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公开(公告)号：US20200172645A1
公开(公告)日：2020-06-04
申请号：US16692804
申请日：2019-11-22
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： David M. Fiscus , Peijun Jiang , Yong Yang
IPC: C08F210/02 , C08F232/08 , C08J5/18
Abstract: The present disclosure provides copolymers comprising from about 0.5 wt % to about 25 wt % cyclic olefin content and films comprising the copolymers. In one embodiment, a copolymer includes a C2-C40 monomer content of from about 75 wt % to about 99.5 wt %; and a C5-C40 cyclic olefin comonomer content of from about 0.5 wt % to about 25 wt %. The copolymer has a density of about 0.91 g/cm3 to about 0.933 g/cm3. Films of the present disclosure can have advantageous mechanical properties (such as melt strength) and optical properties (such as haze %).
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公开(公告)号：US20190233580A1
公开(公告)日：2019-08-01
申请号：US16263048
申请日：2019-01-31
Inventor： David A. Schiraldi , Hua Sun , Yong Yang
IPC: C08G63/185 , C08J5/04
CPC classification number: C08G63/185 , B29C45/0001 , B29K2067/003 , B29K2309/08 , C08G2250/00 , C08J5/043 , C08J2367/02
Abstract: Fiber-reinforced terephthalate-co-4,4′-bibenzoate copolyester behaves like a liquid crystalline polymer, providing fast crystallization, short cycling times, high Tg and Tm, high strength and stiffness, while the viscosity is unexpectedly reduced at a low fiber loading ratio. In an injection molding process, the viscosity of the fiber reinforced copolyester at low fiber loading is reduced by increasing the fiber loading.
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公开(公告)号：US20190010314A1
公开(公告)日：2019-01-10
申请号：US15965560
申请日：2018-04-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Yong Yang , Alexander I. Norman , Andy H. Tsou , Kimari T.M. Slaughter , Bethany M. Weike , Dinara R. Sunagatullina
IPC: C08L23/06
Abstract: A composite comprising a polyethylene and within a range from 1 wt % to 25 wt % of at least one cyclic-olefin copolymer by weight of the composition, where the polyethylene may have a density of at least 0.90 g/cm3, and where the cyclic-olefin copolymer has a glass transition temperature (Tg) of at least 30° C. Disclosed also is the feature of orienting the composite to form an oriented article, wherein the article comprises rods having an average length of at least 1 μm, and at least 5 nm in average diameter.
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公开(公告)号：US20180346736A1
公开(公告)日：2018-12-06
申请号：US16058516
申请日：2018-08-08
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Yong Yang , Andy H. Tsou , Kimari T.M. Slaughter
CPC classification number: C09D5/08 , B60C1/0016 , C08F8/30 , C08F8/42 , C08G81/00 , C09D123/36 , C08F8/06 , C08F10/00
Abstract: Stable star-structured functional polyolefins and methods of making them, the functional polyolefins comprising a polyolefin bound at any position along its chain length to at least one nucleophile-containing silane of the following formula: wherein Y is a di- or trivalent linker group selected from heteroatoms, C1 to C10 alkylenes, and other groups disclosed herein; Nu is a nucleophilic atom or unsaturation group; R5 is selected from hydrogen, and C1 to C10 alkyls, and other groups as disclosed herein; X is a divalent group selected from linear and branched alkylenes and heteroatom-alkylenes, and other groups as disclosed herein; and PO is a polyolefin having a weight average molecular weight of at least 400 g/mole; with the proviso that at least one of R1, R2, and R3 is selected from the same or different functional polyolefin moieties. Star-structured functional polyolefins are useful as filler dispersive additives in tire formulations and processing aids.
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公开(公告)号：US20180155471A1
公开(公告)日：2018-06-07
申请号：US15808096
申请日：2017-11-09
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Carlos R. Lopez-Barron , Mark K. Davis , Alan A. Galuska , Yong Yang , Mosha H. Zhao
IPC: C08F112/32 , C08L25/04
Abstract: Disclosed is an article comprising polymers and copolymers selected from the group consisting of poly(vinylbiphenyl), poly(vinylcyclohexylstyrene), substituted versions thereof, and blends thereof, the polymer or copolymer having a weight average molecular weight (Mw) of at least 100 kg/mole and a glass transition temperature (Tg) of at least 100° C. The polymers are desirably processed in the melted state at a temperature of at least 150° C. to impart orientation and extensional strain hardening.
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Patent Agency Ranking
公开(公告)号：US20160215102A1
公开(公告)日：2016-07-28
申请号：US14917401
申请日：2014-08-11
Applicant: ExxonMobil Chemical Patents INC.
Inventor： Yong Yang , John R. Hagadorn , Andy H. Tsou
CPC classification number: C08G81/025 , C08F4/65908 , C08F110/02 , C08F255/00 , C08F283/00 , C08F283/08 , C08F290/04 , C08F290/042 , C08G61/02 , C08G61/12 , C08G69/48 , C08G73/105 , C08G73/1071 , C08G2261/128 , C08G2261/45 , C08G2261/75 , C08G2261/77 , C08L51/08 , C08L71/123 , C08F210/02 , C08L71/12 , C08F10/02 , C08F4/65927 , C08F210/16 , C08F210/14
Abstract: A graft copolymer comprising polyolefin and engineering thermoplastic components, wherein the thermoplastic component is a polymer comprising heteroatoms or heteroatom containing moieties in its backbone and phenyl or substituted phenyl groups, the polyolefin component covalently bound to the engineering thermoplastic component. The graft copolymer is the reaction product of an engineering thermoplastic having at least one phenylene in the polymer backbone, and a vinyl/vinylidene terminated polyolefin having a weight average molecular weight of at least 300 g/mole, wherein the vinyl/vinylidene terminated polyolefin is selected from polyethylenes, polypropylenes, ethylene-propylene copolymers, polyisobutylenes, polydienes, propylene-based elastomers, ethylene-based plastomers, and combinations thereof.
