公开(公告)号：US20130324713A1

公开(公告)日：2013-12-05

申请号：US13837694

申请日：2013-03-15

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： David William Norman ,  Elaine Beatrice Mackenzie

IPC: C07C45/50 ,  B01J31/24

CPC classification number: C07C45/505 ,  B01J31/183 ,  B01J31/189 ,  B01J31/2404 ,  B01J31/2447 ,  B01J2231/321 ,  B01J2531/0205 ,  B01J2531/025 ,  B01J2531/0291 ,  B01J2531/22 ,  B01J2531/822 ,  C07C45/50 ,  C07C47/02

Abstract: Industrially relevant product selectivities and reaction rates are obtained from rhodium catalyzed hydroformylation of propylene via the use of a novel induction period in which the supramolecular ligand assembly, the rhodium precatalyst and an initial substrate are allowed to form a hydroformylation catalyst that is more selective toward branched aldehydes. Upon heating this incubated mixture and addition of propylene, iso-butyraldehyde is obtained in higher concentrations and rates that are otherwise unattainable.

Abstract translation: 通过使用新的诱导期，从铑催化的丙烯加氢甲酰化获得工业相关的产物选择性和反应速率，其中超分子配体组合，铑预催化剂和初始底物被允许形成对分支更具选择性的加氢甲酰化催化剂 醛。 加热该温育混合物并加入丙烯后，以更高的浓度和速率获得异丁醛，否则无法实现。

公开(公告)号：US12006376B2

公开(公告)日：2024-06-11

申请号：US18190415

申请日：2023-03-27

Applicant: Eastman Chemical Company

Inventor： Matthew Allen Boone ,  Christopher Harlan Burk ,  Peter Borden Mackenzie ,  Jennifer A. Fish ,  Eduardo Gallas Cervo ,  Elaine Beatrice Mackenzie ,  Robert Joseph Maleski ,  Wesley Wayne McConnell ,  David William Norman ,  Tabatha Stearns ,  Bin Wang

IPC: C08B3/16 ,  B32B7/12 ,  B32B23/08 ,  B32B27/06 ,  B32B27/08 ,  B32B27/18 ,  B32B27/22 ,  B32B27/24 ,  B32B27/28 ,  B32B27/32 ,  B32B27/36 ,  C08L1/14 ,  G02B5/30 ,  G02F1/13363 ,  H10K50/84 ,  H10K50/86 ,  C08L1/08 ,  C08L1/10

CPC classification number: C08B3/16 ,  B32B7/12 ,  B32B23/08 ,  B32B27/06 ,  B32B27/08 ,  B32B27/18 ,  B32B27/22 ,  B32B27/24 ,  B32B27/281 ,  B32B27/325 ,  B32B27/36 ,  B32B27/365 ,  C08L1/14 ,  G02B5/3033 ,  G02B5/305 ,  G02B5/3083 ,  G02F1/13363 ,  H10K50/846 ,  H10K50/86 ,  B32B2307/40 ,  B32B2307/516 ,  B32B2307/518 ,  B32B2307/546 ,  B32B2307/732 ,  B32B2309/105 ,  B32B2457/202 ,  B32B2457/206 ,  C08L1/08 ,  C08L1/10 ,  C09K2323/03 ,  C09K2323/035 ,  G02F1/133638 ,  G02F2413/13

Abstract: Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.

公开(公告)号：US10759872B2

公开(公告)日：2020-09-01

申请号：US15482910

申请日：2017-04-10

Applicant: Eastman Chemical Company

Inventor： Matthew Allen Boone ,  Christopher Harlan Burk ,  Peter Borden Mackenzie ,  Jennifer A. Fish ,  Eduardo Gallas Cervo ,  Elaine Beatrice Mackenzie ,  Robert Joseph Maleski ,  Wesley McConnell ,  David William Norman ,  Tabatha Stearns ,  Bin Wang

IPC: C08B3/16 ,  B32B27/24 ,  B32B27/08 ,  B32B27/36 ,  B32B7/12 ,  B32B27/28 ,  C08L1/14 ,  B32B23/08 ,  B32B27/32 ,  B32B27/18 ,  G02B5/30 ,  B32B27/22 ,  B32B27/06 ,  G02F1/13363 ,  H01L51/52 ,  C08L1/08 ,  C08L1/10

Abstract: Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.

