公开(公告)号：US4439598A

公开(公告)日：1984-03-27

申请号：US503463

申请日：1983-06-13

申请人： Bobby J. Sublett ,  Samuel D. Hilbert

发明人： Bobby J. Sublett ,  Samuel D. Hilbert

IPC分类号： C08G63/199 ,  C08G63/54

CPC分类号： C08G63/199

摘要： Poly(tetramethylene terephthalate) modified with an aliphatic dicarboxylic acid having 4-12 carbon atoms and either dimer acid or dimer glycol. This copolyester is blow moldable and is found to have improved resistance to gamma radiation.

摘要翻译： 用具有4-12个碳原子的脂族二羧酸和二聚酸或二聚体二醇改性的聚（对苯二甲酸丁二酯）。 该共聚酯是可吹塑的并被发现具有改善的耐γ辐射性。

公开(公告)号：US4056356A

公开(公告)日：1977-11-01

申请号：US664841

申请日：1976-03-08

申请人： Russell Gilkey ,  Samuel D. Hilbert ,  Bobby J. Sublett ,  Thomas H. Wicker, Jr.

发明人： Russell Gilkey ,  Samuel D. Hilbert ,  Bobby J. Sublett ,  Thomas H. Wicker, Jr.

IPC分类号： D01F6/92 ,  D01F6/62 ,  D01F9/08

CPC分类号： D01F6/92 ,  Y10S8/04 ,  Y10S8/922

摘要： Disclosed is a textile fiber comprised of a poly(oxyethylene)-glycol modified poly(1,4-cyclohexylenedimethylene terephthalate) type polyester containing phosphorus, a stabilizer, an organic titanium compound, and optionally a manganous ion. The fiber exhibits an unobvious combination of commercially acceptable mechanical properties, commercially acceptable lightfastness, commercially acceptable gasfastness, and commercially acceptable dye rate.

摘要翻译： 公开了由含有磷，稳定剂，有机钛化合物和任选的二价锰离子的聚（氧乙烯） - 二醇改性的聚（1,4-环己烯二亚甲基对苯二甲酸酯）型聚酯构成的纺织纤维。 纤维表现出商业上可接受的机械性能，商业上可接受的耐光性，商业上可接受的耐气体性和商业上可接受的染料速率的非显而易见的组合。

公开(公告)号：US5989665A

公开(公告)日：1999-11-23

申请号：US267373

申请日：1999-03-15

申请人： Gary W. Connell ,  Bobby J. Sublett

发明人： Gary W. Connell ,  Bobby J. Sublett

IPC分类号： B65D1/00 ,  B65D81/24 ,  C08G63/181 ,  C08G63/183 ,  C08G63/189 ,  C08J5/18 ,  B29D22/00 ,  C08G63/02

CPC分类号： C08G63/189 ,  C08G63/183 ,  Y10T428/1352 ,  Y10T428/1397 ,  Y10T428/29

摘要： The invention relates to a copolyester having an inherent viscosity ranging from about 0.4 to about 1.4 and a cold crystallization temperature ranging from about 120 to about 160.degree. C. Such copolyesters comprise the reaction product of a glycol component comprising from about 85 to about 100 mole % of 1,3-propanediol, a dibasic acid component comprising from about 85 to about 100 mole % of a dibasic acid selected from terephthalic acid, napthalenedicarboxylic acid, anhydrides, acid chlorides, and lower alkyl esters thereof, and mixtures thereof, and from about 5 to about 15 mole % of a comonomer. The presence of the comonomer lowers the crystallization temperature of the copolyesters according to the invention such that amorphous preforms can be easily molded from the copolyesters. Such amorphous preforms are readily stretch blow molded into bottles or other container shapes or may be injection molded into various shapes or objects or extruded into film or sheeting. Accordingly, in another embodiment of the invention relates to film and containers prepared from the copolyester composition described above. The films and containers according to the invention have improved gas barrier properties such that they may be used for packaging perishable goods, such as beverages, foods, and cosmetics.

