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29 条记录 (耗时 0.026 秒)

    Controlling particle size in HIPS using metal carboxylates
    13.
    发明授权
    Controlling particle size in HIPS using metal carboxylates 失效
    使用金属羧酸盐控制HIPS中的粒径

    公开(公告)号：US07041733B2

    公开(公告)日：2006-05-09

    申请号：US10691827

    申请日：2003-10-23

    申请人： Cyril Chevillard ,  Jose M. Sosa

    发明人： Cyril Chevillard ,  Jose M. Sosa

    IPC分类号： C08F279/02 ,  C08F4/38

    CPC分类号： C08F279/02 ,  C08F212/08

    摘要： It has been discovered that certain compounds serve as particle size regulators when employed together with peroxide initiators for the polymerization of vinylaromatic monomers in the presence of diene polymers. Suitable compounds that can control particle size include, but are not necessarily limited to, cobalt naphthenate, zinc naphthenate, iron octoate, calcium octoate, zinc octoate, zinc neodecanoate, potassium octoate, copper naphthenate, calcium versalate, and the like. Use of these metal carboxylates when vinylaromatic monomers are polymerized in the presence of polybutadienes and peroxide initiators results in reduced polybutadiene particles. Grafting and morphology characteristics may also be improved.

    摘要翻译： 已经发现，当与二烯聚合物存在下乙烯基芳族单体聚合时，某些化合物与过氧化物引发剂一起使用时用作粒度调节剂。 可以控制颗粒尺寸的合适的化合物包括但不一定限于环烷酸钴，环烷酸锌，辛酸铁，辛酸钙，辛酸锌，新癸酸锌，辛酸钾，环烷酸铜，三钙酸钙等。 当乙烯基芳族单体在聚丁二烯和过氧化物引发剂存在下聚合时，这些金属羧酸盐的使用导致聚丁二烯颗粒减少。 接枝和形态特征也可以改善。

    Measurement and preparation of branched vinyl polymers
    14.
    发明申请
    Measurement and preparation of branched vinyl polymers 失效
    支链乙烯基聚合物的测量和制备

    公开(公告)号：US20050277754A1

    公开(公告)日：2005-12-15

    申请号：US11208909

    申请日：2005-08-22

    申请人： Brad Stiles ,  Jose Sosa ,  Cyril Chevillard ,  Aron Griffith ,  Jay Reimers

    发明人： Brad Stiles ,  Jose Sosa ,  Cyril Chevillard ,  Aron Griffith ,  Jay Reimers

    IPC分类号： C08F2/38 ,  C08F4/36 ,  C08F12/02 ,  C08F279/02 ,  C08L20060101 ,  C08L51/00

    CPC分类号： C08F2/00 ,  C08F112/08 ,  C08F279/02 ,  C08F2400/02 ,  C08L25/06 ,  C08L2205/02 ,  C08L2666/04 ,  C08F212/08

    摘要： Disclosed are novel non-linear vinyl polymers comprised of a multifunctional peroxide, and a cross-linking agent and/or a chain transfer agent, and methods of making such polymers having: at least 0.03 branches/1000 backbone carbons; linear portions with a molecular weight (Mw) of 350,000 or less; 0.2 to 3.0 branches/molecule; or, a Mz/Mw of from 1.7 to 5.7. Methods of quantifying branching are disclosed using a linear reference having 0.0 to 0.06 branches/1000 backbone carbons along with SEC techniques and measurements of molecular weight, molecular size, and concentration. Also discovered is a vinyl polymer resin comprised of from 0.1 to 50 weight percent of non-linear polymers having at least 0.06 branches/1000 backbone carbons, where branching is measured using a heat polymerized polystyrene having from 0.0 to 0.06 branches/1000 backbone carbons as a linear reference.

    摘要翻译： 公开了由多官能过氧化物，交联剂和/或链转移剂组成的新型非线性乙烯基聚合物，以及制备这种聚合物的方法，其具有：至少0.03个支链/ 1000个骨架碳; 分子量（Mw）为350,000以下的线性部分; 0.2〜3.0支/分子; 或者为1.7至5.7的Mz / Mw。 使用具有0.0至0.06个支链/ 1000个骨架碳的线性参考文献以及SEC技术和分子量，分子大小和浓度的测量来公开定量分支的方法。 还发现了乙烯基聚合物树脂，其由0.1至50重量％的具有至少0.06个支链/ 1000个骨架碳的非线性聚合物组成，其中使用具有0.0至0.06个支链/ 1000个骨架碳的热聚合聚苯乙烯测量分支， 线性参考。

    Measurement and preparation of branched vinyl polymers
    16.
    发明授权
    Measurement and preparation of branched vinyl polymers 失效
    支链乙烯基聚合物的测量和制备

    公开(公告)号：US07514516B2

    公开(公告)日：2009-04-07

    申请号：US11208909

    申请日：2005-08-22

    申请人： Brad Stiles ,  Jose M. Sosa ,  Cyril Chevillard ,  Aron Griffith ,  Jay L. Reimers

    发明人： Brad Stiles ,  Jose M. Sosa ,  Cyril Chevillard ,  Aron Griffith ,  Jay L. Reimers

    IPC分类号： C08F212/34 ,  C08F212/36 ,  C08F2/38 ,  G01N30/84

    CPC分类号： C08F2/00 ,  C08F112/08 ,  C08F279/02 ,  C08F2400/02 ,  C08L25/06 ,  C08L2205/02 ,  C08L2666/04 ,  C08F212/08

    摘要： Disclosed are novel non-linear vinyl polymers comprised of a multifunctional peroxide, and a cross-linking agent and/or a chain transfer agent, and methods of making such polymers having: at least 0.03 branches/1000 backbone carbons; linear portions with a molecular weight (Mw) of 350,000 or less; 0.2 to 3.0 branches/molecule; or, a Mz/Mw of from 1.7 to 5.7. Methods of quantifying branching are disclosed using a linear reference having 0.0 to 0.06 branches/1000 backbone carbons along with SEC techniques and measurements of molecular weight, molecular size, and concentration. Also discovered is a vinyl polymer resin comprised of from 0.1 to 50 weight percent of non-linear polymers having at least 0.06 branches/1000 backbone carbons, where branching is measured using a heat polymerized polystyrene having from 0.0 to 0.06 branches/1000 backbone carbons as a linear reference.