公开(公告)号：US09493390B2

公开(公告)日：2016-11-15

申请号：US14626111

申请日：2015-02-19

Applicant: Eastman Chemical Company

Inventor： Venkata Bharat Ram Boppana ,  David William Norman ,  Melissa Page Steffey

IPC: C07C51/377 ,  B01J27/198 ,  B01J37/03 ,  B01J21/06 ,  B01J35/00 ,  C07C51/09

CPC classification number: C07C51/377 ,  B01J21/063 ,  B01J27/198 ,  B01J35/002 ,  B01J37/031 ,  B01J2523/00 ,  C07C51/09 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55 ,  C07C57/04

Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed. Additionally, the catalyst composition is catalytically active towards the formation of acrylic acid from methylene diacetate and methacrylic acid from methylene dipropionate; both reactions are carried out with high space time yields.

公开(公告)号：US20160185701A1

公开(公告)日：2016-06-30

申请号：US14585915

申请日：2014-12-30

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： Andrew James Vetter ,  Jonathan Michael Penney ,  David William Norman

IPC: C07C45/49 ,  B01J31/24

CPC classification number: C07C45/49 ,  B01J31/2409 ,  B01J2231/34 ,  B01J2531/845 ,  C07C29/16 ,  C07C45/50 ,  C07C51/12 ,  C07C47/06 ,  C07C53/08 ,  C07C31/08

Abstract: Disclosed is a process for the reductive carbonylation of a low molecular weight alcohol to produce the homologous aldehyde and/or alcohol. The process includes conducting the reaction to produce the aldehyde in the presence of a catalyst complex composed of cobalt, an onium cation and iodide in a ratio of 1:2:4 with a phosphine ligand. A ruthenium co-catalyst is used in the production of the homologous alcohol. The reductive carbonylation reaction does not require an additional iodide promoter and produces a crude reductive carbonylation product substantially free of methyl iodide.

Abstract translation: 公开了一种用于还原性羰基化低分子量醇以产生同源醛和/或醇的方法。 该方法包括在由钴，鎓阳离子和碘化物以1:2:4的比例组成的催化剂络合物与膦配体的存在下进行反应生成醛。 钌助催化剂用于同源醇的生产。 还原羰基化反应不需要另外的碘化物促进剂并产生基本上不含甲基碘的粗还原羰基化产物。

公开(公告)号：US09365479B1

公开(公告)日：2016-06-14

申请号：US14585884

申请日：2014-12-30

Applicant: Eastman Chemical Company

Inventor： Jonathan Michael Penney ,  David William Norman ,  Andrew James Vetter

IPC: C07C45/49 ,  C07C51/12 ,  C07C29/157 ,  B01J27/128 ,  B01J31/22 ,  B01J31/24

CPC classification number: C07C45/49 ,  B01J27/128 ,  B01J31/0239 ,  B01J31/0268 ,  B01J31/20 ,  B01J2231/321 ,  B01J2531/821 ,  C07C29/32 ,  C07C51/12 ,  C07C31/08 ,  C07C47/06 ,  C07C53/08

Abstract: Disclosed is a process for the reductive carbonylation of a low molecular weight alcohol to produce the homologous aldehyde and/or alcohol. The process includes conducting the reaction to produce the aldehyde in the presence of a single component catalyst complex composed of cobalt, an onium cation and iodide in a ratio of 1:2:4 without additional promoters. A ruthenium co-catalyst is used in the production of the homologous alcohol. The reductive carbonylation reaction does not require an additional iodide promoter and produces a crude reductive carbonylation product substantially free of methyl iodide.

Abstract translation: 公开了一种用于还原性羰基化低分子量醇以产生同源醛和/或醇的方法。 该方法包括进行反应以在由钴，鎓阳离子和碘化物组成的单组分催化剂络合物的存在下以1:2:4的比例进行反应，而无需另外的助催化剂。 钌助催化剂用于同源醇的生产。 还原羰基化反应不需要另外的碘化物促进剂并产生基本上不含甲基碘的粗还原羰基化产物。

公开(公告)号：US09266806B1

公开(公告)日：2016-02-23

申请号：US14586070

申请日：2014-12-30

Applicant: Eastman Chemical Company

Inventor： Andrew James Vetter ,  Jonathan Michael Penney ,  David William Norman

IPC: C07C45/49 ,  B01J31/00 ,  C07C45/00 ,  B01J37/04 ,  B01J31/24

CPC classification number: C07C45/002 ,  B01J31/2404 ,  B01J37/04 ,  B01J2231/44 ,  B01J2531/845 ,  C07C47/04

Abstract: Catalyst composition produced by combining a cobalt-containing precursor in an alkyl alcohol with a phosphine ligand to the solution; and subsequently adding an iodine compound. Reductive carbonylation processes using the catalyst composition to produce aldehydes are also provided.

