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11.发明授权
公开(公告)号：US4849186A
公开(公告)日：1989-07-18
申请号：US935374
申请日：1986-11-26
CPC分类号： C07C2/12 , C10G29/16 , C07C2529/40 , F02B3/06 , Y10S203/06
摘要： An oligomerization system is provided for upgrading lower olefins to distillate hydrocarbons, especially useful as high quality jet or diesel fuels. Thye olefinic feedstock is reacted over a shape selective acid zeolite, such as ZSM-5, to oligomerize feedstock olefins and further convert recycled hydrocarbons. Reactor effluent is fractionated to recover a light-middle distillate range product stream and to obtain gasoline and heavy hydrocarbon streams for recycle.
摘要翻译： 提供了一种低聚体系，用于将低级烯烃升级成馏分烃，特别适用于高质量的喷气或柴油燃料。 烯烃原料在形状选择性酸性沸石（如ZSM-5）上反应，使原料烯烃低聚并进一步转化回收的烃。 将反应器流出物分馏以回收轻 - 中馏分范围的产物流并获得用于再循环的汽油和重烃流。
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公开(公告)号：US4634798A
公开(公告)日：1987-01-06
申请号：US779369
申请日：1985-09-23
申请人： Hartley Owen , Samuel A. Tabak , Bernard S. Wright
发明人： Hartley Owen , Samuel A. Tabak , Bernard S. Wright
CPC分类号： C07C2/62 , C07C1/20 , C10G3/49 , C10L1/06 , C07C2527/1206 , C07C2529/06 , C07C2529/40 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/20 , Y02P30/42
摘要： Alkylate is produced by catalytically converting oxygenate feedstock, such as methanol, to lower olefins comprising C.sub.2 -C.sub.4 olefins. Ethene is separated by interstage sorption of C.sub.3 + components and an isoparaffin is alkylated with C.sub.3 -C.sub.4 olefins.The improved technique comprises fractionating an olefinic feedstream containing ethene and C.sub.3 + olefinic components by contacting the olefinic feedstream in a sorption zone with a liquid hydrocarbon sorbent to selectively sorb C.sub.3 + components; reacting C.sub.3 + olefins with excess isoparaffin in a catalytic alkylation reactor to produce C.sub.7 + alkylate hydrocarbons; fractionating the alkylation reactor effluent to provide a liquid hydrocarbon fraction rich in C.sub.4 + isoparaffin for recycle to the sorption zone as lean sorbent; and recovering C.sub.7 + alkylate product from the process.
摘要翻译： 烷基化物通过将含氧化合物原料如甲醇催化转化成包含C 2 -C 4烯烃的低级烯烃来制备。 乙烯通过C3 +组分的级间吸附分离，异链烷烃用C 3 -C 4烯烃烷基化。 改进的技术包括通过使吸附区中的烯烃进料流与液体烃吸附剂接触以选择性吸附C3 +组分来分馏含有乙烯和C3 +烯烃组分的烯烃进料流; 在催化烷基化反应器中使C3 +烯烃与过量的异链烷烃反应生成C7 +烷基化烃; 分馏烷基化反应器流出物以提供富含C 4 +异链烷烃的液体烃馏分，作为贫吸附剂再循环至吸附区; 并从该过程中回收C7 +烷基化产物。
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公开(公告)号：US4633028A
公开(公告)日：1986-12-30
申请号：US779367
申请日：1985-09-23
申请人： Hartley Owen , Samuel A. Tabak , Bernard S. Wright
发明人： Hartley Owen , Samuel A. Tabak , Bernard S. Wright
CPC分类号： C10L1/06 , C07C9/16 , C10G3/49 , C07C2527/1206 , C07C2529/06 , C07C2529/40 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2400/02 , C10G2400/20
摘要： Alkylate is produced by catalytically converting oxygenate feedstock, such as methanol, to lower olefins comprising C.sub.2 -C.sub.4 olefins. Ethene is separated by interstage sorption of C.sub.3 + components and an isoparaffin is alkylated with C.sub.3 -C.sub.4 olefins derived from sorbate.The improved technique comprises fractionating an olefinic feedstream containing ethene and C.sub.3 + olefinic components by contacting the olefinic feedstream in a sorption zone with a liquid hydrocarbon sorbent to selectively sorb C.sub.3 + components; reacting C.sub.3 + olefins with excess isoparaffin in a catalytic alkylation reactor to produce C.sub.7 + alkylate hydrocarbons; fractionating the alkylation reactor effluent to provide a liquid hydrocarbon fraction rich in C.sub.7 +, alkylate for recycle to the sorption zone as lean sorbent; and recovering C.sub.7 + alkylate product and C.sub.5 + gasoline from the process.
