摘要:
Novel bulk tri-metallic catalysts for use in the hydroprocessing of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor containing an organic agent.
摘要:
The instant invention relates to a bulk metal hydrotreating catalyst used for hydrotreating diesel boiling range feedstreams to produce low sulfur diesel products.
摘要:
A reduced or partially reduced nickel-molybdenum catalyst prepared by a process having the steps of 1) reacting nickel carbonate and molybdenum oxide precursors to form nickel molybdate and 2) treating the nickel molybdate under reducing conditions to form the reduced or partially reduced nickel-molybdenum catalyst. There is also a process for making the catalyst. There is also a process for using the catalyst in the hydrogenation of an oxo aldehyde, thereby forming an oxo alcohol of high selectivity. There is also a process for forming an oxo alcohol from the hydroformylation/hydrogenation of an olefinic feedstream. There is also a process for forming an oxo alcohol by contacting formates, dimers, trimers, and organic acids with hydrogen in the presence of a reduced or partially reduced nickel-molybdenum catalyst. The foregoing processes are also useful with a catalyst having the general formula YxZ wherein Y is nickel and/or cobalt and Z is molybdenum and/or tungsten; and wherein x ranges between about 0.25 to about 4.0. There are also reduced or partially reduced catalysts of the general formula NixMo or YxZ wherein x ranges between about 0.25 to about 4.0 and wherein oxide precursors of the catalysts are substantially free of ammonium groups.
摘要:
A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要:
Hydrocarbon feeds are upgraded by contact of the stream under hydrodesulfurization (HDS) conditions with a catalyst system comprising a sulfided, transition metal promoted tungsten/molybdenum HDS catalyst, e.g., Ni/Co--Mo/Al.sub.2 O.sub.3 and a solid acid catalyst which is effective for the isomerization/disproportionation/transalkylation of alkyl substituted, condensed ring heterocyclic sulfur compounds present in the feedstream, e.g. zeolite or a heteropolyacid compound. Isomerization, disproportionation and transalkylation reactions convert refractory sulfur compounds such as 4- or 4,6-alkyl dibenzothiophenes into corresponding isomers or disproportionated isomers which can be more readily desulfurized by conventional HDS catalysts to H.sub.2 S and other products.
摘要翻译:通过加氢脱硫(HDS)条件下的物流与包含硫化的过渡金属促进的钨/钼HDS催化剂(例如Ni / Co-Mo / Al 2 O 3)和固体酸催化剂的催化剂体系接触来提高烃进料,该催化剂体系对于 在进料流中存在的烷基取代的稠环杂环硫化合物的异构化/歧化/烷基转移, 沸石或杂多酸化合物。 异构化,歧化和烷基转移反应将难溶性硫化合物如4-或4,6-烷基二苯并噻吩转化为相应的异构体或歧化异构体,这些异构体可以通过常规的HDS催化剂更容易地脱硫至H 2 S和其它产物。
摘要:
The invention relates to a process for upgrading hydrocarbonaceous feedstreams by hydroprocessing using bulk bimetallic catalysts. More particularly, the invention relates to a catalytic hydrotreating process for the removal of sulfur and nitrogen from a hydrocarbon feed such as a fuel or a lubricating oil feed. The catalyst is a bulk catalyst containing a Group VIII metal and a Group VIB metal.
摘要:
The instant invention relates to a process for producing low sulfur diesel products through the hydrotreating of diesel boiling range feedstreams in the presence of a bulk metal hydrotreating catalyst.
摘要:
The instant invention relates to a process to produce lube oil products through the hydrotreating of lube oil boiling range feedstreams in the presence of a bulk metal hydrotreating catalyst.
摘要:
The instant invention relates to a process to produce liquid products through the hydroprocessing of hydrocarbonaceous feedstreams in the presence of a bulk metal hydroprocessing catalyst.
摘要:
The instant invention relates to a process to produce low sulfur distillate products through the hydrotreating of distillate boiling range feedstreams in the presence of a bulk metal hydrotreating catalyst.