Polyether polyols based on aromatic diamines and polyamines, a process
for their preparation, and their use for polyurethane and
polyisocyanurate plastics
    13.
    发明授权
    Polyether polyols based on aromatic diamines and polyamines, a process for their preparation, and their use for polyurethane and polyisocyanurate plastics 失效
    基于芳族二胺和聚氨酯的聚醚多元醇,其制备方法及其用于聚氨酯和聚异氰酸酯塑料的方法

    公开(公告)号:US5141968A

    公开(公告)日:1992-08-25

    申请号:US394046

    申请日:1989-08-15

    摘要: The present invention relates to polyether polyols having OH numbers of about 300 to 630 obtained by sequentially reacting 2,4- and/or 2,6-tolylenediamine or mixtures of 2,4-and/or 2,6-tolylenediamine and one or more other aromatic amines with from about 1 to 2.5 moles of ethylene oxide for each NH.sub.2 group, and then with from about 0.5 to 5 moles of propylene oxide for each NH.sub.2 group, wherein said polyether polyols contain secondary amino groups comprising from about 2 to 20% of the isocyanate-reactive groups in said polyols and a free aromatic amine content of less than about 0.2% by weight. The present invention further relates to a process for preparing the polyether polyols of the invention, as well as to a method of using the polyether polyols for the preparation of polyurethane plastics.

    摘要翻译: 本发明涉及通过使2,4-和/或2,6-甲苯二胺或2,4-和/或2,6-甲苯二胺和一种或多种2,6-二甲苯基二胺的混合物顺序反应获得的OH值为约300至630的聚醚多元醇 每个NH 2基团具有约1至2.5摩尔环氧乙烷的其它芳族胺,然后每个NH 2基团使用约0.5至5摩尔环氧丙烷,其中所述聚醚多元醇含有仲氨基,其包含约2-20% 的所述多元醇中的异氰酸酯反应性基团,游离芳族胺含量小于约0.2重量%。 本发明还涉及制备本发明的聚醚多元醇的方法,以及使用聚醚多元醇制备聚氨酯塑料的方法。

    Process for the preparation of polymers containing hydroxyl groups and
their use for the production of polyurethanes
    14.
    发明授权
    Process for the preparation of polymers containing hydroxyl groups and their use for the production of polyurethanes 失效
    制备含羟基聚合物的方法及其用于生产聚氨酯的方法

    公开(公告)号:US4803246A

    公开(公告)日:1989-02-07

    申请号:US849649

    申请日:1986-04-09

    CPC分类号: C08F8/14 C08G18/6258

    摘要: The present invention is directed to a process for the preparation of polymers containing hydroxyl groups by reacting polymers based on acrylic acid and/or methacrylic acid and containing carboxyl groups with alkylene oxides in the presence of catalysts, characterized in that the catalysts used are(a) addition products containing two thioether groups of (i) mercaptoalkanols corresponding to the formula ##STR1## and (ii) doubly unsaturated terpene hydrocarbons and/or condensation products with a maximum molecular weight of 5000 obtained by the condensation of such addition products on their own or with other polyhydric alcohols having a molecular weight of 62 to about 200, and/or(b) relatively high molecular weight thioethers having a molecular weight of about 500 to 5000 obtainable by the condensation of thiodiglycols corresponding to the formula ##STR2## optionally in admixture with up to 50 hydroxyl equivalents percent, based on the total mixture, of other polyhydroxyl compounds having a molecular weight of 62 to about 200, in which formula, R and R' may be identical or different and denote hydrogen or a methyl group.The present invention is further directed to the use of the hydroxyl containing alkoxylation products obtained by this process as reactants for organic polyisocyanates (optionally blocked with blocking agents for isocyanate groups) in the production of polyurethane plastics, in particular high quality polyurethane coatings.

