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    Fire retardant polymer
    11.
    发明授权
    Fire retardant polymer 失效
    阻燃聚合物

    公开(公告)号：US4101510A

    公开(公告)日：1978-07-18

    申请号：US775933

    申请日：1977-03-09

    Applicant: James Spanswick

    Inventor： James Spanswick

    IPC: C08K3/00 ,  C08L23/02 ,  C08L25/06 ,  C08L25/18 ,  C08K3/38

    CPC classification number: C08K3/0058 ,  C08L25/06 ,  C08L23/02 ,  C08L25/18

    Abstract: A fire retardant polymer which has a low halogen content is obtained by incorporating a vinyl aromatic containing a group reactive under Friedel-Crafts conditions and a Lewis acid or Lewis acid precursor within a thermoplastic composition.

    Abstract translation: 具有低卤素含量的阻燃聚合物通过在热塑性组合物中掺入在Friedel-Crafts条件下含有基团的乙烯基芳族化合物和路易斯酸或路易斯酸前体而获得。

    Atom transfer radical polymerization process
    14.
    发明授权
    Atom transfer radical polymerization process 有权
    原子转移自由基聚合过程

    公开(公告)号：US08404788B2

    公开(公告)日：2013-03-26

    申请号：US13026919

    申请日：2011-02-14

    Applicant: Krzysztof Matyjaszewski ,  Lindsay Bombalski ,  Wojciech Jakubowski ,  Ke Min ,  Nicolay V. Tsarevsky ,  James Spanswick

    Inventor： Krzysztof Matyjaszewski ,  Lindsay Bombalski ,  Wojciech Jakubowski ,  Ke Min ,  Nicolay V. Tsarevsky ,  James Spanswick

    IPC: C08F4/40

    CPC classification number: C08F265/04 ,  C08F4/40 ,  C08F220/18 ,  C08F265/00 ,  C08F291/00 ,  C08F293/00 ,  C08F293/005 ,  C08F2438/01

    Abstract: Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprises reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.

    Abstract translation: 本发明的聚合方法的实施方案涉及在最初包含至少一种过渡金属催化剂和原子转移自由基聚合引发剂的聚合介质的存在下使可自由基聚合的单体聚合。 聚合介质可另外包含还原剂。 还原剂可以以连续或间歇的方式最初或在聚合过程中加入。 聚合方法可以进一步包括使还原剂与氧化态的至少一种过渡金属催化剂和包含可自由基转移的原子或基团的化合物反应，以形成不显着控制聚合过程的化合物。 本发明的实施方案包括使还原剂与氧化状态的催化剂和包含可自由基转移的原子或基团的化合物中的至少一种反应，以在整个聚合过程中引发和/或维持催化活性。

    Well Defined stars with segmented arms
    15.
    发明申请
    Well Defined stars with segmented arms 审中-公开
    定义明星与分段武器

    公开(公告)号：US20110263722A1

    公开(公告)日：2011-10-27

    申请号：US12799412

    申请日：2010-04-23

    Applicant: Wojciech Jakubowski ,  Patrick McCarthy ,  Nicolay Tsarevsky ,  James Spanswick

    Inventor： Wojciech Jakubowski ,  Patrick McCarthy ,  Nicolay Tsarevsky ,  James Spanswick

    IPC: C08F20/06 ,  A61K47/32

    CPC classification number: A61K47/32 ,  C08F293/005 ,  C08F2438/01

    Abstract: The present invention relates to the preparation and use of well defined star macromolecules wherein the composition of the arms are selected to induce self assembly when the multi-arm segmented star macromolecules are dispersed in a liquid. The self assembled star macromolecules modify the rheology of the dispersing media. When targeting use in aqueous based systems the inner shell of the star macromolecules comprise non-ionizable monomer units. Compositions comprising the self assemblable star macromolecules are suitable for use as rheology modifiers in a number of applications including cosmetic and personal care compositions.

