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    Magnetic materials and metallic particles and methods of making same
    11.
    发明授权
    Magnetic materials and metallic particles and methods of making same 失效
    磁性材料和金属颗粒及其制造方法

    公开(公告)号：US07585543B2

    公开(公告)日：2009-09-08

    申请号：US10363996

    申请日：2001-06-19

    Applicant: Johna Leddy ,  Shelley D. Minteer ,  Wayne L. Gellett

    Inventor： Johna Leddy ,  Shelley D. Minteer ,  Wayne L. Gellett

    IPC: B05D7/14

    CPC classification number: B22F1/0062 ,  B03C1/01 ,  B22F1/02 ,  B22F2001/0066 ,  B22F2998/00 ,  H01F1/0027 ,  H01F1/0552 ,  H01F1/0572 ,  H01F1/112 ,  H01F1/20 ,  H01F1/36 ,  H01F41/16 ,  H01M4/8647 ,  H01M4/8817 ,  H01M4/9041 ,  Y10T428/2991 ,  Y10T428/2993

    Abstract: New magnetic materials and new metallic particles, new methods of making and using same, for example, to prepare magnetically modified electrodes and fuel cells, and coated metallic particles in general. The present invention discloses methods of preparation of cheaper and more uniformly sized magnetic and metallic microparticles formed from the exemplary materials magnetite, nickel, samarium cobalt and neodymium iron boron. In addition, the present invention discloses methodology for preparation and use of coated magnetic and metallic microparticles, in particular, exemplary siloxyl coating of magnetic particles, metallic particles, and magnetic and metallic microparticles with an exemplary silane, 3-aminopropyltrimethoxysilane, that is cross linked thereon. In addition, methods and results are described for preparing and using larger siloxyl coated samarium cobalt milliparticles. Coated magnetic milliparticles and magnetic microparticles are useful as component of composites that are applied to electrodes to alter electrochemical fluxes across those electrodes, as well as to alter chemical reactions on surfaces of those electrodes, when magnetically susceptible reactions occur there.

    Abstract translation: 新的磁性材料和新的金属颗粒，新的制造和使用它们的方法，例如制备磁性改性的电极和燃料电池，以及一般涂覆的金属颗粒。 本发明公开了制备由示例性材料磁铁矿，镍，钐钴和钕铁硼形成的更便宜和更均匀尺寸的磁性和金属微粒的方法。 此外，本发明公开了用于制备和使用涂覆的磁性和金属微粒的方法，特别是具有示例性硅烷，3-氨基丙基三甲氧基硅烷的磁性颗粒，金属颗粒和磁性和金属微粒的示例性硅氧烷涂层，其是交联的 上。 此外，描述了制备和使用较大的含有硅氧烷的涂覆的钐钴微粒的方法和结果。 涂覆的磁性微粒和磁性微粒可用作复合材料的组分，其用于电极以改变跨过这些电极的电化学通量，并且当磁性敏感反应发生在那里时，改变这些电极的表面上的化学反应。

    Lanthanide Electrochemistry
    14.
    发明授权
    Lanthanide Electrochemistry 有权

    公开(公告)号：US10196749B2

    公开(公告)日：2019-02-05

    申请号：US14709682

    申请日：2015-05-12

    Applicant: Johna Leddy

    Inventor： Johna Leddy ,  Krysti L. Knoche

    IPC: C25B1/00 ,  C25B9/08 ,  C25C1/22 ,  C25C7/02 ,  C25D3/54 ,  H01M4/92 ,  B01J19/08 ,  H01M12/06 ,  H01M12/08 ,  H01M8/1016 ,  H01M8/1018

    Abstract: Electrochemically reacting a lanthanide or actinide in solvent at a working electrode; wherein the solvent comprises an organic solvent such as acetonitrile which have a dielectric constant of at least three; wherein the solvent system further comprises an electrolyte; wherein the working electrode comprises an ionically conducting or permeable film such as a fluorosulfonate film; wherein at least one ligand such as triflate distinct from the ionically conducting or permeable film is present; wherein the ligand is chemically similar to a structure in the ionically conducting or ionically permeable film; and optionally wherein the electrochemical oxidation or reduction is carried out under the influence of a magnetic field which favorably enhances the reaction. Improved electrochemical methods, identification, and separation can be achieved. Also, an electrochemical device, wherein the device is adapted to employ the oxygen reduction reaction (ORR) at the cathode, wherein the cathode is magnetically modified, or the electrolyte comprises at least one lanthanide or actinide, or both.