    摘要翻译： 公开了由多官能过氧化物，交联剂和/或链转移剂组成的新型非线性乙烯基聚合物，以及制备这种聚合物的方法，其具有：至少0.03个支链/ 1000个骨架碳; 分子量（Mw）为350,000以下的线性部分; 0.2〜3.0支/分子; 或者为1.7至5.7的Mz / Mw。 使用具有0.0至0.06个支链/ 1000个骨架碳的线性参考文献以及SEC技术和分子量，分子大小和浓度的测量来公开定量分支的方法。 还发现了乙烯基聚合物树脂，其由0.1至50重量％的具有至少0.06个支链/ 1000个骨架碳的非线性聚合物组成，其中使用具有0.0至0.06个支链/ 1000个骨架碳的热聚合聚苯乙烯测量分支， 线性参考。

    Use of accelerators in free-radical polymerizations of styrene
    18.
    发明授权
    Use of accelerators in free-radical polymerizations of styrene 失效
    在苯乙烯的自由基聚合中使用促进剂

    公开(公告)号：US06770716B1

    公开(公告)日：2004-08-03

    申请号：US10379052

    申请日：2003-03-04

    申请人： Jose M. Sosa ,  Cyril Chevillard

    发明人： Jose M. Sosa ,  Cyril Chevillard

    IPC分类号： C08F27902

    CPC分类号： C08F12/04 ,  C08F4/06 ,  C08F236/10 ,  C08F279/02 ,  C08F4/32 ,  C08F212/00

    摘要： It has been discovered that certain compounds serve as polymerization accelerators when employed together with peroxide initiators for the polymerization of vinylaromatic monomers. Suitable accelerators that increase the rate of decomposition of the peroxide initiator include, but are not necessarily limited to, hydroperoxides and/or metallic salts. Representative examples of suitable hydroperoxide accelerators include t-butyl hydroperoxide (TBH), cumyl hydroperoxide, and p-isopropyl cumyl hydroperoxide, whereas suitable metallic salt accelerators include cobalt naphthenate and cobalt acetoacetonate. Use of these accelerators when vinylaromatic monomers are polymerized in the presence of polybutadienes and peroxide initiators results in an increase in grafting as compared with similar copolymers made without the accelerator.

    摘要翻译： 已经发现，当与过氧化物引发剂一起用于乙烯基芳族单体的聚合时，某些化合物用作聚合促进剂。 增加过氧化物引发剂分解速率的合适的促进剂包括但不限于氢过氧化物和/或金属盐。 合适的氢过氧化物加速剂的代表性实例包括叔丁基过氧化氢（TBH），枯基氢过氧化物和对异丙基异丙基氢过氧化物，而合适的金属盐促进剂包括环烷酸钴和乙酰丙酮酸钴。 当在聚丁二烯和过氧化物引发剂的存在下聚合乙烯基芳族单体时，使用这些促进剂导致与不使用促进剂的类似共聚物相比，接枝增加。

    Controlling particle size in HIPS using metal carboxylates
    20.
    发明申请
    Controlling particle size in HIPS using metal carboxylates 失效
    使用金属羧酸盐控制HIPS中的粒径

    公开(公告)号：US20050090614A1

    公开(公告)日：2005-04-28

    申请号：US10691827

    申请日：2003-10-23

    申请人： Cyril Chevillard ,  Jose Sosa

    发明人： Cyril Chevillard ,  Jose Sosa

    IPC分类号： C08F279/02 ,  C08G63/48 ,  C08F4/00

    CPC分类号： C08F279/02 ,  C08F212/08

    摘要： It has been discovered that certain compounds serve as particle size regulators when employed together with peroxide initiators for the polymerization of vinylaromatic monomers in the presence of diene polymers. Suitable compounds that can control particle size include, but are not necessarily limited to, cobalt naphthenate, zinc naphthenate, iron octoate, calcium octoate, zinc octoate, zinc neodecanoate, potassium octoate, copper naphthenate, calcium versalate, and the like. Use of these metal carboxylates when vinylaromatic monomers are polymerized in the presence of polybutadienes and peroxide initiators results in reduced polybutadiene particles. Grafting and morphology characteristics may also be improved.

    摘要翻译： 已经发现，当与二烯聚合物存在下乙烯基芳族单体聚合时，某些化合物与过氧化物引发剂一起使用时用作粒度调节剂。 可以控制颗粒尺寸的合适的化合物包括但不一定限于环烷酸钴，环烷酸锌，辛酸铁，辛酸钙，辛酸锌，新癸酸锌，辛酸钾，环烷酸铜，三钙酸钙等。 当乙烯基芳族单体在聚丁二烯和过氧化物引发剂存在下聚合时，这些金属羧酸盐的使用导致聚丁二烯颗粒减少。 接枝和形态特征也可以改善。