Process and Apparatus For the Polymerization of Ethylene
    11.
    发明申请
    Process and Apparatus For the Polymerization of Ethylene 有权
    用于聚合乙烯的方法和装置

    公开(公告)号:US20080177012A1

    公开(公告)日:2008-07-24

    申请号:US11883713

    申请日:2006-01-30

    IPC分类号: C08F2/34 B01J8/00

    摘要: Process for the polymerization of ethylene or of ethylene with further 1-olefins, in which the ethylene is polymerized in the presence of a catalyst in a gas-phase reactor and reaction gas comprising propane and unpolymerized ethylene is circulated to remove the heat of polymerization, wherein the polymer particles are discharged continuously or discontinuously from the reactor, the polymer particles are separated from the major part of the concomitantly discharged gas and the polymer particles are degassed, the gas is freed of entrained fine particles and is separated from a low-boiling fraction comprising ethylene or from a high boiling fraction containing further 1-olefins or alkanes having from 4 to 12 carbon atoms in a first separation stage, a propane fraction is separated off in a second separation stage and this propane fraction is used for degassing the polymer particles discharged from the reactor, with the proportion of ethylene in the propane fraction being less than 1 mol % and the proportion of 1-olefins and alkanes having from 4 to 12 carbon atoms in the propane fraction being less than 4 mol %, in each case based on the total propane fraction. Furthermore, an apparatus for carrying out the process. In this way, a high heat discharge from the reactor, satisfactory degassing of the discharged polymer particles and recovery of the reaction gas discharged together with the polymer particles and also the gas used for degassing the polymer particles are made possible.

    摘要翻译: 乙烯或乙烯与进一步的1-烯烃聚合的方法,其中乙烯在催化剂存在下在气相反应器和包含丙烷和未聚合乙烯的反应气体中聚合循环以除去聚合热, 其中聚合物颗粒从反应器中连续或不连续地排出,聚合物颗粒与伴随排出气体的主要部分分离,聚合物颗粒脱气,气体不含夹带的细颗粒,并从低沸点 在第一分离阶段,包含乙烯或含有另外的具有4至12个碳原子的1-烯烃或烷烃的高沸点馏分的馏分在第二分离阶段分离出丙烷馏分,该丙烷馏分用于使聚合物脱气 从反应器排出的颗粒,丙烷馏分中乙烯的比例小于1mol %,丙烷馏分中具有4至12个碳原子的1-烯烃和烷烃的比例小于4mol%,基于总丙烷馏分。 此外,一种用于执行该过程的装置。 以这种方式,可以从反应器的高热放电,排出的聚合物颗粒的令人满意的脱气和与聚合物颗粒一起排放的反应气体的回收以及用于使聚合物颗粒脱气的气体成为可能。

    Gas phase fluidized bed method and ethylene homo- and copolymers obtained using said method
    15.
    发明授权
    Gas phase fluidized bed method and ethylene homo- and copolymers obtained using said method 有权
    气相流化床法和使用所述方法获得的乙烯均聚物和共聚物

    公开(公告)号:US06649709B1

    公开(公告)日:2003-11-18

    申请号:US09555594

    申请日:2000-05-31

    IPC分类号: C08F234

    CPC分类号: C08F10/02 C08F4/24 C08F2/34

    摘要: A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.

    摘要翻译: 用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法,其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物(共)聚合 在负载的铬催化剂的存在下,在气相流化床反应器的聚合区域的存在下,在压力范围为1至100巴,温度范围为30至125℃,气相在搅拌床 包含颗粒聚合物的散装材料,通过冷却再循环的反应器气体除去所得到的聚合热,并将所得(共)聚合物从气相流化床反应器中除去,其中,为制备(共)聚合物 特定密度d,(共)聚合在由等式I定义的上包络限制的范围内进行,并且由等式IIin定义的下包络,其中变量具有以下含义:T H是最高的反应温度,单位°C; TL是最低反应温度(℃); d'是待合成的(共)聚合物的密度d的数值。

    Process and apparatus for mixing and splitting fluid streams
    16.
    发明授权
    Process and apparatus for mixing and splitting fluid streams 有权
    用于混合和分裂流体流的方法和装置

