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    Hard waxes comprising terpolymers of ethylene with unsaturated carboxylic acids and unsaturated carboxylic acid esters
    11.
    发明授权
    Hard waxes comprising terpolymers of ethylene with unsaturated carboxylic acids and unsaturated carboxylic acid esters 失效
    硬蜡包括乙烯与不饱和羧酸和不饱和羧酸酯的三元共聚物

    公开(公告)号：US4406705A

    公开(公告)日：1983-09-27

    申请号：US349159

    申请日：1982-02-16

    申请人： Dieter Oeder ,  Wolfram Dietsche ,  Stefan Weiss ,  Walter Ziegler ,  Albert Hettche

    发明人： Dieter Oeder ,  Wolfram Dietsche ,  Stefan Weiss ,  Walter Ziegler ,  Albert Hettche

    IPC分类号： C08F210/00 ,  C08F210/02 ,  C09G1/00 ,  D06M15/263 ,  C08L91/06

    CPC分类号： C08F210/02

    摘要： Water-emulsifiable hard waxes consisting of homogeneous terpolymers of ethylene with--based on weight of terpolymer--from 1 to 8% by weight of C.sub.3 -C.sub.8 -olefinically unsaturated carboxylic acids and from 0.5 to 10% by weight of C.sub.1 -C.sub.12 -alkyl esters of such unsaturated carboxylic acids and having a Staudinger index, determined according to DIN 53,728, of from 5 to 55, an acid number of from 8 to 62 and a Hoppler hardness, measured by DFG standard method M-III-9a(57), at 23.degree. C., of from 250 to 800 bar, are obtained by copolymerizing ethylene with olefinically unsaturated C.sub.3 -C.sub.8 -carboxylic acids and esters of such acids with C.sub.1 -C.sub.12 -alkanols in a continuous process in the presence of a free radical initiator at from 150.degree. to 300.degree. C. under a pressure of from 1,000 to 3,000 bar, using a weight ratio of ethylene:acid:acrylate of from 500:1:1 to 20:1:1, in a one-phase polymerization medium in which the monomers are soluble, in the presence of from 0.01 to 8% by weight, based on the sum of the monomers, of a regulator, from 3 to 25% by weight of the ethylene being converted and the copolymer formed being removed continuously from the reaction zone.

    摘要翻译： 由均相的三元共聚物组成的水可乳化的硬蜡，其基于三元共聚物的重量 - 1至8重量％的C 3 -C 8 - 烯属不饱和羧酸和0.5至10重量％的C 1 -C 12烷基酯 的这种不饱和羧酸，并且根据DIN 53,728测定的Staudinger指数为5至55，酸值为8至62，Höppler硬度通过DFG标准方法M-III-9a（57）测量， 通过在自由基引发剂存在下，在连续方法中将乙烯与烯属不饱和C 3 -C 8 - 羧酸和这些酸的酯与C 1 -C 12 - 链烷醇共聚获得，其熔点为23℃， 在1000-3000巴的压力下，使用乙烯：酸：丙烯酸酯的重量比为500:1:1至20:1:1的单相聚合介质 其中单体可溶，在0.01至8重量％的存在下，基于 单体，调节剂，3至25重量％的乙烯被转化，形成的共聚物从反应区连续除去。