    摘要翻译: 本发明涉及一种通过在催化剂存在下,通过使基于丙烯酸和/或甲基丙烯酸的聚合物与烯化氧反应的聚合物制备含羟基的聚合物的方法,其特征在于所用的催化剂是(a )含有两个硫醚基团的加成产物(i)对应于式“IMAGE”的巯基链烷醇和(ii)通过自身缩合产生的双不饱和萜烯烃和/或最大分子量为5000的缩合产物 或分子量为62至约200的其它多元醇,和/或(b)分子量为约500至5000的相对较高分子量的硫醚,其可通过任选地在式 与其他多羟基化合物的混合物混合至多50个羟基当量百分比 分子量为62至约200,其中R和R'可以相同或不同,表示氢或甲基。 本发明还涉及通过该方法获得的含羟基烷氧基化产物作为有机多异氰酸酯的反应物(任选地用异氰酸酯基团的封闭剂封端)用于生产聚氨酯塑料,特别是高质量聚氨酯涂料中的用途。

    Stable dispersions of polyureas and/or polyhydrazo-dicarbonamides in
relatively high molecular weight hydroxyl-group containing materials, a
process for the production thereof and the use thereof for the
production of polyurethane plastics
    15.
    发明授权
    Stable dispersions of polyureas and/or polyhydrazo-dicarbonamides in relatively high molecular weight hydroxyl-group containing materials, a process for the production thereof and the use thereof for the production of polyurethane plastics 失效
    在相对高分子量含羟基的材料中聚脲和/或聚二氢二碳酰胺的稳定分散体,其制备方法及其在聚氨酯塑料生产中的应用

    公开(公告)号:US4668734A

    公开(公告)日:1987-05-26

    申请号:US811862

    申请日:1985-12-20

    摘要: The present invention is directed to a stable dispersion of a polyurea and/or a polyhydrazodicarbonamide in a relatively high molecular weight hydroxyl-group containing material, which dispersion has a solids content of from 5 to 50 percent by weight and which is obtained by reacting(a) an organic di- and/or polyisocyanate with(b) an amine-functional material comprising an addition product of(1) acrylonitrile and(2) a member selected from the group consisting of(i) hydrazine,(ii) aliphatic di- or polyamines containing at least two primary amino groups,(iii) cycloaliphatic di- or polyamines containing at least two primary amino groups,(iv) araliphatic di- or polyamines containing at least two primary amino groups, and(v) mixtures thereof, the ratio of (1) to (2) being at least one mol of (1) per mol of (2) and at most one mol of (1) for each nitrogen atom contained in (2) per mol of (2),the reaction of component (a) and component (b) being conducted at a temperature of from 30.degree. to 170.degree. C., at an equivalent ratio of components (a) to (b) of from 0.8:1 to 1.5:1, and in the presence of(c) a relatively high molecular weight, hydroxyl-group containing material.The invention also relates to the production and use of such dispersions.

    摘要翻译: 本发明涉及聚脲和/或聚二酰氨基脲在相对高分子量含羟基的材料中的稳定分散体,该分散体的固体含量为5-50重量%,其通过使( a)有机二 - 和/或多异氰酸酯与(b)胺官能材料,其包含(1)丙烯腈和(2)选自(i)肼,(ii)脂族二 - 或含有至少两个伯氨基的多胺,(iii)含有至少两个伯氨基的脂环族二元或多胺,(iv)含有至少两个伯氨基的芳脂族二元或多胺,和(v)其混合物, (2)中所含的每个氮原子(2)每摩尔(2)至少1摩尔(1)和至多1摩尔(1)的比例(1)至(2) 组分(a)和组分(b)的反应在30℃的温度下进行 (a)至(b)的当量比为0.8:1至1.5:1,并且在(c)相对高分子量的含羟基材料的存在下进行。 本发明还涉及这种分散体的生产和使用。

    Method for operating an internal combustion engine
    20.
    发明申请
    Method for operating an internal combustion engine 审中-公开
    操作内燃机的方法

    公开(公告)号:US20140100764A1

    公开(公告)日:2014-04-10

    申请号:US14046270

    申请日:2013-10-04

    IPC分类号: F02D43/04

    摘要: A method is described for operating an internal combustion engine, the internal combustion engine including an angle of rotation sensor. In normal operation, a function is activated at a first angle of rotation. In stop operation, internal combustion engine is temporarily brought to a standstill. The function is activated in a start operation following the stop operation at a second angle of rotation, which follows the first angle of rotation in the direction of rotation.

    摘要翻译: 描述了一种用于操作内燃机的方法,内燃机包括旋转角传感器。 在正常操作中,功能以第一旋转角度被激活。 在停机运行中,内燃机暂时停机。 该功能在第二旋转角度的停止操作之后的启动操作中被激活,该第二旋转角沿着旋转方向上的第一旋转角度。