摘要翻译： 本发明涉及具有约0.4至约1.4的特性粘度和约120至约160℃的冷结晶温度的共聚多酯。这种共聚酯包含二醇组分的反应产物，其包含约85至约100摩尔 ％的1,3-丙二醇，二元酸组分，其包含约85至约100摩尔％的选自对苯二甲酸，萘二甲酸，酸酐，酰氯和其低级烷基酯的二元酸及其混合物，以及 约5至约15摩尔％的共聚单体。 共聚单体的存在降低了根据本发明的共聚酯的结晶温度，使得非晶预成型体可以容易地从共聚酯模塑。 这种无定型预成型件容易地拉伸吹塑成瓶或其它容器形状，或者可以注塑成各种形状或物体或挤出成膜或片材。 因此，在本发明的另一个实施方案中涉及由上述共聚聚酯组合物制备的膜和容器。 根据本发明的薄膜和容器具有改进的阻气性能，使得它们可用于包装易腐食品，例如饮料，食品和化妆品。

公开(公告)号：US5616404A

公开(公告)日：1997-04-01

申请号：US541746

申请日：1995-10-10

申请人： Bobby J. Sublett

发明人： Bobby J. Sublett

IPC分类号： C08G63/189 ,  C08G63/199 ,  C08J5/18 ,  B32B7/02 ,  C08G63/18

CPC分类号： C08J5/18 ,  C08G63/189 ,  C08G63/199 ,  C08J2367/02 ,  Y10T428/249921 ,  Y10T428/29

摘要： Disclosed are orientable, heat setable, semi-crystalline copolyesters which have high glass transition temperatures. These copolyesters have high heat distortion temperatures along with excellent molding and film properties which makes them useful in packaging materials and molded parts. These copolyesters have repeat units from about 100 mol % 1,4-cyclohexanedimethanol, about 1-99 mol % terephthalic acid and about 99-1 mol % naphthalene dicarboxylic acid.

摘要翻译： 公开了具有高玻璃化转变温度的可取向的，可热固化的半结晶共聚酯。 这些共聚酯具有高的热变形温度以及优异的成型和膜性能，使得它们在包装材料和模制部件中是有用的。 这些共聚酯具有约100摩尔％1,4-环己烷二甲醇，约1-99摩尔％对苯二甲酸和约99-1摩尔％萘二甲酸的重复单元。

公开(公告)号：US5399595A

公开(公告)日：1995-03-21

申请号：US293628

申请日：1994-08-22

申请人： Bobby J. Sublett ,  Richard L. McConnell

发明人： Bobby J. Sublett ,  Richard L. McConnell

IPC分类号： C08J9/04

CPC分类号： C08J9/04 ,  C08J2367/02

摘要： Disclosed are foamable copolyester compositions containing 0.5 to 5.0 mole percent of a dicarboxylic acid sulfomonomer which contains at least one metal sulfonate group attached to an aromatic nucleus. These copolyesters possess high melt viscosity and are readily foamable with a wide range of foaming agents to provide low density shaped articles, films, and sheets.

摘要翻译： 公开了含有0.5至5.0摩尔％的含有至少一个连接到芳香核上的金属磺酸盐基团的二羧酸磺基单体的可发泡共聚酯组合物。 这些共聚酯具有高的熔融粘度，并且可以用宽范围的发泡剂容易地发泡，以提供低密度成形的制品，薄膜和薄片。

公开(公告)号：US5013820A

公开(公告)日：1991-05-07

申请号：US337231

申请日：1989-04-12

申请人： Jimmy R. Trotter ,  Bobby J. Sublett

发明人： Jimmy R. Trotter ,  Bobby J. Sublett

IPC分类号： C08G63/181 ,  C08G63/189 ,  C08G63/42 ,  C08G63/78 ,  C08G63/82 ,  C08G63/87

CPC分类号： C08G63/42 ,  C08G63/189 ,  C08G63/87

摘要： This invention relates to a method of preparing poly(ethylene 2,6-naphthalene dicarboxylate) by the polycondensation reaction of ethylene glycol and dimethyl-2,6-naphthalene dicarboxylate, using a dimethyl-2,6-naphthalene dicarboxylate starting material which contains significant amounts of methyl hydrogen 2,6-naphthalene dicarboxylate as a contaminant. The methyl hydrogen 2,6-naphthalene dicarboxylate moiety is incorporated into the polymer structure by initially esterifying the methyl hydrogen 2,6-naphthalene dicarboxylate acid end-group with ethylene carbonate, in the presence of an amine or ammonium catalyst, before the polyesterification/polycondensation reaction is performed.