    Pyrazoline compounds
    13.
    发明授权
    Pyrazoline compounds 失效
    吡唑啉化合物

    公开(公告)号：US4183851A

    公开(公告)日：1980-01-15

    申请号：US913949

    申请日：1978-06-09

    申请人： Manfred Patsch ,  Albert Hettche

    发明人： Manfred Patsch ,  Albert Hettche

    IPC分类号： C07D231/06 ,  C07D231/12 ,  C07D401/12

    CPC分类号： C07D231/06 ,  C07D231/12

    摘要： Pyrazoline compounds of the formula (I): ##STR1## in which each of B.sup.1 or B.sup.5 is hydrogen or C.sub.1 to C.sub.4 alkyl;R.sup.1 is hydrogen, alkyl or hydroxy;R.sup.2, R.sup.3, R.sup.5, R.sup.6 and R.sup.7 independently of one another are hydrogen, chloro, bromo, fluoro, methyl, ethyl, methoxy or ethoxy;R.sup.4 is hydrogen, alkyl, benzyl, phenylethyl or also phenyl optionally bearing chloro, bromo, methyl, ethyl, methoxy, ethoxy, cyano, dialkylamino or SO.sub.3 H as a substituent;X is --O--, --S--, --NR.sup.8 --, --NR.sup.8 CO--, --NR.sup.8 --SO.sub.2 --, --OSO.sub.3 -- or --SO.sub.3 --;R.sup.8 is hydrogen, alkyl or alkyl bearing hydroxy or C.sub.1 to C.sub.4 alkoxy as a sbustituent;A is hydrogen, sodium, potassium, unsubstituted or substituted ammonium, unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl; and--NR.sup.8 -- and A together may be an optionally quaternized saturated or unsaturated heterocyclic ring.The compounds are eminently suitable as optical brighteners for example for acrylonitrile polymers, wool and polyamides.

    摘要翻译： 式（I）的吡唑啉化合物：其中B 1或B 5各自为氢或C 1至C 4烷基; R1是氢，烷基或羟基; R 2，R 3，R 5，R 6和R 7彼此独立地是氢，氯，溴，氟，甲基，乙基，甲氧基或乙氧基; R4是氢，烷基，苄基，苯基乙基，或者也可以是含有氯，溴，甲基，乙基，甲氧基，乙氧基，氰基，二烷基氨基或SO3H作为取代基的苯基; X是-O - ， - S - ， - NR 8 - ， - NR 8 CO-， - NR 8 -SO 2 - ， - SO 3 - 或-SO 3 - ; R8是氢，具有羟基的烷基或烷基或作为取代基的C1-C4烷氧基; A是氢，钠，钾，未取代或取代的铵，未取代或取代的烷基，环烷基，芳烷基或芳基; 并且-NR 8 - 和A一起可以是任选季铵化的饱和或不饱和杂环。 该化合物特别适用于例如丙烯腈聚合物，羊毛和聚酰胺的荧光增白剂。

    Pyrazoline compounds
    14.
    发明授权
    Pyrazoline compounds 失效
    吡唑啉化合物

    公开(公告)号：US4129563A

    公开(公告)日：1978-12-12

    申请号：US702975

    申请日：1976-07-06

    申请人： Manfred Patsch ,  Albert Hettche

    发明人： Manfred Patsch ,  Albert Hettche

    IPC分类号： C07D231/06 ,  C07D231/12 ,  C09B57/00 ,  D21H21/30 ,  C07D401/12

    CPC分类号： C07D231/06 ,  C07D231/12 ,  D21H21/30

    摘要： Pyrazoline compounds of the formula (I): ##STR1## in which EACH OF B.sup.1 to B.sup.5 is hydrogen or C.sub.1 to C.sub.4 alkyl;R.sup.1 is hydrogen, alkyl or hydroxy;R.sup.2, r.sup.3, r.sup.5, r.sup.6 and R.sup.7 independently of one another are hydrogen, chloro, bromo, fluoro, methyl, ethyl, methoxy or ethoxy;R.sup.4 is hydrogen, alkyl, benzyl, phenylethyl or also phenyl optionally bearing chloro, bromo, methyl, ethyl, methoxy, ethoxy, cyano, dialkylamino or SO.sub.3 H as a substituent;X is --O--, --S--, --NR.sup.8 --, --NR.sup.8 CO--, --NR.sup.8 --SO.sub.2 --, --OSO.sub.3 -- or --SO.sub.3 --;R.sup.8 is hydrogen, alkyl or alkyl bearing hydroxy or C.sub.1 to C.sub.4 alkoxy as a substituent;A is hydrogen, sodium, potassium, unsubstituted or substituted ammonium, unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl; and--NR.sup.8 -- and A together may be an optionally quaternized saturated or unsaturated heterocyclic ring.The compounds are eminently suitable as optical brighteners for example for acrylonitrile polymers, wool and polyamides.

