公开(公告)号：US20140313670A1

公开(公告)日：2014-10-23

申请号：US14366237

申请日：2012-12-05

Applicant: Dow Global Technologies LLC

Inventor： Suh Joon Han ,  Brian R. Maurer ,  Xiaodong Zhang

IPC: H01B3/20 ,  H05K7/20

CPC classification number: H01B3/20 ,  H01B3/22 ,  H05K7/20218

Abstract: The present disclosure is directed to a dielectric fluid comprising a farnesene-based oligomer and an antioxidant and devices containing the dielectric fluid.

Abstract translation: 本公开涉及包含法呢烯基低聚物和抗氧化剂的介电流体和包含电介质流体的装置。

公开(公告)号：US20240067812A1

公开(公告)日：2024-02-29

申请号：US18258878

申请日：2022-03-23

Applicant: Dow Global Technologies LLC

Inventor： Paul J. Caronia ,  Jeffrey M. Cogen ,  Bharat I. Chaudhary ,  Timothy J. Person ,  Suh Joon Han

IPC: C08L43/04 ,  C08K3/04

CPC classification number: C08L43/04 ,  C08K3/04 ,  C08L2203/20 ,  C08L2312/08

Abstract: A moisture-curable semiconductive formulation consisting essentially of a polyethylene-based polymer blend (uncured) and a conventional carbon black. The polyethylene-based polymer blend comprises a mixture of an ethylene/(alkenyl-functional hydrolyzable silane)/(optional olefinic hydrocarbon) copolymer and an ethylene/unsaturated carboxylic ester copolymer that is free of moisture curable groups. We also discovered methods of making and using same, a moisture-cured semiconductive product made therefrom, and articles containing or made from same.

公开(公告)号：US09963648B2

公开(公告)日：2018-05-08

申请号：US14901059

申请日：2014-06-18

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Paul R. Elowe ,  Wanglin Yu ,  Brad C. Bailey ,  Daniel J. Arriola ,  Jerzy J. Klosin ,  Suh Joon Han ,  Zenon Lysenko ,  Martin R. Greaves

IPC: C10G69/12 ,  B01J31/22 ,  C10M107/04 ,  C10G50/02 ,  C10M177/00 ,  C10M107/08 ,  C10M107/10 ,  C10M105/04

CPC classification number: C10G69/126 ,  B01J31/2239 ,  B01J2231/20 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C10G50/02 ,  C10G2300/1088 ,  C10G2400/10 ,  C10M105/04 ,  C10M107/04 ,  C10M107/08 ,  C10M107/10 ,  C10M177/00 ,  C10M2205/0225 ,  C10M2205/0265 ,  C10M2205/0285 ,  C10N2220/022 ,  C10N2220/028 ,  C10N2230/02 ,  C10N2230/08 ,  C10N2260/02

Abstract: Processes to prepare branched polyolefins for lubricant applications comprise combining at least one olefin and a coordination-insertion catalyst under conditions such that at least one oligomer product is formed. Low molecular weight by-products are fractionated out and the oligomer product is converted to a saturated hydrocarbon via hydrogenation.

公开(公告)号：US09777205B2

公开(公告)日：2017-10-03

申请号：US15501878

申请日：2014-09-22

Applicant: Dow Global Technologies LLC

Inventor： Yunfeng Yang ,  Hongyu Chen ,  Brad C. Bailey ,  Mohamed Esseghir ,  Suh Joon Han

