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公开(公告)号：US20150190790A1
公开(公告)日：2015-07-09
申请号：US14417404
申请日：2013-08-21
Applicant: Dow Global Technologies LLC
Inventor： David G. Barton , Adam Chojecki , Paul R. Elowe , Beata A. Kilos
CPC classification number: B01J27/10 , B01J23/10 , B01J37/0201 , B01J37/031 , B01J37/08 , C01B11/00 , C01F17/0043 , C07C41/09 , C09K5/00 , C07C43/275
Abstract: Provided is a process for preparing a diaryl ether compound through the dehydration of an aromatic alcohol compound in the presence of a dehydration catalyst. The dehydration catalyst is an oxide of a medium rare earth element, wherein the medium rare earth element is samarium, europium, gadolinium, or mixtures thereof.
Abstract translation: 提供了通过在脱水催化剂的存在下通过芳族醇化合物的脱水来制备二芳基醚化合物的方法。 脱水催化剂是中等稀土元素的氧化物，其中中等稀土元素是钐，铕，钆或其混合物。
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公开(公告)号：US20240351004A1
公开(公告)日：2024-10-24
申请号：US18683045
申请日：2022-08-17
Applicant: Dow Global Technologies LLC
Inventor： Glenn Pollefeyt , Kevin Blann , Daniela Ferrari , Alexey Kirilin , Adam Chojecki , Cheng L. Chung , Andrzej Malek
CPC classification number: B01J23/31 , B01J23/002 , B01J37/0018 , B01J37/0036 , B01J37/009 , B01J37/04 , B01J37/10 , C07C5/322 , B01J2523/54 , B01J2523/55 , B01J2523/56 , B01J2523/68 , C07C2523/20 , C07C2523/22 , C07C2523/31
Abstract: An oxidative dehydrogenation catalyst having: a structure having a formula MovVwNbyBizOx, where v is 1, w is from 0.1 to 0.5, y is from 0.001 to 0.3, z is from 0.01 to 0.3, and x is the oxygen content required to charge-balance the structure. The oxidative dehydrogenation catalyst has a Pba2-32 space group, characterized by reflections determined with Cu—Kα X-ray diffraction (XRD) as follows.
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公开(公告)号：US11986799B2
公开(公告)日：2024-05-21
申请号：US17417846
申请日：2019-12-16
Applicant: Dow Global Technologies LLC
Inventor： Adam Chojecki , Alexey Kirilin , Andrzej Malek , Joseph F. DeWilde , Vera P. Santos Castro , David F. Yancey , Kyle C. Andrews
CPC classification number: B01J23/08 , B01J23/002 , B01J29/85 , B01J35/19 , B01J35/612 , B01J35/613 , B01J35/615 , B01J37/0201 , B01J37/04 , C07C1/043 , C07C2521/06 , C07C2523/08 , C07C2529/85
Abstract: A process for preparing C2 to C4 olefins includes introducing a feed stream comprising hydrogen gas and a carbon-containing gas selected from carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor. The feed stream is converted into a product stream including C2 to C4 olefins in the reaction zone in the presence of the hybrid catalyst. The hybrid catalyst includes a metal oxide catalyst component comprising gallium oxide and phase pure zirconia, and a microporous catalyst component.
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14.发明授权公开(公告)号：US11884605B2
公开(公告)日：2024-01-30
申请号：US17253925
申请日：2019-06-20
Applicant: Dow Global Technologies LLC
Inventor： Glenn Pollefeyt , Davy L. S. Nieskens , Vera P. Santos Castro , Alexey Kirilin , Adam Chojecki , David Yancey , Andrzej Malek
CPC classification number: C07C1/043 , B01J21/04 , B01J23/002 , B01J23/26 , B01J29/85 , B01J35/0006 , B01J37/088 , C10G2/334 , C07C2521/02 , C07C2523/06 , C07C2523/08 , C07C2523/26 , C07C2529/85
Abstract: A hybrid catalyst including a metal oxide catalyst component comprising chromium, zinc, and at least one additional metal selected from the group consisting of aluminum and gallium, and a microporous catalyst component that is a molecular sieve having 8-MR pore openings. The metal oxide catalyst component includes anatomic ratio of chromium:zinc (Cr:Zn) from 0.35 to 1.00, and the at least one additional metal is present in an amount from 25.0 at % to 40.0 at %. A process for preparing C2 and C3 olefins comprising: a) introducing a feed stream comprising hydrogen gas and a carbon-containing gas selected from the group consisting of carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor; and b) converting the feed stream into a product stream comprising C2 and C3 olefins in the reaction zone in the presence of said hybrid catalyst.