    摘要翻译： 式（I）的吡唑啉化合物：其中每个B 1至B 5为氢或C 1至C 4烷基; R1是氢，烷基或羟基; R 2，R 3，R 5，R 6和R 7彼此独立地是氢，氯，溴，氟，甲基，乙基，甲氧基或乙氧基; R4是氢，烷基，苄基，苯基乙基，或者也可以是含有氯，溴，甲基，乙基，甲氧基，乙氧基，氰基，二烷基氨基或SO3H作为取代基的苯基; X是-O - ， - S - ， - NR 8 - ， - NR 8 CO-， - NR 8 -SO 2 - ， - SO 3 - 或-SO 3 - ; R8是氢，烷基或烷基，带有羟基或C1-C4烷氧基作为取代基; A是氢，钠，钾，未取代或取代的铵，未取代或取代的烷基，环烷基，芳烷基或芳基; 并且-NR 8 - 和A一起可以是任选季铵化的饱和或不饱和杂环。

    Washing agents containing, as additives, carboxyl-containing copolymers which are neutralized or amidated with amines
    16.
    发明授权
    Washing agents containing, as additives, carboxyl-containing copolymers which are neutralized or amidated with amines 失效
    作为添加剂含有用胺中和或酰胺化的含羧基共聚物的洗涤剂

    公开(公告)号：US4702858A

    公开(公告)日：1987-10-27

    申请号：US888957

    申请日：1986-07-24

    申请人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Erhard Klahr ,  Albert Hettche

    发明人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Erhard Klahr ,  Albert Hettche

    IPC分类号： C08F8/32 ,  C08F8/44 ,  C11D3/37

    CPC分类号： C11D3/3761 ,  C11D3/3769

    摘要： Washing agents contain, as additives for inhibiting redeposition and promoting the primary washing action, homopolymers of acrylic acid and of methacrylic acid, copolymers of acrylic acid and methacrylic acid and copolymers which contain, as essential components,(a) an ethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms and(b) acrylic acid, methacrylic acid and/or hydroxy-C.sub.2 -C.sub.6 -alkyl esters of ethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids as copolymerized units,where the homo- and copolymers in the form of the free acids have a weight average molecular weight of from 5000 to 500,000 in the neutralized or amidated form, the carboxyl groups of the homo- and copolymers in each case being partially or completely neutralized with amines of the formula ##STR1## where R is C.sub.8 -C.sub.18 -alkyl or R.sup.1 --O--CH.sub.2 --(CH.sub.2).sub.n --, n is from 1 to 3, R.sup.1 is C.sub.1 -C.sub.18 -alkyl, R.sup.2 and R.sup.3 are each H or C.sub.1 -C.sub.18 -alkyl and/or from 5 to 50% of the said carboxyl groups being in the form of amides derived from primary and secondary amines of the formula I.

    摘要翻译： 洗涤剂含有作为抑制再沉积和促进初次洗涤作用的添加剂，丙烯酸和甲基丙烯酸的均聚物，丙烯酸和甲基丙烯酸的共聚物以及含有作为必要成分的（a）烯属不饱和二羧酸 4至6个碳原子，和（b）丙烯酸，甲基丙烯酸和/或烯属不饱和C 3 -C 6 - 羧酸的羟基-C 2 -C 6烷基酯作为共聚单元，其中以自由基形式存在的均聚物和共聚物 酸的中和或酰胺化形式的重均分子量为5000至500,000，每种情况下的均聚物和共聚物的羧基用式“IMAGE”的胺部分或完全中和，其中R为C8-C18 - 烷基或R 1 -O-CH 2 - （CH 2）n - ，n为1至3，R 1为C 1 -C 18烷基，R 2和R 3各自为H或C 1 -C 18 - 烷基和/或5至50％ 的所述羧基为衍生自原料的酰胺形式 芳胺和仲胺。

