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公开(公告)号：US4516566A
公开(公告)日：1985-05-14
申请号：US454655
申请日：1982-12-30
申请人： Chien C. Chao , John D. Sherman
发明人： Chien C. Chao , John D. Sherman
CPC分类号： C13K13/007
摘要： A process for the separation of arabinose is disclosed which comprises the selective adsorption of same on BaX zeolitic molecular sieves. The process is especially useful for separating arabinose from mixtures of sugars containing arabinose.
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公开(公告)号：US4344851A
公开(公告)日：1982-08-17
申请号：US225528
申请日：1981-01-16
申请人： John D. Sherman , Ronald J. Ross
发明人： John D. Sherman , Ronald J. Ross
CPC分类号： B01J39/02 , B01J20/186
摘要： Ammonium ions are selectively removed from aqueous solutions containing calcium cations by cation exchange with natural or synthetic zeolites of the phillipsitegismondite type, which possess unusual capacity and selectivity for the ammonium ion.
摘要翻译： 通过与具有异常容量和对铵离子的选择性的天然或合成的金刚石皂石型沸石的阳离子交换，从含有钙阳离子的水溶液中选择性地除去铵离子。
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13.发明授权Bulk cyclohexanol/cyclohexanone separation by selective adsorption on zeolitic molecular sieves 失效通过选择性吸附在沸石分子筛上的大量环己醇/环己酮分离
公开(公告)号：US4283560A
公开(公告)日：1981-08-11
申请号：US098714
申请日：1979-11-30
申请人： Chien C. Chao , John D. Sherman
发明人： Chien C. Chao , John D. Sherman
IPC分类号： C07C29/76 , C07C29/88 , C07C45/79 , C07C49/303
CPC分类号： C07C29/88 , C07C29/76 , C07C45/79 , C07C2101/14
摘要： Cyclohexanone is selectively adsorbed from admixture with cyclohexanol using specific cationic forms of zeolite X and zeolite Y. The process utilizes the interaction of the electrostatic field of the zeolite with the slightly greater polarity of the cyclohexanone to enhance the adsorptive strength difference between the competing adsorbates.
摘要翻译： 使用特定阳离子形式的沸石X和沸石Y选择性地吸附环己酮与环己醇的混合物。该方法利用沸石的静电场与环己酮的极性极性的相互作用，以增强竞争性吸附物之间的吸附强度差异。
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公开(公告)号：US5413625A
公开(公告)日：1995-05-09
申请号：US992187
申请日：1992-12-17
IPC分类号： B01D53/047 , B01J20/18 , C01B13/02 , C01B21/04 , B01D53/04
CPC分类号： B01D53/02 , B01J20/186 , C01B13/027 , C01B21/0466 , B01D2253/108 , B01D2253/1085 , B01D2256/12 , B01D2257/102 , B01D53/047 , C01B2210/0046 , Y10S95/902
摘要： Lithium/alkaline earth metal X zeolites in which the lithium:alkaline earth metal equivalent ratio is from about 95:5 to about 50:50 and lithium/alkaline earth metal A zeolites in which the lithium:alkaline earth metal equivalent ratio is from about 10:90 to about 70:30 are useful for separating oxygen and nitrogen from mixtures because they combine high adsorption capacity with high thermal stability.
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公开(公告)号：US4663052A
公开(公告)日：1987-05-05
申请号：US808173
申请日：1985-12-12
CPC分类号： B01J20/186
摘要： A process for the removal of water and other polar compounds from an acidic stream containing water and at least one acid compound comprising contacting the acidic stream with an adsorbent comprising a chabazite-type zeolite wherein said adsorbent has a M.sub.2 O/Al.sub.2 O.sub.3 mole oxide ratio of at least 0.5 where "M" is at least one cation selected from the group consisting of potassium, rubidium and cesium.
摘要翻译： 一种从含有水和至少一种酸化合物的酸性流中除去水和其它极性化合物的方法，包括使酸性流与包含菱沸石型沸石的吸附剂接触，其中所述吸附剂具有M 2 O / Al 2 O 3摩尔氧化物比为 至少0.5，其中“M”是选自钾，铷和铯中的至少一种阳离子。
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16.发明授权
公开(公告)号：US4471114A
公开(公告)日：1984-09-11
申请号：US454646
申请日：1982-12-30
申请人： John D. Sherman , Chien C. Chao
发明人： John D. Sherman , Chien C. Chao
CPC分类号： C13K13/007
摘要： A process for the separation of mannose is disclosed which comprises the selective adsorption of same on certain types of zeolitic molecular sieves. The process is especially useful for separating mannose from glucose epimerization product or plant tissue hydrolyzate, using zeolites selected from the group consisting of BaX, BaY, SrY, NaY and CaY.