    Abstract translation: 本发明涉及明确定义的星形大分子的制备和用途，其中当多臂分段的星形大分子分散在液体中时，选择臂的组成以诱导自组装。 自组装的星形大分子改变了分散介质的流变性。 当在含水系统中靶向时，星形大分子的内壳包含不可离子化的单体单元。 包含自组装星形大分子的组合物适用于许多应用中的流变改性剂，包括化妆品和个人护理组合物。

    Atom transfer radical polymerization process
    17.
    发明授权
    Atom transfer radical polymerization process 有权
    原子转移自由基聚合过程

    公开(公告)号：US07893174B2

    公开(公告)日：2011-02-22

    申请号：US10591426

    申请日：2005-03-07

    Applicant: Krzysztof Matyjaszewski ,  Lindsay Bombalski ,  Wojciech Jakubowski ,  Ke Min ,  James Spanswick ,  Nicolay V. Tsarevsky

    Inventor： Krzysztof Matyjaszewski ,  Lindsay Bombalski ,  Wojciech Jakubowski ,  Ke Min ,  James Spanswick ,  Nicolay V. Tsarevsky

    IPC: C08F4/40

    CPC classification number: C08F265/04 ,  C08F4/40 ,  C08F220/18 ,  C08F265/00 ,  C08F291/00 ,  C08F293/00 ,  C08F293/005 ,  C08F2438/01

    Abstract: Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprise reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.

    Abstract translation: 本发明的聚合方法的实施方案涉及在最初包含至少一种过渡金属催化剂和原子转移自由基聚合引发剂的聚合介质的存在下使可自由基聚合的单体聚合。 聚合介质可另外包含还原剂。 还原剂可以以连续或间歇的方式最初或在聚合过程中加入。 聚合方法还可包括使还原剂与氧化态的至少一种过渡金属催化剂和包含可自由基转移的原子或基团的化合物反应，以形成不显着控制聚合方法的化合物。 本发明的实施方案包括使还原剂与氧化状态的催化剂和包含可自由基转移的原子或基团的化合物中的至少一种反应，以在整个聚合过程中引发和/或维持催化活性。

    Atom Transfer Radical Polymerization Process
    18.
    发明申请
    Atom Transfer Radical Polymerization Process 有权
    原子转移自由基聚合方法

    公开(公告)号：US20070276101A1

    公开(公告)日：2007-11-29

    申请号：US10591426

    申请日：2005-03-07

    Applicant: Krzysztof Matyjaszewski ,  Lindsay Bombalski ,  Wojciech Jakubowski ,  Ke Min ,  James Spanswick ,  Nicolay Tsarevsky

    Inventor： Krzysztof Matyjaszewski ,  Lindsay Bombalski ,  Wojciech Jakubowski ,  Ke Min ,  James Spanswick ,  Nicolay Tsarevsky

    IPC: C08F251/00 ,  C08F4/06 ,  C08F8/00

    CPC classification number: C08F265/04 ,  C08F4/40 ,  C08F220/18 ,  C08F265/00 ,  C08F291/00 ,  C08F293/00 ,  C08F293/005 ,  C08F2438/01

    Abstract: Embodiments of the polymerization process of the present invention are directed to polymerizing free radically polymerizable monomers in the presence of a polymerization medium initially comprising at least one transition metal catalyst and an atom transfer radical polymerization initiator. The polymerization medium may additionally comprise a reducing agent. The reducing agent may be added initially or during the polymerization process in a continuous or intermittent manner. The polymerization process may further comprise reacting the reducing agent with at least one of the transition metal catalyst in an oxidized state and a compound comprising a radically transferable atom or group to form a compound that does not participate significantly in control of the polymerization process. Embodiments of the present invention comprise reacting a reducing agent with at least one of catalyst in an oxidized state and a compound comprising a radically transferable atom or group to initiate and/or maintain catalytic activity throughout the polymerization process.

