摘要:
The present invention relates to polyol mixtures which are suitable for the preparation of rigid polyurethane foams and comprise addition products of alkylene oxide on aromatic di- or polyamines, and rigid foams prepared with these polyol mixtures.
摘要:
A process is described for the preparation of stable, agglomerate-free, low-viscosity graft copolymer dispersions by the free-radical polymerization of olefinic monomers, such as styrene and/or acrylonitrile, with polyol compounds in the presence of a hydroxyl compound modified with castor oil. The use of these graft copolymer dispersions in the manufacture of polyurethane plastics, particularly flexible foams, by the isocyanate polyaddition process is also described.
摘要:
The present invention relates to polyether polyols having OH numbers of about 300 to 630 obtained by sequentially reacting 2,4- and/or 2,6-tolylenediamine or mixtures of 2,4-and/or 2,6-tolylenediamine and one or more other aromatic amines with from about 1 to 2.5 moles of ethylene oxide for each NH.sub.2 group, and then with from about 0.5 to 5 moles of propylene oxide for each NH.sub.2 group, wherein said polyether polyols contain secondary amino groups comprising from about 2 to 20% of the isocyanate-reactive groups in said polyols and a free aromatic amine content of less than about 0.2% by weight. The present invention further relates to a process for preparing the polyether polyols of the invention, as well as to a method of using the polyether polyols for the preparation of polyurethane plastics.
摘要:
The present invention is directed to a process for the preparation of polymers containing hydroxyl groups by reacting polymers based on acrylic acid and/or methacrylic acid and containing carboxyl groups with alkylene oxides in the presence of catalysts, characterized in that the catalysts used are(a) addition products containing two thioether groups of (i) mercaptoalkanols corresponding to the formula ##STR1## and (ii) doubly unsaturated terpene hydrocarbons and/or condensation products with a maximum molecular weight of 5000 obtained by the condensation of such addition products on their own or with other polyhydric alcohols having a molecular weight of 62 to about 200, and/or(b) relatively high molecular weight thioethers having a molecular weight of about 500 to 5000 obtainable by the condensation of thiodiglycols corresponding to the formula ##STR2## optionally in admixture with up to 50 hydroxyl equivalents percent, based on the total mixture, of other polyhydroxyl compounds having a molecular weight of 62 to about 200, in which formula, R and R' may be identical or different and denote hydrogen or a methyl group.The present invention is further directed to the use of the hydroxyl containing alkoxylation products obtained by this process as reactants for organic polyisocyanates (optionally blocked with blocking agents for isocyanate groups) in the production of polyurethane plastics, in particular high quality polyurethane coatings.
摘要:
The present invention is directed to a stable dispersion of a polyurea and/or a polyhydrazodicarbonamide in a relatively high molecular weight hydroxyl-group containing material, which dispersion has a solids content of from 5 to 50 percent by weight and which is obtained by reacting(a) an organic di- and/or polyisocyanate with(b) an amine-functional material comprising an addition product of(1) acrylonitrile and(2) a member selected from the group consisting of(i) hydrazine,(ii) aliphatic di- or polyamines containing at least two primary amino groups,(iii) cycloaliphatic di- or polyamines containing at least two primary amino groups,(iv) araliphatic di- or polyamines containing at least two primary amino groups, and(v) mixtures thereof, the ratio of (1) to (2) being at least one mol of (1) per mol of (2) and at most one mol of (1) for each nitrogen atom contained in (2) per mol of (2),the reaction of component (a) and component (b) being conducted at a temperature of from 30.degree. to 170.degree. C., at an equivalent ratio of components (a) to (b) of from 0.8:1 to 1.5:1, and in the presence of(c) a relatively high molecular weight, hydroxyl-group containing material.The invention also relates to the production and use of such dispersions.
摘要:
A superconducting fiber of a superconducting fiber bundle, in which a base layer of a carbide or oxide is applied to the outer surface of a carrier fiber and subsequently a superconducting layer is deposited on the base layer to which the superconducting layer adheres.
摘要:
The invention relates to (meth)acrylic acid esters of compounds of Formula (I) as defined infra and methods for their preparation. The esters formed can be used to provide dental repair material and also to provide adhesive or sealing agents. In addition, the invention includes a process for preparing compositions which harden in the absence of oxygen by admixing a compound of the invention with an initiator.
摘要:
The invention relates to a method of introducing reaction mixtures for single-component foams into pressure containers. The reaction mixture comprises at least two reaction components and a blowing agent and is formed in an injection mixing head. The reaction mixture is then introduced into an evacuated pressure bottle provided with a valve. Additional pure blowing agent is added via the injection mixhead subsequent to the introduction of the reaction mixture into the pressure container.
摘要:
The invention relates to a method for restarting an internal combustion engine, in which a first cylinder (ZYL1) has a low air level and a second cylinder (ZYL2) has a high air level, and wherein a predefined speed threshold value (ns) is selected as a function of said air levels. A method for the restart is selected and carried out as a function of a comparison of the determined speed (n) of the internal combustion engine with the predefined speed threshold value (ns).
摘要:
A method is described for operating an internal combustion engine, the internal combustion engine including an angle of rotation sensor. In normal operation, a function is activated at a first angle of rotation. In stop operation, internal combustion engine is temporarily brought to a standstill. The function is activated in a start operation following the stop operation at a second angle of rotation, which follows the first angle of rotation in the direction of rotation.