摘要翻译： 公开了一种用于分离甘露糖的方法，其包括在某些类型的沸石分子筛上选择性吸附它们。 该方法特别适用于使用选自BaX，BaY，SrY，NaY和CaY的沸石从葡萄糖差向异构化产物或植物组织水解产物中分离甘露糖。
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17.发明授权Bulk separation of polyhydric alcohols by selective adsorption on zeolitic molecular sieves 失效通过选择性吸附在沸石分子筛上大量分离多元醇
公开(公告)号：US4456774A
公开(公告)日：1984-06-26
申请号：US540915
申请日：1983-10-13
申请人： John D. Sherman , Chien C. Chao
发明人： John D. Sherman , Chien C. Chao
摘要： Mannitol is separated from admixture with galactitol and/or from sorbitol by selective adsorption on cationic forms of zeolite X and zeolite Y.
摘要翻译： 通过在阳离子形式的沸石X和沸石Y上选择性吸附，将甘露糖与半乳糖醇和/或从山梨糖醇混合物分离。
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公开(公告)号：US4123390A
公开(公告)日：1978-10-31
申请号：US742062
申请日：1976-11-15
申请人： John D. Sherman , Ronald J. Ross
发明人： John D. Sherman , Ronald J. Ross
IPC分类号： A23L2/00 , A23L2/40 , B01F1/00 , B01J20/18 , C01B33/38 , C01B33/40 , C01B39/00 , C01B39/14 , C01B39/22 , C01B39/24 , C01B39/26 , C01B39/28 , C01B39/30 , C01B39/34 , C01B39/36 , C01B39/38 , C01B39/42 , B01J29/06 , B01J35/00
CPC分类号： B01J20/183 , A23L2/40
摘要： Zeolite agglomerates in which the distribution of capillary pores is modified to enhance the number of pores in the diameter range of from 2 to 100 microns are found to have a greatly improved ability to release adsorbed CO.sub.2 into liquid media in a manner which favors both a high rate of desorption and a high degree of solubility of the desorbate gases in the liquid media. The agglomerates are particularly useful for the carbonation of an aqueous medium.
摘要翻译： 发现其中毛细孔分布被修饰以增加直径范围为2至100微米的孔数的沸石附聚物具有大大改进的能力，其以有利于高的方式释放吸附的CO 2到液体介质中 溶解速率和解吸附气体在液体介质中的高溶解度。 附聚物特别可用于水性介质的碳酸化。
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19.发明授权
公开(公告)号：US5962735A
公开(公告)日：1999-10-05
申请号：US35798
申请日：1998-03-06
申请人： Santi Kulprathipanja , Benjamin C. Spehlmann , Richard R. Willis , John D. Sherman , William A. Leet
发明人： Santi Kulprathipanja , Benjamin C. Spehlmann , Richard R. Willis , John D. Sherman , William A. Leet
摘要： A solution is provided to the long sought inorganic alternative to resin based adsorbents for iodide clean-up service for corrosive organic liquid. The solution involves the use of a solid inorganic adsorbent comprising a combination of a silica-rich zeolite molecular sieve, which has been cation-exchanged with an iodide-reactive metal selected from silver, mercury, copper, lead, thallium, palladium or mixtures thereof, with a substantially insoluble, porous refractory inorganic oxide binder. Reactivation and regeneration technique for the spent inorganic adsorbent are also covered.
摘要翻译： 提供了一种解决方案，用于长期寻求无机替代树脂基吸附剂，用于腐蚀性有机液体的碘化物清除服务。 该溶液包括使用固体无机吸附剂，其包含与选自银，汞，铜，铅，铊，钯或其混合物的碘化物反应性金属进行阳离子交换的富含二氧化硅的沸石分子筛的组合 具有基本上不溶的多孔耐火无机氧化物粘合剂。 还讨论了废无机吸附剂的再活化和再生技术。
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20.发明授权Mixed ion-exchanged zeolites and processes for the use thereof in gas separations 失效混合离子交换沸石及其在气体分离中的应用方法
公开(公告)号：US5174979A
公开(公告)日：1992-12-29
申请号：US418428
申请日：1989-10-06
IPC分类号： B01D53/047 , B01J20/18 , C01B13/02 , C01B21/04
CPC分类号： B01D53/02 , B01J20/186 , C01B13/027 , C01B21/0466 , B01D2253/108 , B01D2253/1085 , B01D2256/12 , B01D2257/102 , B01D53/047 , C01B2210/0046 , Y10S95/902
摘要： Lithium/alkaline earth metal X zeolites in which the lithium:alkaline earth metal equivalent ratio is from about 95:5 to about 50:50 and lithium/alkaline earth metal A zeolites in which the lithium:alkaline earth metal equivalent ratio is from about 10:90 to about 70:30 are useful for separating oxygen and nitrogen from mixtures because they combine high adsorption capacity with high thermal stability.
摘要翻译： 锂/碱土金属X沸石，其中锂：碱土金属当量比为约95:5至约50:50，锂/碱土金属A沸石，其中锂：碱土金属当量比为约10 ：90至70:30可用于从混合物中分离氧和氮，因为它们具有高吸附能力和高热稳定性。
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