Abstract translation: 通过将烷基醇中的含钴前体与膦配体结合到溶液中而制备的催化剂组合物; 随后加入碘化合物。 还提供了使用催化剂组合物制备醛的还原性羰基化方法。

公开(公告)号：US09238606B1

公开(公告)日：2016-01-19

申请号：US14585940

申请日：2014-12-30

Applicant: Eastman Chemical Company

Inventor： Jonathan Michael Penney ,  Andrew James Vetter ,  David William Norman

IPC: C07C45/49 ,  B01J31/00 ,  B01J31/24

CPC classification number: C07C45/49 ,  B01J31/24 ,  B01J2231/34 ,  B01J2531/10 ,  B01J2531/845 ,  C07C45/50 ,  C07C51/12 ,  C07C47/04 ,  C07C53/08

Abstract: Disclosed is a process for the reductive carbonylation of methanol to produce acetaldehyde. The process includes conducting the reaction to produce acetaldehyde in the presence of a catalyst comprising a complex composed of cobalt, an onium cation and iodide in a ratio of 1:2:4, a phosphine ligand, and a phosphonium iodide. The reductive carbonylation reaction produces a crude reductive carbonylation product substantially free of methyl iodide.

Abstract translation: 公开了一种用于还原羰基化甲醇以生产乙醛的方法。 该方法包括在催化剂存在下进行反应生成乙醛，所述催化剂包含由钴，鎓阳离子和碘化物以1:2:4的比例组成的络合物，膦配体和碘化鏻。 还原羰基化反应产生基本上不含甲基碘的粗还原羰基化产物。

公开(公告)号：US08993801B2

公开(公告)日：2015-03-31

申请号：US13826180

申请日：2013-03-14

Applicant: Eastman Chemical Company

Inventor： Venkata Bharat Ram Boppana ,  David William Norman ,  Melissa Dawn Page

IPC: B01J27/198 ,  C07C51/377 ,  B01J37/03 ,  B01J21/06 ,  B01J35/00 ,  C07C51/09

CPC classification number: C07C51/377 ,  B01J21/063 ,  B01J27/198 ,  B01J35/002 ,  B01J37/031 ,  B01J2523/00 ,  C07C51/09 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55 ,  C07C57/04

Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed. Additionally, the catalyst composition is catalytically active towards the formation of acrylic acid from methylene diacetate and methacrylic acid from methylene dipropionate; both reactions are carried out with high space time yields.

Abstract translation: 本发明涉及包含钒，钛和磷的混合氧化物的催化剂组合物。 钛组分衍生自水溶性，氧化还原活性有机钛化合物。 催化剂组合物在促进甲醛与乙酸的气相缩合以产生丙烯酸方面是非常有效的，特别是使用工业上相关的水性液体进料。 此外，催化剂组合物对于从亚甲基二乙酸酯和甲基丙烯酸由二丙酸亚丙酯形成丙烯酸具有催化活性; 两个反应均以高空时产率进行。

公开(公告)号：US20230235093A1

公开(公告)日：2023-07-27

申请号：US18190415

申请日：2023-03-27

Applicant: Eastman Chemical Company

Inventor： Matthew Allen Boone ,  Christopher Harlan Burk ,  Peter Borden Mackenzie ,  Jennifer A. Fish ,  Eduardo Gallas Cervo ,  Elaine Beatrice Mackenzie ,  Robert Joseph Maleski ,  Wesley Wayne McConnell ,  David William Norman ,  Tabatha Stearns ,  Bin Wang

IPC: C08B3/16 ,  B32B27/24 ,  B32B27/08 ,  B32B27/36 ,  B32B7/12 ,  B32B27/28 ,  C08L1/14 ,  B32B23/08 ,  B32B27/32 ,  B32B27/18 ,  G02B5/30 ,  B32B27/22 ,  H10K50/86 ,  H10K50/84 ,  B32B27/06 ,  G02F1/13363

CPC classification number: C08B3/16 ,  B32B27/24 ,  B32B27/08 ,  B32B27/36 ,  B32B7/12 ,  B32B27/281 ,  C08L1/14 ,  B32B27/365 ,  B32B23/08 ,  B32B27/325 ,  B32B27/18 ,  G02B5/3033 ,  B32B27/22 ,  H10K50/86 ,  H10K50/846 ,  B32B27/06 ,  G02B5/305 ,  G02B5/3083 ,  G02F1/13363 ,  C08L1/08

Abstract: Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.