-Kyu Chang
IPC: G16C20/70 , G16C10/00 , G16C20/30 , C07C2/76 , G01N21/3577 , G01N33/28 , C07C2/66 , C07C2/64 , G01N21/35 , C07C2/68 , C07C2/70
Abstract: A method is provided for predicting conjunct polymer concentration in spent ionic liquid during a continuous hydrocarbon conversion process.
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公开(公告)号:US10301233B2
公开(公告)日:2019-05-28
申请号:US15640655
申请日:2017-07-03
Applicant: Chevron U.S.A. Inc.
Inventor: Hye-Kyung Cho Timken , Kenneth John Peinado , Bong-Kyu Chang
Abstract: We provide a process, comprising:a. dehydrogenating natural gas liquid to produce a mixture comprising olefins and unconverted paraffins;b. without further purification or modification other than mixing with an isoparaffin, sending the mixture to a single alkylation reactor;c. alkylating the olefins with the isoparaffin, using an ionic liquid catalyst, to produce one or more alkylate products; andd. distilling the one or more alkylate products and collecting a bottoms distillation fraction that is a middle distillate blending component having a sulfur level of 50 wppm or less and a Bromine number less than 1.
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15.
公开(公告)号:US10094778B1
公开(公告)日:2018-10-09
申请号:US15612648
申请日:2017-06-02
Applicant: Chevron U.S.A. Inc.
Inventor: Huping Luo , Hye-Kyung Cho Timken , Toni Zhang Miao , Howard Steven Lacheen , Bi-Zeng Zhan
IPC: G01J3/00 , G01N21/552 , G01N21/3577 , G01N21/15 , G01N1/34 , G01N21/35
Abstract: An integrated system for monitoring a chemical concentration in an ionic liquid, comprising: a. an online FTIR instrument with an ATR window; b. a sample conditioning station that removes light hydrocarbons and produces a degassed ionic liquid that is analyzed by FTIR; and c. a solvent flushing system that flows solvent across the ATR window. Also, a process for monitoring the chemical concentration, comprising: a. degassing the ionic liquid in the sample conditioning station; b. passing the degassed ionic liquid over an ATR window; c. periodically redirecting a flow of the degassed ionic liquid via a bypass line or an on-off valve that isolates the ATR window from the process unit that elutes the ionic liquid; and d. flowing a solvent and a purging gas over the ATR window during the periodically redirecting step c); and e. resuming the passing of the degassed ionic liquid over the ATR window.
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公开(公告)号:US20180065899A1
公开(公告)日:2018-03-08
申请号:US15255271
申请日:2016-09-02
Applicant: Chevron U.S.A. Inc.
Inventor: Hye-Kyung Cho Timken , Bong-Kyu Chang , Sven Ivar Hommeltoft
CPC classification number: C07C2/58 , B01J31/0284 , B01J2231/32 , C07C2/60 , C07C2527/126 , C07C2531/02 , C10G17/02 , C10G29/205 , C10G2300/1088 , C10G2400/02 , C10L1/06 , C10L2270/023 , C07C11/02
Abstract: A process, comprising: providing an olefin feed comprising pentenes, butenes, and isopentane; and alkylating the olefin feed with isobutane using acidic ionic liquid catalyst; wherein less than 5 mol % of C5 olefins in the olefin feed are converted to isopentane, and the alkylate gasoline has defined final boiling points and high RONs. A process comprising: alkylating an olefin feed comprising pentenes and isopentane, with isobutane using acidic ionic liquid catalyst; wherein less than 5 mol % of C5 olefins in the olefin feed are converted to isopentane; and wherein an n-pentane product yield is low. An alkylate gasoline, comprising less than 0.1 wt % olefins and aromatics, less than 1.8 wt % C12+ hydrocarbons, and greater than 60 wt % combined C8 and C9 hydrocarbons, wherein the trimethylpentane in the C8 hydrocarbons and the trimethylhexane in the C9 hydrocarbons are defined.
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17.
公开(公告)号:US20180056212A1
公开(公告)日:2018-03-01
申请号:US15251640
申请日:2016-08-30
Applicant: Chevron U.S.A. Inc.
Inventor: Huping Luo , Hye-Kyung Cho Timken
CPC classification number: B01D17/045 , B01D17/0214 , B01D17/10 , C07C7/00 , C07C7/005 , C07C9/15 , C10G31/00 , C10G33/06 , C07C9/14
Abstract: An integrated coalescing system for separating ionic liquid from a liquid hydrocarbon is provided, comprising: a. a bulk settler, that separates an emulsion comprising the dispersed ionic liquid with a wide range of droplet sizes into a clean ionic liquid phase and a separated liquid hydrocarbon phase comprising retained droplets; b. a pre-coalescer that receives the separated liquid hydrocarbon phase, separates out solid particles from the separated liquid hydrocarbon phase, and begins to form coalesced droplets of the retained droplets; and c. a coalescer that receives an effluent from the pre-coalescer, wherein the at least one coalescer comprises multiple layers of media having a fine pore size, and produces a clean hydrocarbon stream that is free of the dispersed ionic liquid and additional amounts of the clean ionic liquid phase. Also, a process is provided for separating an ionic liquid from a liquid hydrocarbon, using the integrated coalescing system.
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公开(公告)号:US12043589B2
公开(公告)日:2024-07-23
申请号:US18116747
申请日:2023-03-02
Applicant: Chevron U.S.A. Inc.
Inventor: Bong Kyu Chang , Hye-Kyung Cho Timken , Michelle K. Young
CPC classification number: C07C2/22 , C10G50/02 , C07C2527/06 , C07C2527/122 , C07C2527/125 , C07C2527/128
Abstract: A process for producing renewable distillate-range hydrocarbons is provided. The process includes dehydrating a renewable C2-C6 alcohol feedstock to produce an olefin, oligomerizing the olefin the presence of a halometallate ionic liquid catalyst to produce an oligomer product and hydrogenating the oligomer product or fractions thereof to produce saturated distillate-range hydrocarbons.
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公开(公告)号:US11964926B2
公开(公告)日:2024-04-23
申请号:US17954420
申请日:2022-09-28
Applicant: CHEVRON U.S.A. INC.
Inventor: Bong-Kyu Chang , Hye-Kyung Cho Timken , Huping Luo
CPC classification number: C07C2/60 , B01J31/0244 , C07C9/16 , C10L1/06 , C07C2531/02 , C10L2200/0423 , C10L2270/023
Abstract: A process for producing high octane alkylate is provided. The process involves reacting isobutane and ethylene using an ionic liquid catalyst. Reaction conditions can be chosen to assist in attaining, or to optimize, desirable alkylate yields and/or properties.
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公开(公告)号:US11643374B1
公开(公告)日:2023-05-09
申请号:US17954486
申请日:2022-09-28
Applicant: CHEVRON U.S.A. INC.
Inventor: Bong-Kyu Chang , Hye-Kyung Cho Timken , Michelle K. Young , Cong-Yan Chen , Stephen Joseph Miller
CPC classification number: C07C2/60 , B01J31/0284 , C07C1/24 , C07C2531/02
Abstract: A process for producing high octane bio-based alkylate is provided. The process involves reacting isobutane and bio-ethylene using an ionic liquid catalyst. Reaction conditions can be chosen to assist in attaining, or to optimize, desirable alkylate yields and/or properties.
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