公开(公告)号：US4352925A

公开(公告)日：1982-10-05

申请号：US207818

申请日：1980-11-17

申请人： Frederick D. Petke ,  Bobby J. Sublett ,  Richard L. McConnell

发明人： Frederick D. Petke ,  Bobby J. Sublett ,  Richard L. McConnell

IPC分类号： B65D5/00 ,  C08G63/00 ,  C08G63/66 ,  C08G63/672 ,  C09J167/00 ,  C08G63/18

CPC分类号： C08G63/672 ,  Y10T428/31786 ,  Y10T428/3179

摘要： Disclosed are heat-resistant adhesive compositions comprising a copolyester derived from terephthalic acid, from about 30 to about 50 mol % diethylene glycol, and at least 50 mol % ethylene glycol, the polyester having an inherent viscosity of from about 0.4 to about 1.0. The composition is especially useful in bonding parts of ovenable food containers.

摘要翻译： 公开了耐热粘合剂组合物，其包含衍生自对苯二甲酸的共聚酯，约30至约50摩尔％的二甘醇和至少50摩尔％的乙二醇，所述聚酯的特性粘度为约0.4至约1.0。 该组合物特别可用于粘合可烘烤食品容器的部分。

公开(公告)号：US4299933A

公开(公告)日：1981-11-10

申请号：US155807

申请日：1980-06-02

申请人： Richard L. McConnell ,  Jimmy R. Trotter ,  Bobby J. Sublett

发明人： Richard L. McConnell ,  Jimmy R. Trotter ,  Bobby J. Sublett

IPC分类号： C08G63/00 ,  C09D167/02 ,  C09J167/02 ,  D06M17/04 ,  D06M17/06 ,  C08L67/00

CPC分类号： D06M17/06 ,  C08G63/00 ,  C09D167/02 ,  C09J167/02 ,  D06M17/04 ,  Y10T428/2852 ,  Y10T442/2738

摘要： Disclosed are compositions comprising a copolyester of(A) at least one aromatic or saturated aliphatic or cycloaliphatic dibasic acid having 4 to 36 carbon atoms,(B) from about 2 to about 40%, based on the weight of the copolyester, of a carboxylated polyolefin selected from the group consisting of (1) oxidized polyolefins and (2) the reaction product of(a) at least one homo or copolymer of an .alpha.- olefin having from 2 to 10 carbon atoms and(b) at least one unsaturated acid or anhydride having from 3 to 5 carbon atoms or a 1 to 10 carbon atom alkyl ester thereof, and(C) at least one saturated aliphatic or cycloaliphatic glycol having from 2 to 12 carbon atoms,the copolyester having a crystalline melting point of about 70.degree.-200.degree. C. and an I.V. of about 0.2-1.6. These compositions are especially useful as coatings and adhesives.

摘要翻译： 公开了包含（A）至少一种具有4至36个碳原子的芳族或饱和脂族或脂环族二元酸的共聚酯，（B）约2-约40重量％，基于共聚酯的重量，羧化的 选自（1）氧化聚烯烃的聚烯烃和（2）（a）至少一种具有2至10个碳原子的α-烯烃的均聚物或共聚物的反应产物和（b）至少一种不饱和酸 或具有3至5个碳原子的酸酐或其1至10个碳原子的烷基酯，和（C）至少一种具有2至12个碳原子的饱和脂族或脂环族二醇，所述共聚酯的结晶熔点为约70 DEG -200℃，IV 约0.2-1.6。 这些组合物特别可用作涂料和粘合剂。

公开(公告)号：US06287656B1

公开(公告)日：2001-09-11

申请号：US09726478

申请日：2000-12-01

申请人： S. Richard Turner ,  Gary W. Connell ,  Bobby J. Sublett

发明人： S. Richard Turner ,  Gary W. Connell ,  Bobby J. Sublett

IPC分类号： B29D2200

CPC分类号： C08G63/6886 ,  A61L29/06 ,  A61L31/06 ,  C08J5/18 ,  C08J2367/02 ,  Y10T428/1352 ,  Y10T428/249921 ,  Y10T428/29 ,  C08L67/04

摘要： Amorphous copolyesters containing residues derived from 2,2′-[2,2-](sulfonylbis(4,1-phenyleneoxy))bis(ethanol). They exhibit enhanced heat distortion temperatures and glass transition temperatures without a significant increase in viscosity at low shear rates. The amorphous copolyesters also have improved resistance to attack by lipid solutions and are readily molded and extruded to form medial devices such as connectors, tubes, etc. which are useful for transport of lipids and other medical solutions.