    Additives for detergents and cleaning agents
    17.
    发明授权
    Additives for detergents and cleaning agents 失效
    洗涤剂和清洁剂的添加剂

    公开(公告)号：US4698174A

    公开(公告)日：1987-10-06

    申请号：US822610

    申请日：1986-01-27

    申请人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Albert Hettche ,  Rolf Schneider ,  Hans-Juergen Raubenheimer

    发明人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Albert Hettche ,  Rolf Schneider ,  Hans-Juergen Raubenheimer

    IPC分类号： C11D3/33 ,  C11D3/37

    CPC分类号： C11D3/33 ,  C11D3/3761

    摘要： Pulverulent and/or granular additives for pulverulent detergents and cleaning agents, consisting of(a) from 80 to 20% by weight of one or more copolymers comprising from 40 to 90% by weight of (meth)acrylic acid and from 60 to 10% by weight of maleic acid and/or one or more copolymers comprising from 10 to 45% by weight of (meth)acrylic acid, from 10 to 45% by weight of maleic acid and from 10 to 60% by weight of one or more hydroxyalkyl (meth)acrylates where hydroxyalkyl is of 2 to 6 carbon atoms, if appropriate in the form of a partially or completely neutralized water-soluble salt,(b) from 20 to 80% by weight of nitrilotriacetic acid or its mono-, di- or trisodium or mono-, di- or tripotassium salt and(c) from 0 to 20% by weight of one or more additives conventionally used for detergent and cleaning agent formulations, the use of these pulverulent and/or granular mixtures as additives for pulverulent and/or granular detergents and cleaning agents, and processes for the preparation of the said additives.

    摘要翻译： 用于粉状洗涤剂和清洁剂的粉末和/或颗粒添加剂由（a）80至20重量％的一种或多种共聚物组成，所述共聚物包含40至90重量％的（甲基）丙烯酸和60至10重量％ 的马来酸和/或一种或多种共聚物，其包含10至45重量％的（甲基）丙烯酸，10至45重量％的马来酸和10至60重量％的一种或多种羟烷基 （甲基）丙烯酸酯，其中羟基烷基为2至6个碳原子，如果合适的话以部分或完全中和的水溶性盐的形式，（b）20至80重量％的次氮基三乙酸或其单 - 或三钠或单，二或三钾盐和（c）0至20重量％的常规用于洗涤剂和清洁剂配方的一种或多种添加剂，使用这些粉状和/或颗粒状混合物作为粉末状添加剂 和/或颗粒状洗涤剂和清洁剂，以及制备方法 n的所述添加剂。

    Manufacture of very pure halonaphthalic acid anhydrides
    18.
    发明授权
    Manufacture of very pure halonaphthalic acid anhydrides 失效
    制造非常纯的卤代二氢酸酐

    公开(公告)号：US4207255A

    公开(公告)日：1980-06-10

    申请号：US850239

    申请日：1977-11-10

    申请人： Wolfgang Eisfeld ,  Walter Disteldorf ,  Albert Hettche

    发明人： Wolfgang Eisfeld ,  Walter Disteldorf ,  Albert Hettche

    IPC分类号： C07D311/92 ,  C07C51/31 ,  C07C63/34

    CPC分类号： C07C51/316

    摘要： Pure halonaphthalic acid anhydrides are prepared from haloacenaphthenes by oxidation with nitric acid in a mixture of aliphatic carboxylic acid, water and nitric acid in the presence of vanadate, with or without further metal salts, at an elevated temperature and the reaction product is isolated and subjected to an oxidative after-treatment with hypochlorite in aqueous solution at a pH of from 9 to 12 at an elevated temperature. The products are intermediates for the manufacture of optical brighteners.

    摘要翻译： 纯的卤代邻苯二甲酸酐通过在酸酐存在下，在有或者没有其它金属盐的情况下，用硝酸在脂族羧酸，水和硝酸的混合物中进行氧化由卤代苊制备，并将反应产物分离并进行 在升高的温度下在pH为9至12的水溶液中用次氯酸盐进行氧化后处理。 该产品是制造荧光增白剂的中间体。