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    Copolymers of ethylene and/or α-olefins and vicinally disubstituted olefins
    17.
    发明授权
    Copolymers of ethylene and/or α-olefins and vicinally disubstituted olefins 失效
    乙烯和/或α-烯烃和邻近二取代烯烃的共聚物

    公开(公告)号：US07037989B2

    公开(公告)日：2006-05-02

    申请号：US10446325

    申请日：2003-05-27

    申请人： Smita Kacker ,  Enock Berluche ,  Timothy Daniel Shaffer ,  Jo Ann Marie Canich

    发明人： Smita Kacker ,  Enock Berluche ,  Timothy Daniel Shaffer ,  Jo Ann Marie Canich

    IPC分类号： C08F4/52

    CPC分类号： C08F210/02 ,  C08F210/08 ,  C08F210/16 ,  C08F2500/20 ,  C08F2500/03 ,  C08F210/06

    摘要： Substantially random ethylene and/or α-olefin copolymers containing units derived from vicinally disubstituted olefin monomers are described. The vicinally disubstituted olefin monomers may be represented by the generic formula (R1)CH═CH(R2), where R1 and R2 independently comprise hydrocarbyl or silyl-hydrocarbyl groups containing 1 or more carbon atoms, or may be linear, branched or cyclic substituted or unsubstituted hydrocarbyl groups having from 1-100 carbon atoms, or they may contain 30 or less carbon atoms. The copolymers may be prepared by coordination polymerization by means of contacting at least one vicinally disubstituted olefin monomer and ethylene and/or α-olefin, optionally with one or more other coordination polymerizable monomers, with a catalyst system comprising a monocyclopentadienyl heteroatom-containing Group 4 transition metal catalyst component.

    摘要翻译： 描述了含有衍生自邻近二取代的烯烃单体的单元的基本无规的乙烯和/或α-烯烃共聚物。 邻位二取代的烯烃单体可以由通式（R 1）CH-CH（R 2）表示，其中R 1和R 2 独立地包含含有1个或更多个碳原子的烃基或甲硅烷基 - 烃基，或者可以是具有1-100个碳原子的直链，支链或环状取代或未取代的烃基，或者它们可以含有30或 碳原子少。 共聚物可以通过使至少一个相邻二取代的烯烃单体和乙烯和/或α-烯烃（任选地与一种或多种其它配位可聚合单体）与含有单环戊二烯基杂原子的第4组的催化剂体系 过渡金属催化剂组分。

    Copolymers of ethylene and germinally disubstituted olefins
    19.
    发明授权
    Copolymers of ethylene and germinally disubstituted olefins 失效
    乙烯和二取代烯烃的共聚物

    公开(公告)号：US5866665A

    公开(公告)日：1999-02-02

    申请号：US959040

    申请日：1997-10-28

    申请人： Timothy Daniel Shaffer ,  Jo Ann Marie Canich ,  Kevin Richard Squire

    发明人： Timothy Daniel Shaffer ,  Jo Ann Marie Canich ,  Kevin Richard Squire

    IPC分类号： C08F4/64 ,  C08F4/645 ,  C08F4/659 ,  C08F4/6592 ,  C08F210/02 ,  C08F210/10

    CPC分类号： C08F210/02 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  Y10S526/916

    摘要： Substantially random ethylene copolymers containing at least 3.0 mole percent of geminally disubstituted olefin monomers are described. The geminally disubstituted olefin monomers can be represented by the generic formula R.sub.1 =R.sub.2 (R.sub.3)(R.sub.4), where R.sub.1 is CH.sub.2, R.sub.2 is C, and R.sub.3 and R.sub.4 are, independently, essentially linear hydrocarbyl groups having from 1 to 30 carbon atoms, or more, and containing one carbon atom bound directly to R.sub.2. The copolymers can be prepared by coordination polymerization by means of contacting at least one geminally disubstituted olefin monomer and ethylene, optionally with one or more other coordination polymerizable monomers, with a catalyst system comprising a monocyclopentadienyl, heteroatom-containing Group 4 transition metal catalyst component.

    摘要翻译： 描述了含有至少3.0摩尔％的双取代烯烃单体的基本上无规的乙烯共聚物。 氧化双取代的烯烃单体可以由通式R 1（R 2）（R 3）（R 4）表示，其中R 1是CH 2，R 2是C，R 3和R 4独立地是具有1至30个碳原子的直链烃基 或更多，并含有直接与R2结合的一个碳原子。 共聚物可以通过使至少一种双取代烯烃单体和任选与一种或多种其它配位聚合单体的乙烯与包含单环戊二烯基，含杂原子的第4族过渡金属催化剂组分的催化剂体系接触进行配位聚合制备。