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15.发明授权公开(公告)号：US09919981B2
公开(公告)日：2018-03-20
申请号：US15324869
申请日：2015-07-08
Applicant: Dow Global Technologies LLC
Inventor： Adam Chojecki , Davy Nieskens , Thomas Davidian , Peter E. Groenendijk , Matthijs Ruitenbeek , Barry B. Fish , Max M. Tirtowidjojo , Garmt R. Meima
IPC: C07C1/04 , C07C1/12 , B01J37/03 , B01J37/04 , B01J35/02 , B01J35/00 , B01J23/26 , B01J29/85 , B01J23/80
CPC classification number: C07C1/043 , B01J23/26 , B01J23/80 , B01J29/005 , B01J29/85 , B01J35/0006 , B01J35/026 , B01J37/031 , B01J37/04 , C07C1/12 , C07C2521/04 , C07C2523/06 , C07C2523/26 , C07C2523/72 , C07C2523/80 , C07C2529/70 , C07C2529/83 , C07C2529/85 , C07C9/06 , C07C9/08
Abstract: A feedstream comprising hydrogen and a gas selected from carbon monoxide, carbon dioxide, or a combination thereof is converted to a product mixture containing a combination of saturated and unsaturated two carbon atom and three carbon atom hydrocarbons via contact with a mixed catalyst comprising a mixed metal oxide catalyst selected from a copper oxide, copper oxide/zinc oxide, copper oxide/alumina, copper oxide/zinc oxide/alumina catalyst, a zinc oxide/chromium oxide catalyst, or a combination thereof, in admixture with a molecular sieve catalyst having a CHA, AEI, AEL, AFI, BEA, or DDR framework type, or a combination of such molecular sieves. Exemplary molecular sieve catalysts include SAPO-34, SAPO-18, SAPO-5, and Beta. Advantages include reduced production of C1 hydrocarbons, C4 and higher hydrocarbons, or both; long catalyst lifetimes; desirable conversions; and desirable proportions of C2 and C3 paraffins.
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Patent Agency Ranking
16.发明申请CATALYST COMPOSITION FOR THE SELECTIVE CONVERSION OF SYNTHESIS GAS TO LIGHT OLEFINS 有权合成气选择性转化为轻油的催化剂组合物公开(公告)号：US20160107144A1
公开(公告)日：2016-04-21
申请号：US14889483
申请日：2014-06-25
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Thomas Davidian , Matthijs Ruitenbeek , Adam Chojecki , Adrianus Koeken
IPC: B01J23/10 , B01J23/745 , B01J23/78 , C07C1/04
CPC classification number: B01J23/10 , B01J21/066 , B01J23/745 , B01J23/78 , B01J23/83 , B01J27/22 , B01J37/0205 , B01J37/084 , C07C1/044 , C07C2521/06 , C07C2523/04 , C07C2523/10 , C07C2523/745 , C07C2523/78 , C07C2523/83 , C07C2527/224 , Y02P20/52 , C07C11/04 , C07C11/06
Abstract: A catalyst composition and process for preparing it and for using it to enhance the selectivity to light (C2 to C3) olefins in a Fischer-Tropsch conversion of synthesis gas is disclosed. The catalyst composition is an iron-based catalyst on an yttria/zirconia support. In a Fischer-Tropsch reaction the selectivity to ethylene may be enhanced by at least 20 mole percent and to propylene by at least 4 mole percent, in comparison with use of an otherwise identical catalyst that is free of yttria, in an otherwise identical Fischer-Tropsch reaction.