    Abstract translation: 本发明的聚合方法的实施方案涉及在最初包含至少一种过渡金属催化剂和原子转移自由基聚合引发剂的聚合介质的存在下使可自由基聚合的单体聚合。 聚合介质可另外包含还原剂。 还原剂可以以连续或间歇的方式最初或在聚合过程中加入。 聚合方法还可包括使还原剂与氧化态的至少一种过渡金属催化剂和包含可自由基转移的原子或基团的化合物反应，以形成不显着控制聚合方法的化合物。 本发明的实施方案包括使还原剂与氧化状态的催化剂和包含可自由基转移的原子或基团的化合物中的至少一种反应，以在整个聚合过程中引发和/或维持催化活性。

    Degradable polymers
    19.
    发明申请
    Degradable polymers 审中-公开
    可降解聚合物

    公开(公告)号：US20070155926A1

    公开(公告)日：2007-07-05

    申请号：US10548354

    申请日：2004-03-29

    Applicant: Krzysztof Matyjaszewski ,  Im Sik Chung ,  Jinyu Huang ,  Traian Sarbu ,  Daniel Siegwart ,  James Spanswick ,  Nicolay Tsarevsky

    Inventor： Krzysztof Matyjaszewski ,  Im Sik Chung ,  Jinyu Huang ,  Traian Sarbu ,  Daniel Siegwart ,  James Spanswick ,  Nicolay Tsarevsky

    IPC: C08F120/00

    CPC classification number: C08L51/08 ,  C08F8/00 ,  C08F8/04 ,  C08F8/12 ,  C08F212/08 ,  C08F220/14 ,  C08F224/00 ,  C08F246/00 ,  C08F277/00 ,  C08F287/00 ,  C08F291/00 ,  C08F293/00 ,  C08F293/005 ,  C08F2438/01 ,  C08F2800/10 ,  C08L33/14 ,  C08L33/24 ,  C08L51/006 ,  C08L53/00 ,  C08L53/005 ,  C08L65/00 ,  C08L2666/02 ,  C08L2666/04 ,  C08F120/14 ,  C08F120/18 ,  C08F112/08

    Abstract: Polymers comprising a polymer backbone comprising one or more degradable units are described. The polymer may additionally comprise two or more polymer segments comprising radically (co)polymerizable vinyl monomer units. The degradable units may be independently selected from, but not limited to, at least one of hydrodegradable, photodegradable and biodegradable units between the polymer segments and dispersed along the polymer backbone. The degradable units may be derived from one or more monomers comprising a heterocyclic ring that is capable of undergoing radical ring opening polymerization, a coupling agent, or from a polymerization initiator, radically polymerizable monomers, as well as other reactive sources. Embodiments of the degradable polymer of claim are capable of degrading by at least one of a hydrodegradation, photodegradation or biodegradation mechanisms to form at least one of telechelic oligomer and telechelic polymeric fragments of the polymer. The degradable polymer may be able to degrade into polymer fragments having a molecular weight distribution of less than 5, or in certain applications it may be preferable for embodiments of the polymer to be capable of forming polymer fragments having a molecular weight distribution of the polymer fragments less than 3.0 or even less than 2.5. Embodiments of the present invention also include methods of producing degradable polymers.

    Abstract translation: 描述了包含包含一个或多个可降解单元的聚合物主链的聚合物。 聚合物可以另外包含两个或更多个包含自由基（共）可聚合的乙烯基单体单元的聚合物链段。 可降解单元可以独立地选自但不限于聚合物链段之间的可分解降解的，可光降解的和可生物降解的单元中的至少一种，并沿着聚合物主链分散。 可降解单元可以衍生自一种或多种包含能够进行自由基开环聚合的杂环，偶联剂或聚合引发剂，可自由基聚合的单体以及其它反应性源的单体。 权利要求中的可降解聚合物的实施方案能够通过加氢降解，光降解或生物降解机理中的至少一种降解以形成聚合物的遥爪低聚物和遥爪聚合物片段中的至少一种。 可降解聚合物可能能够降解为具有小于5的分子量分布的聚合物片段，或者在某些应用中，聚合物的实施方案可优选地形成具有聚合物片段的分子量分布的聚合物片段 小于3.0或甚至小于2.5。 本发明的实施方案还包括生产可降解聚合物的方法。

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