Method For Producing Epoxide Amine Addition Compounds
    12.
    发明申请
    Method For Producing Epoxide Amine Addition Compounds 审中-公开
    生产环氧胺添加化合物的方法

    公开(公告)号:US20120130013A1

    公开(公告)日:2012-05-24

    申请号:US13321028

    申请日:2010-05-04

    IPC分类号: C08G59/02 C08L75/12 C08G18/58

    CPC分类号: C08G18/581 C08G18/643

    摘要: The present invention relates to a method for the production of addition compounds by converting an epoxide component (A) comprising at least two epoxide functions with at least one amine component (B) comprising a primary amine function in a continuous operation in a reactor, with the epoxide component (A) and the amine component (B) being continuously supplied in a molar ratio from 5:1 to 1:50 such that in the reactor a reaction mixture product develops comprising the epoxide component (A) and the amine component (B), as well as the conversion products from the epoxide component (A) and the amine component (B), which is drained from the reactor in the form of a product flow, with 10-100 mol % of the epoxy functions introduced into the reactor via the epoxide component (A) being converted in the reactor. The addition compounds yielded are preferably used as cross-linking and dispersing agents.

    摘要翻译: 本发明涉及通过在反应器中连续操作中将包含至少两种环氧官能团的环氧化物组分(A)与至少一种包含伯胺官能团的胺组分(B)转化生产加成化合物的方法, 环氧化物组分(A)和胺组分(B)以5:1至1:50的摩尔比连续地供应,使得在反应器中产生包含环氧化物组分(A)和胺组分( B),以及从反应器以产物流形式排出的环氧化物组分(A)和胺组分(B)的转化产物,其中10-100mol%的环氧官能团引入 通过环氧化物组分(A)的反应器在反应器中转化。 产生的加成化合物优选用作交联和分散剂。

    Terminal unsaturated, glycidol-based macromonomers, polymers obtainable therefrom, preparation and use
    17.
    发明授权
    Terminal unsaturated, glycidol-based macromonomers, polymers obtainable therefrom, preparation and use 有权
    末端不饱和,缩水甘油基大分子单体,可从其获得的聚合物,制备和用途

    公开(公告)号:US08987410B2

    公开(公告)日:2015-03-24

    申请号:US13379303

    申请日:2010-06-04

    摘要: Process for preparing a macromonomer, in which a starting compound H2C═CR1—C6H4-s(R4)s—R3—OH or H2C═CR2—CO—NH—R3—OH, where R1 and R2 are each H or a linear or branched alkyl radical having from 1 to 4 carbon atoms, R3 is a linear or branched alkylene, aralkylene radical which has from 1 to 20 carbon atoms and can contain one or more hydroxy groups and the radicals R4 are each, independently of one another, a linear or branched alkyl, aralkyl, alkoxy or aralkoxy radical having from 1 to 20 carbon atoms and s=0-4, is, after partial deprotonation, reacted with at least one hydroxy-functional oxirane compound in the presence of an inhibitor of free-radical polymerization with opening of the oxirane ring, where the molar ratio of the molar amounts used n(starting compound):n(oxirane compound) is in the range from 1:100 to 1:1.Macromonomers which can be obtained by the process, polymers which can be obtained therefrom and their use as additives in coating compositions, plastics and cosmetics.

    摘要翻译: 制备大分子单体的方法,其中起始化合物H2C = CR1-C6H4-s(R4)s-R3-OH或H2C = CR2-CO-NH-R3-OH,其中R1和R2各自为H或直链或 具有1至4个碳原子的支链烷基,R3是具有1至20个碳原子并且可以含有一个或多个羟基的基团的直链或支链亚烷基,亚芳基,并且基团R 4各自彼此独立地为 具有1至20个碳原子且s = 0-4的直链或支链烷基,芳烷基,烷氧基或芳烷氧基是在部分去质子化后与至少一种羟基官能的环氧乙烷化合物在游离 - 使用n(起始化合物):n(环氧乙烷化合物)的摩尔量的摩尔比为1:100〜1:1的环氧乙烷环的开环自由基聚合。 可以通过该方法获得的大分子单体,可从其获得的聚合物及其作为涂料组合物,塑料和化妆品中的添加剂的用途。

    Randomly branched copolymers, preparation thereof and use thereof as levelling agents in coating substances
    19.
    发明授权
    Randomly branched copolymers, preparation thereof and use thereof as levelling agents in coating substances 有权
    无规分支的共聚物,其制备方法及其作为涂层物质中的流平剂的用途

    公开(公告)号:US08642697B2

    公开(公告)日:2014-02-04

    申请号:US13390999

    申请日:2010-07-17

    IPC分类号: C08F2/38 C09D7/06

    摘要: A process for preparing a randomly branched copolymer, by reacting the components (a) 10-98.9 mol % of at least one acrylic ester of a straight-chain, branched or cyclic C1-C22-alkyl monoalcohol, (b) 0.1-10 mol % of at least one polyethylenically unsaturated monomer and (c) optionally one or more monoethylenically unsaturated monomers other than acrylic esters of straight-chain, branched or cyclic C1-C22-alkyl monoalcohols and other than compounds of the formula (I), in the presence of (d) 1-10 mol % of at least one compound of the formula (I) H3C—CRaRc—CH2—CRa—CH2 (I) where Ra, Rb are each independently aryl, CN or COOR1 where R1═H, alkyl, aryl or aralkyl, and Rc=alkyl, aryl or aralkyl, and is the presence of at least one initiator of free-radical polymerization in a free-radical polymerization, where the stated molar proportions of components (a), (b), (c) and (d) add up to 100 mol %, and where the molar proportion of component (b) does not exceed the molar proportion of component (d), Copolymers obtainable by the process and use thereof as levelling agents in coating substances.

    摘要翻译: 通过使成分(a)10-98.9摩尔%的至少一种直链,支链或环状的C 1 -C 22 - 烷基一元醇的丙烯酸酯,(b)0.1-10摩尔的 %的至少一种多烯属不饱和单体和(c)任选的除直链,支链或环状的C 1 -C 22烷基一元醇的丙烯酸酯以外的任何一种或多种单烯属不饱和单体,而不是式 存在(d)1-10摩尔%的至少一种式(I)化合物H3C-CRaRc-CH2-CRa-CH2(I)其中Ra,Rb各自独立地为芳基,CN或COOR1,其中R1 = H, 烷基,芳基或芳烷基,Rc =烷基,芳基或芳烷基,并且是在自由基聚合中存在至少一种自由基聚合引发剂,其中组分(a),(b)的摩尔比例 ,(c)和(d)加到100摩尔%,组分(b)的摩尔比例不超过组分(d ),可通过该方法获得的共聚物及其作为涂层物质中的流平剂的用途。