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公开(公告)号：US06482522B1
公开(公告)日：2002-11-19
申请号：US08994378
申请日：1997-12-19
IPC分类号： B32B2700
CPC分类号： B32B27/08 , B32B25/04 , C08J5/12 , C08L19/003 , Y10T156/1089 , Y10T428/1352 , Y10T428/3154 , Y10T428/31544
摘要： A method for increasing the adhesion of a first layer comprising a fluoropolymer substantially free of interpolymerized units derived from vinylidene fluoride to a second layer comprising a curable elastomer is described. The method comprises adding a dehydrofluorinating composition to the curable elastomer, contacting the layers and curing the layered article so formed. The resulting multilayer compositions and articles are also disclosed.
摘要翻译： 描述了一种用于增加包含基本上不含衍生自偏二氟乙烯的共聚单元的含氟聚合物的第一层与包含可固化弹性体的第二层的粘合力的方法。 该方法包括向可固化弹性体中加入脱氟化氢组合物，使层接触并固化如此形成的层状制品。 还公开了所得的多层组合物和制品。
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公开(公告)号：US4894410A
公开(公告)日：1990-01-16
申请号：US165936
申请日：1988-03-09
IPC分类号： C08J3/24 , C08F8/34 , C08F14/18 , C09D127/12
CPC分类号： C08F8/34 , C08F2810/20
摘要： This invention provides fluorine-containing polymers having at least one thioorgano group. These polymers are prepared by reacting a fluoropolymer precursor with one or more, organic, thiolate compounds thereby modifying the fluoropolymer precursor by grafting onto its backbone the thioorgano groups. Said thioorgano groups may contain functional moieties that modify the cure properties, bulk, properties or compatibility of the thioorgano fluoropolymer precursor. This invention also provides shaped or formed cured articles, coatings and solutions comprising the thioorgano fluoropolymers, and blends thereof with other compatible polymers.
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公开(公告)号：US4287320A
公开(公告)日：1981-09-01
申请号：US122513
申请日：1980-02-19
申请人： Robert E. Kolb
发明人： Robert E. Kolb
摘要： A diorgano sulfur oxide is included in a curable vinylidene fluoride elastomer formulation to provide desirable curing characteristics.
摘要翻译： 二有机硫氧化物包括在可固化偏二氟乙烯弹性体配方中以提供所需的固化特性。
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14.发明授权Fluoropolymer compositions containing a nitrogen cure site monomer and a sulfone or sulfoxide compound 失效含有氮固化位点单体和砜或亚砜化合物的含氟聚合物组合物公开(公告)号：US06887927B2
公开(公告)日：2005-05-03
申请号：US10228507
申请日：2002-08-27
CPC分类号： C08F14/18 , C08K5/0025 , C08L27/12
摘要： Compositions comprising a fluoropolymer derived from a nitrogen-containing cure site monomer, a catalyst composition which comprises at least one anionic functional group and at least one cationic functional group having the formula QR′k(+), wherein Q is selected from phosphorous, sulfur, nitrogen, arsenic, or antimony, wherein each R′ is independently selected from hydrogen and a nonfluorinated, partially fluorinated, or perfluorinated, C1-C20 alkyl, aryl, aralkyl, or alkenyl group, and wherein k is the valence of Q plus one; wherein the catalyst composition is a compound or the precursors thereof added separately or as a mixture; and a composition of the formula: R″2SOx wherein each R″ is C1-C30 alkyl, aralkyl, the two R″ groups together form a heterocyclic C3-C30 cycloalkyl, aryl, or aralkyl, each R″ can be fluorinated, and x is 1 or 2. Also provided are methods of making a fluoropolymer and fluoropolymer articles containing fluoropolymer compositions.