IPC: C10M125/04 ,  C07F15/00 ,  C07F7/00 ,  C07F7/28 ,  C09K5/10 ,  C08K3/22 ,  C08K3/28

CPC classification number: C09K5/10 ,  B01J31/22 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/65912 ,  C08F110/02 ,  C08K3/22 ,  C08K3/28 ,  C08K2003/2227 ,  C08K2003/2296 ,  C08K2003/282 ,  C10M107/06 ,  C10M169/02 ,  C10M2201/0416 ,  C10M2201/0616 ,  C10M2201/0626 ,  C10M2201/0656 ,  C10M2205/0225 ,  C10M2229/041 ,  C10M2229/042 ,  C10M2229/045 ,  C10N2220/022 ,  C10N2220/028 ,  C10N2230/08 ,  C08F2500/10 ,  C08F2500/02 ,  C08F10/02 ,  C08F4/64193 ,  C08F210/16 ,  C08F210/06 ,  C08F2500/17 ,  C08L23/14 ,  C08L23/06 ,  C10M2205/0245 ,  C10M2205/0285

Abstract: Disclosed is an effective thermal grease comprising a hyperbranched olefinic fluid and a thermally conductive filler. Property-modifying additives and fillers may also be included. The hyperbranched olefinic fluid is selected to have an average of at least 1.5 methine carbons per oligomer molecule and at least 40 methine carbons per one thousand total carbons. The thermal grease exhibits a flash point of 180° C. or higher, a pour point of 0° C. or lower, and a kinematic viscosity at 40° C. of no more than 200 cSt (0.0002 m 2/s). The composition may offer improved thermal conductivity, reduced tendency to migrate, and lower cost when compared with many other thermal greases, including silicone-based thermal greases.

公开(公告)号：US09607732B2

公开(公告)日：2017-03-28

申请号：US14397385

申请日：2013-05-15

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Suh Joon Han ,  Suzanne M. Guerra ,  Jeffrey M. Cogen ,  Gary R. Marchand ,  Jerker B. L. Kjellqvist

IPC: H01B7/00 ,  H01B3/44 ,  H01B7/28

CPC classification number: H01B3/441 ,  H01B7/2813

Abstract: Coated conductors including a conductive core at least partially surrounded by a polymeric coating. The polymeric coating has an α-olefin based polymer and an α-olefin based block composite. The α-olefin block composite has block copolymers having hard segments and soft segments.

公开(公告)号：US20140330056A1

公开(公告)日：2014-11-06

申请号：US14362420

申请日：2012-11-28

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Jerzy Klosin ,  Zenon Lysenko ,  Suh Joon Han

IPC: H01B3/22

CPC classification number: H01B3/22 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F4/64193 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/02 ,  C08F110/14

Abstract: The present invention generally relates to a dielectric composition which is a poly-α-olefin or poly(co-ethylene-α-ol-efin) having a backbone weight average molecular weight less than 10,000 daltons. The dielectric composition uses a metal-ligand complex as a precatalyst and exhibits a hyperbranched structure that enables low viscosity, and therefore good flow characteristics, combined with high fire point due to ability to increase molecular weight via branching rather than backbone growth. Other desirable properties include lowered pour point due to crystallization disruption, and desirable thermal oxidative stability.

Abstract translation: 本发明一般涉及具有骨架重均分子量小于10,000道尔顿的聚-α-烯烃或聚（共 - 乙烯-α-醇 - 烯烃）的电介质组合物。 电介质组合物使用金属 - 配体络合物作为预催化剂，并且表现出超支化结构，其能够通过分支而不是主链生长增加分子量的能力而实现低粘度，因此具有良好的流动特性以及高火点。 其它所需的性质包括由于结晶破坏引起的降低的倾点和所需的热氧化稳定性。

公开(公告)号：US20140252281A1

公开(公告)日：2014-09-11

申请号：US14348360

申请日：2012-09-26

Applicant: Dow Global Technologies LLC

Inventor： Suh Joon Han ,  Dirk B. Zinkweg ,  Zenon Lysenko

IPC: H01B3/24 ,  H01B3/20

CPC classification number: H01B3/24 ,  H01B3/20

Abstract: A dielectric fluid composition for electrical apparatus comprises a functionalized methyl-12-carboxy methyl stearate having desirable properties including a pour point less than −30° C. and a fire point greater than 250° C. It may be prepared by a process wherein methyl-12-hydroxy methyl stearate is transesterified by reaction with a C3-C20 alcohol to form the hydroxy methyl ester, followed by reaction with a linear or branched C4-C20 carboxylic acid selected from free acid chlorides, fatty acids, carboxylic acid anhydrides, and combinations thereof. The second step serves to end-cap the hydroxyl groups, thereby producing the functionalized methyl-12-carboxy methyl stearate compound that exhibits improved thermoxidative stability and low temperature flowability, as well as increased fire point.