摘要翻译： 烷基化物通过将含氧化合物原料如甲醇催化转化成包含C 2 -C 4烯烃的低级烯烃来制备。 乙烯通过C3 +组分的级间吸附分离，异链烷烃用来自山梨酸酯的C3-C4烯烃烷基化。 改进的技术包括通过使吸附区中的烯烃进料流与液体烃吸附剂接触以选择性吸附C3 +组分来分馏含有乙烯和C3 +烯烃组分的烯烃进料流; 在催化烷基化反应器中使C3 +烯烃与过量的异链烷烃反应生成C7 +烷基化烃; 分馏烷基化反应器流出物以提供富含C 7+的烷烃馏分，作为贫吸附剂再循环到吸附区; 并从该过程中回收C7 +烷基化物产物和C5 +汽油。
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公开(公告)号：US4568786A
公开(公告)日：1986-02-04
申请号：US709143
申请日：1985-03-07
摘要： Olefin upgrading in plural reactors can achieve conversion of lower olefinic feedstock, such as propene, butene, etc., to valuable heavy hydrocarbons containing a lubricant fraction of high viscosity index. Other fuel products, such as (C.sub.10 -C.sub.20) distillate, gasoline and LPG may also be recovered as products. In a preferred process for converting lower olefinic feed to heavier hydrocarbons by contacting the feed with a shape selective medium pore acidic zeolite catalyst at elevated temperature and pressure the catalyst surface is rendered relatively inactive by adding to the olefinic feed an inactivating amount of a sterically-hindered organic base, whereby the catalyst is selectively surface-deactivated, to produce substantially linear heavier hydrocarbons rich in C.sub.10.sup.+ olefins. In the preferred multi-stage process the olefinic feed comprises C.sub.2 -C.sub.8 olefins and the catalyst employed in each stage comprises aluminosilicate having a silica-to-alumina mole ratio of at least 12 and a constraint index of about 1 to 12.
摘要翻译： 在多个反应器中的烯烃升级可以实现将低级烯烃原料如丙烯，丁烯等转化成含有高粘度指数的润滑剂部分的有价值的重烃。 其他燃料产品，如（C10-C20）馏出物，汽油和LPG也可作为产品回收。 在优选的方法中，通过使进料与形状选择性中孔孔酸性沸石催化剂在升高的温度和压力下接触来将低级烯烃进料转化成较重的烃，通过向烯烃进料中加入灭活量的空间位阻，使催化剂表面相对无活性， 受阻的有机碱，其中催化剂被选择性地表面失活，以产生富含C10 +烯烃的基本上线性的较重的烃。 在优选的多级方法中，烯烃进料包含C 2 -C 8烯烃，并且在每个阶段中使用的催化剂包含二氧化硅与氧化铝的摩尔比至少为12，约束指数为约1至12的硅铝酸盐。
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公开(公告)号：US4560537A
公开(公告)日：1985-12-24
申请号：US641245
申请日：1984-08-16
申请人： Samuel A. Tabak
发明人： Samuel A. Tabak
CPC分类号： C10G69/02 , C07C1/20 , C07C2529/40 , Y02P20/52 , Y02P30/42
摘要： An integrated system is provided for converting methanol or the like to heavy hydrocarbon products, especially distillate range hydrocarbons. In a first stage catalytic process oxygenate feedstock is converted to lower olefins. Byproduct aromatics are passed through a second stage oligomerization reactor with olefins. Distillate range hydrocarbons are recovered and hydrotreated to provide an improved fuel product.
摘要翻译： 提供了一种用于将甲醇等转化为重质烃产物，特别是馏出物烃类的集成系统。 在第一阶段中，催化过程将含氧化合物原料转化为低级烯烃。 副产物芳烃通过具有烯烃的第二级低聚反应器。 蒸馏馏分烃被回收和加氢处理以提供改进的燃料产物。
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公开(公告)号：US4487985A
公开(公告)日：1984-12-11
申请号：US526852
申请日：1983-08-26
申请人： Samuel A. Tabak
发明人： Samuel A. Tabak
CPC分类号： C07C2/12 , C10G50/00 , C07C2529/40 , Y02P20/584
摘要： A reactor sequencing technique is useful for multi-stage hydrocarbon conversion systems employing a number of fixed bed catalytic reactors at various process temperatures and catalytic activity levels. A process for oligomerizing lower olefins (e.g., C.sub.2 -C.sub.6) is disclosed wherein catalyst partially inactivated in a primary stage is employed to effect conversion at higher temperature in a secondary stage prior to catalyst regeneration.