摘要翻译： 包含衍生自含氮固化位点单体的含氟聚合物的组合物，包含至少一个阴离子官能团的催化剂组合物和至少一种具有式QR'（+ ）其中Q选自磷，硫，氮，砷或锑，其中每个R'独立地选自氢和非氟化，部分氟化或全氟化的C 1 H 2， -C 20烷基，芳基，芳烷基或烯基，其中k是Q + 1的化合价; 其中所述催化剂组合物是分别或作为混合物加入的化合物或其前体; 和式“R”2 SO x x的组合物，其中每个R“为C 1 -C 30 - ， - 烷基，芳烷基，两个R“基团一起形成杂环C 3 -C 30 - 环烷基，芳基或芳烷基，每个R”可以被氟化， 并且x是1或2.还提供了制备含氟聚合物组合物的含氟聚合物和含氟聚合物制品的方法。
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公开(公告)号：US06803425B2
公开(公告)日：2004-10-12
申请号：US10122487
申请日：2002-04-11
IPC分类号： C08F814
CPC分类号： C08F16/24 , C08F214/18 , C08F214/262 , C08J5/18
摘要： A composition comprising (a) a fluoropolymer having pendant imidate groups, which imidate groups have the formula: —C═NH(OR) wherein R is a C1-C10 aliphatic group which aliphatic group may have F or Cl substituents; and optionally, (b) a perfluorovinyl ether of the general formula: CF2═CFO(R′fO)a(R″fO)bRf wherein R′f and R″f are the same or are different C1-C6 linear or branched perfluoroalkylene groups; a and b are, independently, 0 or an integer from 1 to 10; and Rf is a C1-C8 perfluoroalkyl group or a C1-C15 perfluoroalkoxy group. Also provided are a method of making a fluoropolymer composition and curable and cured articles comprising a fluoropolymer composition.
摘要翻译： 一种组合物，其包含（a）具有亚酰氨基侧基的含氟聚合物，所述亚胺基具有下式：-C = NH（OR），其中R是C1-C10脂族基团，该脂族基团可以具有F或Cl取代基; 和（b）通式CF 2 = CFO（R'fO）a（R“f O）b R f的全氟乙烯基醚，其中R'f和R''f相同或不同，C1-C6直链或 支链全氟亚烷基; a和b独立地为0或1〜10的整数; Rf为C1-C8全氟烷基或C1-C15全氟烷氧基。 还提供了制备包含含氟聚合物组合物的含氟聚合物组合物和可固化和固化的制品的方法。
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16.发明授权Process for preparing a multi-layer article having a fluoroplastic layer and an elastomer layer 失效制备具有氟塑料层和弹性体层的多层制品的方法公开(公告)号：US06773755B2
公开(公告)日：2004-08-10
申请号：US09980749
申请日：2001-11-15
IPC分类号： B05D138
CPC分类号： C08J7/047 , B05D1/265 , B05D3/0254 , B05D5/083 , B05D7/02 , B05D7/542 , B29C47/0004 , B29C47/0021 , B29C47/0023 , B29C47/0026 , B29C47/0066 , B29C47/021 , B29C47/025 , B29C47/04 , B29C47/065 , B29C47/28 , B29K2023/16 , B29K2027/16 , B29K2027/18 , B29K2995/0015 , B29L2023/22 , B29L2031/712 , B32B25/08 , C08J2321/00 , C08J2427/00
摘要： A method for enhancing the bond strength between a VDF-containing fluoroplastic layer and an elastomer layer of a multi-layer article. A VDF-containing fluoroplastic composition is applied to the surface of a precursor article that includes a curable elastomer layer to form a fluoroplastic layer. Prior to application of the fluoroplastic composition, the curable elastomer layer is thermally insulated to prevent it from undergoing substantial heating. Following application, the fluoroplastic layer is heated and the curable elastomer layer is cured (e.g., thermally cured). Preferably, the elastomer cure occurs separately from and subsequent to heating the fluoroplastic layer. The combination of thermally insulating the curable elastomer layer prior to application of the fluoroplastic composition and heating the fluoroplastic layer following application of the fluoroplastic composition results in formation of a strong bond between the fluoroplastic and elastomer layers upon cure.
摘要翻译： 一种用于增强含VDF的氟塑料层与多层制品的弹性体层之间的结合强度的方法。 将含VDF的氟塑料组合物施加到包含可固化弹性体层的前体制品的表面以形成氟塑料层。 在施加氟塑料组合物之前，将可固化的弹性体层进行绝热以防止其发生实质的加热。 在施加之后，加热氟塑料层并固化可固化的弹性体层（例如热固化）。 优选地，弹性体固化与氟塑料层的加热分开并随后发生。 在施加氟塑料组合物之前将可固化弹性体层热绝缘并在施加氟塑料组合物之后加热氟塑料层的组合导致在固化后在氟塑料和弹性体层之间形成强结合。
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公开(公告)号：US06657012B2
公开(公告)日：2003-12-02
申请号：US09951921
申请日：2001-09-11
IPC分类号： C08F21400
CPC分类号： C08K5/3465 , C08L27/12
摘要： A composition that includes: (a) a fluoropolymer comprising interpolymerized units derived from a cure site monomer comprising a nitrile group; and (b) a catalyst composition comprising a divalent metal amine complex compound having the formula: where M is a divalent metal, X is an anionic group, and n is 2 to 6, as well as a method for curing this composition and cured articles prepared from this composition.