Abstract translation: 包含聚烯烃和工程热塑性组分的接枝共聚物，其中所述热塑性组分是在其主链和苯基或取代的苯基中含有杂原子或含杂原子的部分的聚合物，所述聚烯烃组分与工程热塑性组分共价结合。 接枝共聚物是聚合物主链中具有至少一个亚苯基的工程热塑性聚合物和重均分子量至少为300g / mol的乙烯基/亚乙烯基封端的聚烯烃的反应产物，其中乙烯基/亚乙烯基封端的聚烯烃是 选自聚乙烯，聚丙烯，乙烯 - 丙烯共聚物，聚异丁烯，聚二烯，丙烯基弹性体，乙烯基塑性体及其组合。
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公开(公告)号：US20160159944A1
公开(公告)日：2016-06-09
申请号：US14923002
申请日：2015-10-26
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Yong Yang , Andy H. Tsou , Kimari T. M. Slaughter
IPC: C08F110/06 , C08L23/12
CPC classification number: C09D5/08 , B60C1/0016 , C08F8/30 , C08F8/42 , C08F10/00 , C08G81/00 , C08G81/021 , C09D123/36 , C08F8/08
Abstract: Stable star-structured functional polyolefins and methods of making them, the functional polyolefins comprising a polyolefin bound at any position along its chain length to at least one nucleophile-containing silane of the following formula: wherein Y is a di- or trivalent linker group selected from heteroatoms, C1 to C10 alkylenes, and other groups disclosed herein; Nu is a nucleophilic atom or unsaturation group; R5 is selected from hydrogen, and C1 to C10 alkyls, and other groups as disclosed herein; X is a divalent group selected from linear and branched alkylenes and heteroatom-alkylenes, and other groups as disclosed herein; and PO is a polyolefin having a weight average molecular weight of at least 400 g/mole; with the proviso that at least one of R1, R2, and R3 is selected from the same or different functional polyolefin moieties. Star-structured functional polyolefins are useful as filler dispersive additives in tire formulations and processing aids.
Abstract translation: 稳定的星形结构官能聚烯烃及其制备方法，所述功能性聚烯烃包含在其链长上任意位置结合的聚烯烃，至少含有下式的含亲核试剂的硅烷：其中Y是选择的二价或三价连接基团 从杂原子，C1至C10亚烷基和本文公开的其它基团; Nu是亲核原子或不饱和基团; R5选自氢和C1至C10烷基，以及本文公开的其它基团; X是选自直链和支链亚烷基和杂原子 - 亚烷基的二价基团，以及本文公开的其它基团; PO是重均分子量至少为400g / mol的聚烯烃; 条件是R 1，R 2和R 3中的至少一个选自相同或不同的官能聚烯烃部分。 星形结构的功能性聚烯烃可用作轮胎配方和加工助剂中的填料分散添加剂。
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18.发明授权公开(公告)号：US11142021B2
公开(公告)日：2021-10-12
申请号：US16773478
申请日：2020-01-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Edward J. Blok , Yong Yang , Jingwen Zhang , Ian C. Stewart , Shuji Luo , Andy H. Tsou
Abstract: A functionalized polyolefin and a tire tread composition comprising the functionalized polyolefin is described. The functionalized polyolefin comprises a vinyl/vinylidene-terminated polyolefin in which the vinyl/vinylidene terminus is functionalized with an alkoxysilane or an alkylsilane and optionally having ether, hydroxyl and/or amine functionality. The invention is also directed to the synthesis of vinyl/vinylidene-terminated polyolefins, functionalization at the vinyl/vinylidene terminus with an alkoxysilane or an alkylsilane and optionally having ether, hydroxyl and/or amine functionality.
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公开(公告)号：US20210238395A1
公开(公告)日：2021-08-05
申请号：US17059666
申请日：2020-11-30
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Edward J. Blok , Anthony J. Dias , Sunny Jacob , Ian C. Stewart , Yong Yang , Jingwen Zhang
Abstract: A tire tread composition is disclosed. The tire tread composition includes components, by weight of the composition, within the range from: 5 to 75 wt % of a diene elastomer; 0 to 40 wt % of processing oil; 20 to 80 wt % of filler; a curative agent; and 5 to 30 wt % of a propylene-ethylene-diene terpolymer containing from 2 wt % to 40 wt % of ethylene and/or C4-C20 α-olefins derived units, from 0.5 to 10 wt % of diene derived units, and having a heat of fusion, as determined by DSC, of from 0 J/g to 80 J/g.
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公开(公告)号：US11072685B2
公开(公告)日：2021-07-27
申请号：US16263048
申请日：2019-01-31
Inventor： David A. Schiraldi , Hua Sun , Yong Yang
IPC: C08G63/185 , C08J5/04 , C08L67/02 , B29K309/08 , B29C45/00 , B29K67/00
Abstract: Fiber-reinforced terephthalate-co-4,4′-bibenzoate copolyester behaves like a liquid crystalline polymer, providing fast crystallization, short cycling times, high Tg and Tm, high strength and stiffness, while the viscosity is unexpectedly reduced at a low fiber loading ratio. In an injection molding process, the viscosity of the fiber reinforced copolyester at low fiber loading is reduced by increasing the fiber loading.
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