Abstract translation: 用于电气设备的介电流体组合物包括官能化的甲基-12-羧甲基硬脂酸酯，其具有包括倾点小于-30℃和高于250℃的点的所需性质。其可以通过以下方法制备：其中甲基 -12-羟基甲基硬脂酸酯通过与C 3 -C 20醇反应来酯交换以形成羟甲基酯，然后与选自游离酰氯，脂肪酸，羧酸酐的直链或支链C 4 -C 20羧酸反应，和 其组合。 第二步用于封端羟基，从而产生表现出改善的热氧稳定性和低温流动性以及增加的火点的官能化甲基-12-羧甲基硬脂酸酯化合物。

公开(公告)号：US20240071645A1

公开(公告)日：2024-02-29

申请号：US18259862

申请日：2022-03-23

Applicant: Dow Global Technologies LLC

Inventor： Paul J. Caronia ,  Jeffrey M. Cogen ,  Bharat I. Chaudhary ,  Timothy J. Person ,  Suh Joon Han

IPC: H01B3/44 ,  C08K3/04 ,  C08L23/08 ,  C09D123/08 ,  H01B13/14

CPC classification number: H01B3/441 ,  C08K3/04 ,  C08L23/0892 ,  C09D123/0892 ,  H01B13/14 ,  C08K2201/006 ,  C08L2310/00

Abstract: A moisture-curable semiconductive formulation consisting essentially of a mixture of an ethylene/(alkenyl-functional hydrolyzable silane)/(optional olefinic hydrocarbon) copolymer and a conventional carbon black. Also discovered methods of making and using same, a moisture-cured semiconductive product made therefrom, and articles containing or made from same.

公开(公告)号：US09416089B2

公开(公告)日：2016-08-16

申请号：US14344937

申请日：2012-09-26

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Suh Joon Han ,  Dirk B. Zinkweg ,  Zenon Lysenko

IPC: C09K5/00 ,  C07C59/01 ,  H01B3/20 ,  C07C51/377 ,  H01B3/24

CPC classification number: H01B3/20 ,  C07C51/367 ,  C07C51/377 ,  C07C59/01 ,  H01B3/24

Abstract: A dielectric fluid composition for electrical apparatus comprises a functionalized 12-hydroxy stearic acid having desirable properties including a pour point less than −30° C. and a fire point greater than 250° C. It may be prepared by a process wherein 12-hydroxy methyl stearate is transesterified by reaction with a C3-C20 alcohol to form an alkyl-12-hydroxy stearate, followed by esterification thereof with a linear or branched C4-C20 carboxylic acid. This acid may be a free acid chloride, a fatty acid, a carboxylic acid anhydride, or combination thereof. The resulting functionalized 12-hydroxy stearic acid exhibits improved thermoxidative capability, low temperature flowability, and increased fire point.

Abstract translation: 用于电气设备的电介质流体组合物包括具有所需性质的功能化的12-羟基硬脂酸，其包括倾点小于-30℃和大于250℃的点。其可以通过以下方法制备：其中将12-羟基 甲基硬脂酸酯通过与C 3 -C 20醇反应以酯交换形成烷基-12-羟基硬脂酸酯，然后用直链或支链C 4 -C 20羧酸酯化。 该酸可以是游离酰氯，脂肪酸，羧酸酐或其组合。 得到的功能化的12-羟基硬脂酸表现出改善的热氧化能力，低温流动性和增加的火点。