摘要翻译： 一种组合物，其包含：（a）包含衍生自包含腈基的固化位点单体的共聚单元的含氟聚合物; 和（b）包含具有下式的二价金属胺络合物的催化剂组合物，其中M是二价金属，X是阴离子基团，n是2-6，以及固化该组合物和固化物的方法 从这种组合物制备。
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公开(公告)号：US06465576B1
公开(公告)日：2002-10-15
申请号：US09608367
申请日：2000-06-30
IPC分类号： C08L2722
CPC分类号： C08F214/262 , C08K5/0025 , C08L27/12
摘要： A fluoroelastomer composition having improved compression set. The fluoroelastomer composition comprises: (1) a fluoroelastomer containing interpolymerized units of at least one perfluoroolefin, at least one perfluorovinyl ether, and a cure site component capable of participation in a peroxide cure reaction; (2) an additive selected from the group consisting of organo-oniums, phosphates, phosphine oxides, amine oxides, alkyl amines, and heterocyclic amines and salts of heterocyclic amines; (3) a peroxide curative, and (4) optionally a coagent.
摘要翻译： 一种具有改进的压缩永久变形的含氟弹性体组合物。 含氟弹性体组合物包含：（1）含有至少一种全氟烯烃，至少一种全氟乙烯基醚和能够参与过氧化物固化反应的固化部位组分的含有共聚单元的含氟弹性体; （2）选自有机鎓，磷酸盐，氧化膦，氧化胺，烷基胺和杂环胺的添加剂和杂环胺的盐; （3）过氧化物固化剂，和（4）任选的助剂。
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公开(公告)号：US06346328B1
公开(公告)日：2002-02-12
申请号：US09329686
申请日：1999-06-10
IPC分类号： B32B2508
CPC分类号： B32B27/08 , B32B1/08 , B32B7/10 , B32B27/28 , B32B27/304 , B32B27/322 , B32B27/34 , B32B27/38 , C08J5/121 , Y10T428/31507 , Y10T428/3154 , Y10T428/31544 , Y10T428/31573 , Y10T428/31576 , Y10T428/3158 , Y10T428/31728 , Y10T428/31732 , Y10T428/31743 , Y10T428/31746 , Y10T428/3175 , Y10T428/31797 , Y10T428/31909 , Y10T428/31913 , Y10T428/31928 , Y10T428/31935 , Y10T428/31938
摘要： A composite article is provided which includes a fluoropolymer intimately bonded to a component including a substantially non-fluorinated thermoplastic having pendant phenolic groups in combination with a base. Increased adhesion is observed by a greater peel strength value between the fluoropolymer component and a non-fluorinated thermoplastic having pendant phenolic groups.
摘要翻译： 提供了一种复合制品，其包括与包含与碱组合的侧基酚基的基本上非氟化的热塑性塑料紧密结合的组分。 通过含氟聚合物组分和具有侧基酚基团的非氟化热塑性塑料之间较大的剥离强度值观察到增加的附着力。
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20.发明授权Fluoroelastomer compositions containing fluoroaliphatic sulfonamides as curing agents 失效含氟脂族磺酰胺作为固化剂的氟弹性体组合物
公开(公告)号：US5086123A
公开(公告)日：1992-02-04
申请号：US619669
申请日：1990-11-28
IPC分类号： C08K5/43
CPC分类号： C08K5/43
摘要： Vulcanizable fluorocarbon elastomer compositions containing a vinylidene fluoride copolymer and a fluoroaliphatic sulfonamide curing agent. A second curing agent selected from organic polyhydroxy compounds or derivatives thereof, and an organo-onium accelerator are also employed. The compositions of this invention can be used to prepare shaped articles that exhibit high tensile strength accompanied by high elongation and a low value of compression set.
摘要翻译： 含有偏氟乙烯共聚物和氟代脂族磺酰胺固化剂的可硫化氟碳弹性体组合物。 还可以使用选自有机多羟基化合物或其衍生物的第二种固化剂和有机鎓促进剂。 本发明的组合物可用于制备具有高拉伸强度并具有高伸长率和低压缩变形值的成型制品。
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