摘要:
The present invention relates to an electrochemical cell comprising a solid electrolyte conductive for O.sup.2- anions in contact with an anode and a cathode of identical or different composition, the electrolyte solid being comprised of a composition derived from Bi.sub.4 V.sub.2 O.sub.11 of which at least one of the cationic constituent elements is substituted by at least one substituting element chosen such that the gamma phase structural type of Bi.sub.4 V.sub.2 O.sub.11 is maintained, as well as the equilibrium of charges, at least one of the anode or the cathode including two parts, a first part being of a mixed electronic and ionic conductive material in contact with the solid electrolyte, the second part being an electronic conductive material superposed on the first part. The invention equally relates to the use of the electrochemical cell with a view towards the separation or the extraction of oxygen.
摘要:
A process for separating dioxygen from a gaseous mixture containing dioxygen, which entails:a) absorbing dioxygen by one or more transition metal complexes at a low oxidation state of the formula (A):(L.sub.n (M.sup.+p).sub.m (X.sup.-z).sub.x.sup.mp-xz (A) the absorption causing formation of a peroxo dihapto deoxygenated product complex of the formula (B):(L.sub.n '(M.sup.p+2 O.sub.2).sub.m' (X.sup.-z).sub.x).sup.m'p-x'z(B)b) desorbing oxygen from the complex by electrochemically oxidizing the peroxo dihapto product complex obtained by reaction of the complex of the formula (A) wiht O.sub.2 : andc) recovering the absorbed oxygen.
摘要:
A fibrous structure testable in a series of run-off tests, wherein each run-off test includes exposing the fibrous structure to a volume of a test solution and the fibrous structure initially is hydrophobic and has been treated to be hydrophilic, wherein the fibrous structure exhibits a run-off level that is less than 5 percent by weight throughout a series of run-off tests, and wherein the series starts with a first run-off test and ends with a fifth run-off test.
摘要:
Methods for treating polymeric substrates by placing the substrate in a gaseous mixture and subjecting it to a dielectric barrier electrical discharge. The gaseous mixture, which has a pressure around atmospheric, contains a carrier gas, a reducing gas and an oxidizing gas. The amount of the oxidizing gas in the gas mixture is between about 50 ppm and about 2000 ppm by volume, while the amount of the reducing gas in the gas mixture is between about 50 ppm and 30000 ppm by volume.
摘要:
Optimization of an installation in which an operation is performed that requires control over the atmosphere inside a chamber (3), the operation being performed in the presence of a gaseous mixture capable of giving off emissions, the optimization being obtained by the presence of inlet (5) and outlet (8) devices external to the chamber to oppose the ingress of air into the chamber and the exit of gaseous emissions; and of an extraction device (4) comprising means (42) for regulating the flow rate to maintain an approximately zero pressure differential between the inside and the outside of the chamber.
摘要:
A process for the surface treatment of a running substrate by an electrical discharge created between two roller electrodes, comprising a first roller electrode and a second roller electrode, in a gas mixture comprising the steps of passing the substrate in between the two roller electrodes by applying it against the first roller electrode; injecting the gas mixture between the rollers to apply a first surface treatment to the substrate; passing the substrate in between the two roller electrodes by applying it against a second roller electrode; and injecting the gas mixture between the rollers to apply a second surface treatment to the substrate.
摘要:
Novel compounds capable of carrying and releasing nitrogen oxide (NO) in a biological medium, their use for implementing a therapeutic treatment method or a diagnostic method applied to a human or animal body, and for making medicines useful for treating or preventing disorders affecting the human or animal cardiovascular, nervous, immune, renal or pulmonary system, specifically, an organometallic complex of nitrogen oxide, wherein the cationic part is of the formula (I) in which x=0 or 1; x′=2 or 3; y=0, 2 or 3; z=0 or 1; with the condition that, if y=0 (or z=0) then z=0 (or y=0; respectively); R is a group chosen from the group formed by: a hydrogen atom, —(CH2)2COOH and R1, R2, R3 and R4 are groups chosen from the group formed by: a hydrogen atom and alkyl groups comprising from 1 to 4 carbon atoms; and M2+ is a divalent cation Fe++ or Co++.
摘要:
The present invention relates to an electrochemical cell comprising a solid electrolyte which conducts O.sup.2- anions in contact with an anode and a cathode of identical or different composition, the solid electrolyte being comprised of a composition derived from Bi.sub.4 V.sub.2 O.sub.11 of which at least one of the constituent cationic elements is substituted by at least one substituting element such that the gamma phase structural type of Bi.sub.4 V.sub.2 O.sub.11 is maintained as well as the equilibrium of charges, at least one of the anode or of the cathode is a material containing at least one element of substitution of said composition derived from Bi.sub.4 V.sub.2 O.sub.11, that element being in a metallic or cationic state. The invention equally relates to the use of the electrochemical cell with a view towards the separation or extraction of oxygen.