    公开(公告)号:US09000114B2

    公开(公告)日:2015-04-07

    申请号:US13813604

    申请日:2011-08-02

    摘要: A process for continuously mixing at least two fluid streams and splitting the stream of the mixture into at least two partial streams, comprising a) providing streams of the at least two fluids via separated conduits; b) combining the streams of the fluids and forming a homogeneous mixture; c) measuring the pressure in the conduit conveying the mixture of the fluids; d) splitting the stream of the mixture of the fluids into at least two partial streams and feeding each of the partial streams to a conduit equipped with a flow control device controlled by a controller; and e) adjusting the flow rates of the partial streams of the mixture of the fluids by feeding the pressure information measured in step c) as process variable to the controllers controlling the flow control devices, a process for feeding a mixture of at least two fluids via at least two feeding points, an apparatuses for carrying out such processes and a process for polymerizing olefins.

    摘要翻译: 一种用于连续混合至少两种流体流并将混合物流分解为至少两个部分流的方法,包括a)经由分离的导管提供所述至少两种流体的流; b)组合流体流并形成均匀的混合物; c)测量输送流体混合物的管道中的压力; d)将流体混合物的流分成至少两个部分流,并将每个部分流输送到配备有由控制器控制的流量控制装置的导管; 以及e)通过将在步骤c)中测量的压力信息作为过程变量输入到控制流量控制装置的控制器,来调节流体混合物的部分流的流速;将至少两种流体 通过至少两个进料点,用于进行这些方法的装置和聚合烯烃的方法。

    Vapor-phase fluidized-bed process and ethylene homopolymers and copolymers produced thereby
    18.
    发明授权
    Vapor-phase fluidized-bed process and ethylene homopolymers and copolymers produced thereby 失效
    气相流化床方法和由此制备的乙烯均聚物和共聚物

    公开(公告)号:US06849699B2

    公开(公告)日:2005-02-01

    申请号:US10658916

    申请日:2003-09-11

    CPC分类号: C08F10/02 C08F4/24 C08F2/34

    摘要: A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢   ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢   ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.

    摘要翻译: 用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法,其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物(共)聚合 在负载的铬催化剂的存在下,在气相流化床反应器的聚合区域的存在下,在压力范围为1至100巴,温度范围为30至125℃,气相在搅拌床 包含颗粒聚合物的散装材料,通过冷却再循环的反应器气体除去所得到的聚合热,并将所得(共)聚合物从气相流化床反应器中除去,其中,为制备(共)聚合物 特定密度d,(共)聚合在由等式I定义的上包络限制的范围内进行,并且由等式IIin定义的下包络,其中变量具有以下含义:T H是最高的反应温度,单位°C; TL是最低反应温度(℃); d'是待合成的(共)聚合物的密度d的数值。

    PROCESS AND APPARATUS FOR MIXING AND SPLITTING FLUID STREAMS
    20.
    发明申请
    PROCESS AND APPARATUS FOR MIXING AND SPLITTING FLUID STREAMS 有权
    混合和分流流体流的方法和装置

    公开(公告)号:US20130131300A1

    公开(公告)日:2013-05-23

    申请号:US13813604

    申请日:2011-08-02

    IPC分类号: B29B7/00

    摘要: A process for continuously mixing at least two fluid streams and splitting the stream of the mixture into at least two partial streams, comprising a) providing streams of the at least two fluids via separated conduits; b) combining the streams of the fluids and forming a homogeneous mixture; c) measuring the pressure in the conduit conveying the mixture of the fluids; d) splitting the stream of the mixture of the fluids into at least two partial streams and feeding each of the partial streams to a conduit equipped with a flow control device controlled by a controller; and e) adjusting the flow rates of the partial streams of the mixture of the fluids by feeding the pressure information measured in step c) as process variable to the controllers controlling the flow control devices, a process for feeding a mixture of at least two fluids via at least two feeding points, an apparatuses for carrying out such processes and a process for polymerizing olefins.

    摘要翻译: 一种用于连续混合至少两种流体流并将混合物流分解为至少两个部分流的方法,包括a)经由分离的导管提供所述至少两种流体的流; b)组合流体流并形成均匀的混合物; c)测量输送流体混合物的管道中的压力; d)将流体混合物的流分成至少两个部分流,并将每个部分流输送到配备有由控制器控制的流量控制装置的导管; 以及e)通过将在步骤c)中测量的压力信息作为过程变量输入到控制流量控制装置的控制器,来调节流体混合物的部分流的流速;将至少两种流体 通过至少两个进料点,用于进行这些方法的装置和聚合烯烃的方法。