摘要翻译： 含有衍生自2,2' - [2,2 - ]（磺酰基双（4,1-亚苯氧基））双（乙醇）的残基的无定形共聚酯。 它们在低剪切速率下表现出增强的热变形温度和玻璃化转变温度，而不显着增加粘度。 无定形共聚酯也具有改善的抵抗脂质溶液的抵抗性，并且易于模制和挤出以形成可用于脂质和其它医疗溶液运输的中间装置，例如连接器，管等。

公开(公告)号：US06183848B2

公开(公告)日：2001-02-06

申请号：US09453922

申请日：2000-04-28

申请人： S. Richard Turner ,  Bobby J. Sublett ,  Gary W. Connell

发明人： S. Richard Turner ,  Bobby J. Sublett ,  Gary W. Connell

IPC分类号： B32B702

CPC分类号： C08F255/04 ,  C08F255/02 ,  C08G63/6886 ,  C08J5/18 ,  C08J2367/02 ,  Y10T428/249921 ,  Y10T428/29 ,  C08F222/06

摘要： An amorphous copolyester having a maximum melt viscosity at 1 radian/second and at about 260 to about 290° C. of about 12000 poise, a glass transition temperature ranging from about 88° C. to about 120° C., and an inherent viscosity of at least about 0.6 dl/g. The amorphous copolyesters comprise the reaction product of a diol component and a dicarboxylic acid component. The diol component comprises residues of from about 5.0 to about 50 mole % of 2,2′-(sulfonylbis (4,1-phenyleneoxy))-bis(ethanol) which has the following chemical formula: and from about 50 to about 95 mole % of a mixture of at least two diols selected from the group consisting of ethylene glycol, neopentyl glycol, 1,3-propanediol, 1,4-butanediol, 1,4-cyclohexanedimethanol, and mixture thereof. The dicarboxylic acid component comprises residues of terephthalic acid, isophthalic acid, 1,4-cyclohexandedicarboxylic acid, 2,6-naphthalene dicarboxylic acid and mixtures thereof. The amorphous copolyesters according to the invention have relatively low melt viscosities and relatively high glass transition temperatures. Because of the low melt viscosities and high glass transition temperatures, copolyesters with increased IV or molecular weight can easily be obtained. The copolyesters according to the invention can be used for molded or extruded articles, sheets, and films. Accordingly, the invention also relates to molded and extruded articles, sheets, and films made from a copolyester as described above. Additionally, articles, sheets, and films according to the invention have improved gas barrier properties such that they may be used for packaging perishable goods, such as beverages, foods and cosmetics, as well as other oxygen sensitive products such as inks and adhesives.

摘要翻译： 无定形共聚酯，其熔体粘度为1弧度/秒，约260至290℃，熔点约为12000泊，玻璃化转变温度范围为约88℃至约120℃，特性粘度 至少约0.6dl / g。 无定形共聚酯包括二醇组分和二羧酸组分的反应产物。 二醇组分包括具有以下化学式的2,2'-（磺酰基双（4,1-亚苯氧基）） - 双（乙醇）的约5.0-约50摩尔％的残基和约50-约95摩尔 ％的至少两种选自乙二醇，新戊二醇，1,3-丙二醇，1,4-丁二醇，1,4-环己烷二甲醇及其混合物的二醇的混合物。 二羧酸组分包括对苯二甲酸，间苯二甲酸，1,4-环己二羧酸，2,6-萘二甲酸及其混合物的残留物。 根据本发明的无定形共聚酯具有相对低的熔体粘度和相对较高的玻璃化转变温度。 由于熔体粘度低和玻璃化转变温度高，因此可以容易地获得IV或分子量增加的共聚酯。 根据本发明的共聚酯可用于模制或挤出制品，片材和薄膜。 因此，本发明还涉及由如上所述的共聚酯制成的模制和挤压制品，片材和薄膜。 此外，根据本发明的制品，片材和薄膜具有改进的阻气性能，使得它们可用于包装易腐食品，例如饮料，食品和化妆品，以及其它氧敏感产品如油墨和粘合剂。