    Lanthanide electrochemistry
    15.
    发明授权
    Lanthanide electrochemistry 有权

    公开(公告)号：US10081873B2

    公开(公告)日：2018-09-25

    申请号：US15963457

    申请日：2018-04-26

    Applicant: Johna Leddy

    Inventor： Johna Leddy ,  Krysti L. Knoche

    IPC: C25C1/22 ,  C25B1/00 ,  C25B9/08 ,  H01M12/08 ,  H01M12/06 ,  H01M8/1016 ,  C25C7/02 ,  B01J19/08 ,  C25D3/54 ,  H01M8/1018 ,  H01M4/92

    Abstract: Electrochemically reacting a lanthanide or actinide in solvent at a working electrode; wherein the solvent comprises an organic solvent such as acetonitrile which have a dielectric constant of at least three; wherein the solvent system further comprises an electrolyte; wherein the working electrode comprises an ionically conducting or permeable film such as a fluorosulfonate film; wherein at least one ligand such as triflate distinct from the ionically conducting or permeable film is present; wherein the ligand is chemically similar to a structure in the ionically conducting or ionically permeable film; and optionally wherein the electrochemical oxidation or reduction is carried out under the influence of a magnetic field which favorably enhances the reaction. Improved electrochemical methods, identification, and separation can be achieved. Also, an electrochemical device, wherein the device is adapted to employ the oxygen reduction reaction (ORR) at the cathode, wherein the cathode is magnetically modified, or the electrolyte comprises at least one lanthanide or actinide, or both.

    Magnet incorporated electrically conductive electrodes
    16.
    发明授权
    Magnet incorporated electrically conductive electrodes 有权
    磁体结合导电电极

    公开(公告)号：US07842178B2

    公开(公告)日：2010-11-30

    申请号：US11405268

    申请日：2006-04-17

    Applicant: Johna Leddy ,  Angela Wolf ,  Drew Dunwoody ,  Wayne Gellett ,  Murat Ünlü

    Inventor： Johna Leddy ,  Angela Wolf ,  Drew Dunwoody ,  Wayne Gellett ,  Murat Ünlü

    IPC: C25B11/00 ,  C25B11/04

    CPC classification number: H01F1/083 ,  H01M4/621 ,  H01M4/625 ,  H01M4/74 ,  H01M4/8652

    Abstract: An electrically conducting electrode having a composite and a current collector in electrical contact with the composite, the composite can comprise at least about 10 weight percent electrically conductive particles, at least about 0.5 weight percent magnetic particles, and an optional polymeric binder, wherein composite is at least about 80 weight percent with respect to the combined weight of the electrically conductive particles, the magnetic particles and the binder. Electrochemical systems can effectively use these electrodes to improve system performance.

    Abstract translation: 具有与复合材料电接触的复合材料和集电器的导电电极，所述复合材料可以包含至少约10重量％的导电颗粒，至少约0.5重量％的磁性颗粒和任选的聚合物粘合剂，其中复合材料 相对于导电颗粒，磁性颗粒和粘合剂的组合重量，至少约80重量％。 电化学系统可以有效地利用这些电极来提高系统性能。

    Magnet incorporated electrically conductive electrodes
    17.
    发明申请
    Magnet incorporated electrically conductive electrodes 有权
    磁体结合导电电极

    公开(公告)号：US20070056849A1

    公开(公告)日：2007-03-15

    申请号：US11405268

    申请日：2006-04-17

    Applicant: Johna Leddy ,  Angela Wolf ,  Drew Dunwoody ,  Wayne Gellett ,  Murat Unlu

    Inventor： Johna Leddy ,  Angela Wolf ,  Drew Dunwoody ,  Wayne Gellett ,  Murat Unlu

    IPC: C25B11/04 ,  C25B11/12

    CPC classification number: H01F1/083 ,  H01M4/621 ,  H01M4/625 ,  H01M4/74 ,  H01M4/8652

    Abstract: An electrically conducting electrode having a composite and a current collector in electrical contact with the composite, the composite can comprise at least about 10 weight percent electrically conductive particles, at least about 0.5 weight percent magnetic particles, and an optional polymeric binder, wherein composite is at least about 80 weight percent with respect to the combined weight of the electrically conductive particles, the magnetic particles and the binder. Electrochemical systems can effectively use these electrodes to improve system performance.

    Abstract translation: 具有与复合材料电接触的复合材料和集电器的导电电极，所述复合材料可以包含至少约10重量％的导电颗粒，至少约0.5重量％的磁性颗粒和任选的聚合物粘合剂，其中复合材料 相对于导电颗粒，磁性颗粒和粘合剂的组合重量，至少约80重量％。 电化学系统可以有效地利用这些电极来提高系统性能。

    Methods for forming magnetically modified electrodes and articles produced thereby
    18.
    发明申请
    Methods for forming magnetically modified electrodes and articles produced thereby 审中-公开
    用于形成磁改性电极的方法和由此制备的制品

    公开(公告)号：US20050213187A1

    公开(公告)日：2005-09-29

    申请号：US11130231

    申请日：2005-05-17

    Applicant: Johna Leddy ,  Shelley Minteer

    Inventor： Johna Leddy ,  Shelley Minteer

    IPC: G01N27/26 ,  G02F1/15 ,  G02F1/155

    CPC classification number: G02F1/155

    Abstract: The present invention is directed to methods for making magnetically modified electrodes and electrodes made according to the method. Such electrode are useful as electrodes in batteries, such as Ni-MH batteries, Ni—Cd batteries, Ni—Zn batteries and Ni—Fe batteries.

    Abstract translation: 本发明涉及根据该方法制造磁修饰电极和电极的方法。 这种电极可用作电池中的电极，例如Ni-MH电池，Ni-Cd电池，Ni-Zn电池和Ni-Fe电池。

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