Abstract:
A light emitting device that includes a light emitting element having a peak emission wavelength at 400-480 nm and a fluorescent member can be provided. The fluorescent member includes a first fluorescent material that includes a nitride containing alkaline-earth metal, alkali metal, aluminium and europium, a second fluorescent material that includes a nitride containing alkaline-earth metal, aluminium, silicon and europium, and a third fluorescent material having a peak emission wavelength in a range of from 500 nm to 560 nm. A content of the first fluorescent material to a total content of the first fluorescent material and the second fluorescent material is from 5% by mass to 95% by mass.
Abstract:
A light emitting device includes a light emitting element, a molded member, and a sealing member. The light emitting element is arranged on or above the molded member. The sealing member covers the light emitting element. The sealing member contains a phosphor, and a filler material. The phosphor can be excited by light of the light emitting element, and emit luminescent radiation. The filler material contains neodymium hydroxide, neodymium aluminate or neodymium silicate. The filler material absorbs a part of the spectrum of the mixed light of the light emitting element and the phosphor so that the other parts of the spectrum of this mixed light are extracted from the light emitting device.
Abstract:
Provided are a red light emitting fluorescent material excellent in durability, and a method for producing the red light emitting fluorescent material. The present disclosure provides a method for producing a fluoride fluorescent material that includes subjecting a mixture that contains a fluoride in a liquid medium to a pressurization treatment and a heating treatment, the fluoride having a chemical composition represented by the following formula (I). The present disclosure also provides a fluoride fluorescent material that exhibits a rate of decrease in light-emitting energy efficiency is 5% or less after the fluoride fluorescent material is irradiated with laser light having a wavelength of 445 nm at an optical density of 3.5 W/cm2 for 300 seconds, and has a chemical composition represented by the following formula (I). A2[M1-aMn4+aF6] (I) In the formula (I), A represents at least one cation selected from the group consisting of K+, Li+, Na+, Rb+, Cs+ and NH4+, M represents at least one element selected from the group consisting of Group 4 elements and Group 14 elements, and a represents a number that satisfies 0
Abstract:
A phosphor is provided which is represented by the general formula MxCeySi6−zBzN8+w. M is at least one element selected from the group consisting of La, Y, Tb and Lu. And w, x, y, and z satisfy 2.0
Abstract:
Provided are silicon-containing aluminum nitride particles having a high reflectance, a method for producing the same, and a light emitting device. In certain embodiment, silicon-containing aluminum nitride particles having a total amount of aluminum and nitrogen of 90% by mass or more, a content of silicon in a range of 1.5% by mass or more and 4.0% by mass or less, and a content of oxygen in a range of 0.5% by mass or more and 2.0% by mass or less, and having an average reflectance in a wavelength range of 380 nm or more and 730 nm or less of 85% or more.
Abstract:
Disclosed are a production method for a nitride fluorescent material, a nitride fluorescent material and a light emitting device. The production method is for producing a nitride fluorescent material that has, as a fluorescent material core, a calcined body having a composition containing at least one element Ma selected from the group consisting of Sr, Ca, Ba and Mg, at least one element Mb selected from the group consisting of Li, Na and K, at least one element Mc selected from the group consisting of Eu, Ce, Tb and Mn, and Al, and optionally Si, and N, and the method includes preparing a calcined body having the above-mentioned composition, bringing the calcined body into contact with a fluorine-containing substance, and subjecting it to a first heat treatment at a temperature of 100° C. or higher and 500° C. or lower to form a fluoride-containing first film on the calcined body, and forming on the calcined body, a second film that contains a metal oxide containing at least one metal element M2 selected from the group consisting of Si, Al, Ti, Zr, Sn and Zn and subjecting it to a second heat treatment at a temperature in a range of higher than 250° C. and 500° C. or lower.
Abstract:
A method for producing a nitride fluorescent material having high emission luminance can be provided. The method includes heat-treating a raw material mixture containing silicon nitride, silicon, an aluminium compound, a calcium compound, and a europium compound.
Abstract:
Disclosed are an aluminate fluorescent material having a high light emission intensity, and a light emitting device using the same. The aluminate fluorescent material includes a composition represented by the following formula (I). X1pEutMgqMnrAlsOp+t+q+r+1.5s (I) wherein X1 represents at least one element selected from the group consisting of Ba, Sr, and Ca; and p, q, r, s, and t each satisfy 0.5≤p≤1.0, 0≤q
Abstract:
Provided is a rare earth aluminate fluorescent material and a method of producing the same. The rare earth aluminate fluorescent material contains at least one rare earth element Ln selected from the group consisting of Y, La, Lu, Gd, and Tb; Ce; Al; and optionally at least one element M1 selected from Ga and Sc, wherein a total molar ratio of the rare earth element Ln and Ce is 3, a total molar ratio of Al and the element M1 is a product of 5 and a parameter k in a range of 0.95 or more and 1.05 or less, and a molar ratio of Ce is a product of a parameter n in a range of 0.003 or more and 0.017 or less and 3, and wherein a light emission peak wavelength λp (nm) at an excitation wavelength of 450 nm and the parameter n satisfy λp≥1590n+531.
Abstract:
Disclosed are a production method for a nitride fluorescent material, a nitride fluorescent material and a light emitting device. The production method is for producing a nitride fluorescent material that has, as a fluorescent material core, a calcined body having a composition containing at least one element Ma selected from the group consisting of Sr, Ca, Ba and Mg, at least one element Mb selected from the group consisting of Li, Na and K, at least one element Mc selected from the group consisting of Eu, Ce, Tb and Mn, and Al, and optionally Si, and N, and the method includes preparing a calcined body having the above-mentioned composition, bringing the calcined body into contact with a fluorine-containing substance, and subjecting it to a first heat treatment at a temperature of 100° C. or higher and 500° C. or lower to form a fluoride-containing first film on the calcined body, and forming on the calcined body, a second film that contains a metal oxide containing at least one metal element M2 selected from the group consisting of Si, Al, Ti, Zr, Sn and Zn and subjecting it to a second heat treatment at a temperature in a range of higher than 250° C. and 500° C. or lower.