摘要翻译： 反应器测序技术可用于在各种工艺温度和催化活性水平下使用多个固定床催化反应器的多级烃转化系统。 公开了低级烯烃（例如C 2 -C 6）的低聚方法，其中在初级阶段部分灭活的催化剂用于在催化剂再生之前的次级中在较高温度下进行转化。
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17.发明授权Production of gasoline from light olefins with FCC gas plant improvement by olefin upgrading 失效通过烯烃升级生产FCC轻油烯烃汽油改善汽油
公开(公告)号：US4831204A
公开(公告)日：1989-05-16
申请号：US133772
申请日：1987-12-16
IPC分类号： C07C11/02
CPC分类号： C07C11/02
摘要： A continuous technique for upgrading light olefinic crackate gas from hydrocarbon cracking comprising methods and means for: (a) compressing and cooling a first portion of the light crackate gas to provide a first pressurized ethene-rich vapor stream and a first condensed crackate stream rich in C.sub.3.sup.+ aliphatics; (b) contacting said first ethene-rich vapor stream under pressure with a C.sub.5 + liquid sorbent stream in a gas-liquid contact absorber column under sorption conditions to selectively absorb a major amount of C.sub.3.sup.+ components; (c) recovering a second ethene-rich vapor stream overhead from the absorber column; (d) converting said second ethene-rich vapor stream in a reaction zone in once-through contact with a fluidized bed of said medium pore zeolite catalyst solid particles under oligomerization conditions to produce an olefinic hydrocarbon effluent stream rich in C.sub.5 + hydrocarbons; (e) cooling and separating the reaction effluent stream to provide a light offgas stream and a condensed liquid hydrocarbon product stream; (f) fractionating the condensed liquid hydrocarbon product stream in the absorber column concurrently with sorption of the first ethene-rich vapor stream for recovery of liquid hydrocarbon product with an absorber bottoms liquid stream rich in C.sub.3.sup.+ components; (g) further fractionating the absorber bottoms liquid stream to provide a C.sub.3 -C.sub.4 product and a liquid hydrocarbon fraction consisting essentially of C.sub.5.sup.+ hydrocarbons; (h) recycling at least a portion of the C.sub.5.sup.+ liquid hydrocarbon fraction to the absorber column as the liquid sorbent stream; and bypassing a second portion of said light crackate gas around said absorber to the reaction zone for conversion concurrently with said second ethene-rich vapor stream.
摘要翻译： 一种用于从烃裂解中提取轻质烯属裂化气体的连续技术，包括以下步骤的方法和装置：（a）压缩和冷却轻质裂化气体的第一部分，以提供富含第一加压的富含乙烯的蒸气流和富含第 C3 +脂肪 （b）在吸附条件下，使气体 - 液体接触吸收塔中的压力下的所述第一富乙烯蒸气流与气液接触吸收塔中的C5 +液体吸附剂流接触以选择性地吸收大量的C3 +组分; （c）从吸收塔塔顶回收第二富含乙烯的蒸汽流; （d）在低聚条件下与所述中孔沸石催化剂固体颗粒的流化床在反应区中转化所述第二富乙烯蒸气流，以产生富含C5 +烃的烯烃排出物流; （e）冷却和分离反应流出物流以提供轻质废气流和冷凝液态烃产物流; （f）吸收吸收塔中的冷凝液体烃产物流与吸附第一富含乙烯的蒸气流同时回收具有富含C3 +组分的吸收塔底液流的液态烃产物; （g）进一步对吸收塔底液流进行分馏以提供基本上由C5 +烃组成的C3-C4产物和液态烃馏分; （h）将至少一部分C5 +液体烃馏分循环至吸收塔作为液体吸附剂流; 并且绕所述吸收器周围的所述轻质裂化气体的第二部分绕过所述反应区，以与所述第二富乙烯蒸气流同时转化。
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18.发明授权Integrated production of gasoline from light olefins in a fluid cracking process plant 失效在流体裂解过程工厂从轻质烯烃综合生产汽油
公开(公告)号：US4831203A
公开(公告)日：1989-05-16
申请号：US133771
申请日：1987-12-16
申请人： Hartley Owen , Samuel A. Tabak
发明人： Hartley Owen , Samuel A. Tabak
IPC分类号： C10G57/02
CPC分类号： C10G57/02
摘要： Separation and recovery of liquid hydrocarbons in a FCC gas plant is improved by integrating therewith a catalytic bed oligomerization reactor which produces predominantly olefinic liquid hydrocarbons from at least one olefinic stream within the gas plant.