Abstract translation: 公开了一种催化剂组合物及其制备方法和用于在合成气的费 - 托转化中提高对光（C 2至C 3）烯烃的选择性的方法。 催化剂组合物是氧化钇/氧化锆载体上的铁基催化剂。 在费 - 托反应中，与使用另外相同的不含氧化钇的催化剂相比，在其它相同的费 - 托反应中，对乙烯的选择性可以提高至少20摩尔％，丙烯至少为4摩尔％ 托反应。
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公开(公告)号：US20150299077A1
公开(公告)日：2015-10-22
申请号：US14385917
申请日：2013-05-29
Applicant: Dow Global Technologies LLC
Inventor： David G. Barton , Adam Chojecki , Paul R. Elowe , Beata A. Kilos
CPC classification number: C07C41/09 , B01J21/066 , B01J27/10 , B01J37/0201 , B01J37/031 , C09K5/00 , C07C43/275
Abstract: Provided is a process for preparing a diaryl ether compound through the dehydration of an aromatic alcohol compound in the presence of a dehydration catalyst. The dehydration catalyst is an oxide of a heavy rare earth element, wherein the heavy rare earth element is terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, or mixtures thereof.
Abstract translation: 提供了通过在脱水催化剂的存在下通过芳族醇化合物的脱水来制备二芳基醚化合物的方法。 脱水催化剂是重稀土元素的氧化物，其中重稀土元素是铽，镝，钬，铒，ium，镱，镥或其混合物。
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公开(公告)号：US20140306145A1
公开(公告)日：2014-10-16
申请号：US14359527
申请日：2012-11-20
Applicant: Dow Global Technologies LLC
Inventor： Paul R. Elowe , David G. Barton , Adam Chojecki , Joost Depicker
CPC classification number: C07C41/09 , C09K5/00 , C09K5/10 , C07C43/275
Abstract: Provided is a method for preparing a diaryl ether compound through the dehydration of an aromatic alcohol compound in the presence of a dehydration catalyst. The dehydration catalyst comprises an oxide of yttrium.
Abstract translation: 提供了通过在脱水催化剂存在下使芳族醇化合物脱水来制备二芳基醚化合物的方法。 脱水催化剂包含钇氧化物。
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公开(公告)号：US12030036B2
公开(公告)日：2024-07-09
申请号：US17417955
申请日：2019-12-16
Applicant: Dow Global Technologies LLC
Inventor： Alexey Kirilin , Adam Chojecki , Glenn Pollefeyt , Davy L. S. Nieskens , Kyle C. Andrews , Vera P. Santos Castro , Joseph F. DeWilde , David F. Yancey , Andrzej Malek
CPC classification number: B01J23/08 , B01J21/063 , B01J21/066 , B01J23/62 , B01J23/825 , B01J29/85 , B01J35/19 , C10G2/33 , C10G2/333 , C10G2/334
Abstract: A method for preparing C2 to C5 paraffins includes introducing a feed stream including hydrogen gas and a carbon-containing gas selected from carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor. Converting the feed stream into a product stream including C2 to C5 paraffins in the presence of a hybrid catalyst. The hybrid catalyst includes a microporous catalyst component; and a metal oxide catalyst component selected from (A) a bulk material consisting of gallium oxide, (B) gallium oxide present on a titanium dioxide support material, and (C) a mixture of gallium oxide and at least one promoter present on a support material selected from Group 4 of the IUPAC periodic table of elements.
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公开(公告)号：US20230234899A1
公开(公告)日：2023-07-27
申请号：US18003800
申请日：2021-06-18
Applicant: Dow Global Technologies LLC
Inventor： Alexey Kirilin , Dean M. Millar , Adam Chojecki , Joseph F. DeWilde , Glenn Pollefeyt , Davy L.S. Nieskens , Andrzej Malek
CPC classification number: C07C1/12 , B01J23/002 , B01J23/08 , B01J21/066 , B01J29/50 , B01J29/60 , B01J35/1057 , C07C2529/50 , C07C2529/60 , C07C2521/06 , C07C2523/08
Abstract: A process for preparing C2 to C3 hydrocarbons may include introducing a feed stream including hydrogen gas and a carbon-containing gas comprising carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor, and converting the feed stream into a product stream comprising C2 to C3 hydrocarbons in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst may include a metal oxide catalyst component and a microporous catalyst component comprising 8-MR pore openings less than or equal to 5.1 A and a cage defining ring size less than or equal to 7.45 A, where a C2/C3 carbon molar ratio of the product stream is greater than or equal to 0.7.
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