摘要翻译： 通过与催化床低聚反应器整合来改善FCC气体装置中的液体烃的分离和回收，催化床低聚反应器主要产生来自气体装置内的至少一个烯烃的烯烃液体烃。
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19.发明授权Process for removing oxygenated compounds or other impurities from hydrocarbon streams 失效从烃流中除去氧化化合物或其他杂质的方法
公开(公告)号：US4686317A
公开(公告)日：1987-08-11
申请号：US815342
申请日：1985-12-31
申请人： Richard J. Quann , Samuel A. Tabak
发明人： Richard J. Quann , Samuel A. Tabak
CPC分类号： C07C1/0485 , C10G21/00
摘要： A process for removing oxygenated impurities from a hydrocarbon stream includes extracting said oxygenates by a heavy organic polar solvent, water scrubbing the extracted hydrocarbon to recover dissolved solvent and combining the solvent phase from the extractor and the water phase from the scrubber and distilling to recover the solvent.
摘要翻译： 从烃流中除去含氧杂质的方法包括通过重的有机极性溶剂萃取所述含氧化合物，水洗涤所提取的烃以回收溶解的溶剂并将来自萃取器的溶剂相和来自洗涤器的水相组合并蒸馏以回收 溶剂。
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公开(公告)号：US4658073A
公开(公告)日：1987-04-14
申请号：US884844
申请日：1986-07-11
申请人： Samuel A. Tabak
发明人： Samuel A. Tabak
IPC分类号： C10G3/00 , C07C1/20 , C07C2/12 , C07C2/62 , C07C9/16 , C10G50/00 , C10G57/02 , C10L1/06 , C07C2/00
CPC分类号： C07C1/20 , C07C2/12 , C07C2/62 , C07C9/16 , C10L1/06 , C07C2527/1206 , C07C2529/04 , C07C2529/06 , C07C2529/40 , C10G2300/1092 , C10G2300/4081 , C10G2400/02 , C10G2400/20 , Y02P20/582 , Y02P30/20 , Y02P30/42 , Y10S208/01 , Y10S585/956
摘要： A process control technique for upgrading C.sub.3 -C.sub.4 hydrocarbon feed containing olefins to produce heavier liquid hydrocarbons comprising converting a major portion of C.sub.3 -C.sub.4 olefins in an oligomerization zone by contacting a shape selective medium pore zeolite catalyst at elevated temperature and pressure to make distillate and olefinic gasoline. The oligomerization stage effluent is fractionated to provide distillate and gasoline product and a C.sub.3 -C.sub.4 intermediate stream containing isobutane and unconverted propene and butylene. The C.sub.3 -C.sub.4 intermediate stream is combined under control with a portion of C.sub.3 -C.sub.4 feed and further converting the combined streams in an alkylation zone to make heavier paraffinic hydrocarbons. The olefin feed may be produced by catalytically converting methanol or similar oxygenated hydrocarbons in a known process. Controlled material balance is achieved by accumulating liquid olefin feed to the oligomerization and akylation units using a surge drum with liquid level control. By-product isobutane is recovered and recycled under liquid level control operatively connected to determine feed of liquid olefin to the conversion units.
摘要翻译： 包括用于升级含有烯烃的C 3 -C 4烃进料以产生较重液体烃的过程控制技术，包括通过在升高的温度和压力下接触形状选择性中孔沸石催化剂来在低聚区域中转化大部分C 3 -C 4烯烃，以制备馏出物和 烯烃汽油。 将低聚阶段流出物分馏以提供馏出物和汽油产物以及含有异丁烷和未转化的丙烯和丁烯的C 3 -C 4中间体流。 C3-C4中间体流在C3-C4进料的一部分控制下合并，并进一步转化在烷基化区中的混合物流，以制备较重的链烷烃。 烯烃进料可以通过在已知方法中催化转化甲醇或类似的氧化烃来制备。 通过使用具有液位控制的缓冲鼓将液体烯烃进料聚集到低聚物和烷基化单元中来实现受控材料平衡。 副产物异丁烷在操作连接的液位控制下回收和循环，以确定液体烯烃向转化单元的进料。
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