摘要:
The invention relates to a method for producing modified lignocellulosic materials. Said method consists of the following steps a) the lignocellulosic material is impregnated with an aqueous composition which contains i) at least one cross-linkable nitrogen compound and ii) at least one substance which catalyses the cross-linking, b) the impregnated lignocellulosic materials are treated at higher temperatures in order to remove the water and to cross-link the cross-linkable nitrogen compound. In step b) the impregnated lignocellulosic material is treated with overheated steam. The invention also relates to lignocellulosic materials which are obtained according to said method.
摘要:
The present invention relates to a solvent-free pigmented formulation comprising I) a binder based on at least one copolymer P in an aqueous polymer dispersion obtainable by free-radical aqueous emulsion polymerization of a monomer mixture containing a) from 45 to 69.95% by weight of at least one monomer a) whose homopolymer has a glass transition temperature Tg of less than 20° C., b) from 30 to 54.95% by weight of at least one monomer b) whose homopolymer has a glass transition temperature Tg of more than 50° C., c) from 0.05 to 1.5% by weight of itaconic acid and/or its anhydride and/or its salts, as acidic monomer c), and d) from 0 to 2% by weight of at least one further monomer d), the sum of the % by weight of a) to d) being 100% by weight, II) at least one pigment, III) at least one pigment dispersant having an acid number to DIN 53402 of less than 600, IV) if desired, an inorganic filler, and V) customary auxiliaries.
摘要:
The thermoplastic, isocyanate-free polyurethane which contains acidic groups, is soluble in tetrahydrofuran, has a molecular weight of from 15,000 to 70,000 and is composed ofA) 1 mol of a polyol having a molecular weight of from 400 to 4000,B) from 0.3 to 9 mol of a mixture ofB1) if required, a diol of 2 to 18 carbon atoms andB2) from 0.03 to 0.4 mol of a diol having at least one acidic group,C) from 0 to 1 mol of a polyol having 3 to 18 carbon atoms and at least 3 OH groups,D) from 1.25 to 13 mol of a diisocyanate of 6 to 30 carbon atoms andE) from 0 to 1 mol of a primary or secondary amino alcohol of 2 to 16 carbon atoms,the molar ratio of the OH and any NH groups present in the sum of the components A, B, C and E to the NCO groups of component D being from 0.98 to 1.4, is obtainable by reacting the above components in the melt and is suitable in particular as a binder for magnetic recording media.
摘要:
Polymers I suitable as dispersing resins are obtained by reactingA. a polymer II obtained by reacting at least one compound III selected from the group consisting ofa) an ester IV ofa1) an .alpha.,.beta.-unsaturated carboxylic acid V anda2) an alkyl alcohol VI of 1 to 25 carbon atoms,b) an ester VII ofb1) vinyl alcohol andb2) a saturated carboxylic acid VIII of 1 to 4 carbon atoms,c) vinyl chlorided) styrene or vinyl benzenes which carry an alkyl group of 1 to 4 carbon atoms on the benzene ring, in the presence of a compound IX which contains an N-oxyl radical function, withB. at least one compound X comprisinga) 50 to 100% by weight, based on X, of at least one compound XI selected from the group consisting ofa1) an ester XII ofa) an .alpha.,.beta.-unsaturated carboxylic acid XIII andb) an alkyl alcohol XIV of 2 to 10 carbon atoms which carries at least one polar or acidic group,a2) an amide XV ofa) an .alpha.,.beta.-unsaturated carboxylic acid XVI andb) ammonia or an amine XVII of 2 to 10 carbon atoms which carries at least one polar or acidic group,a3) N-vinyl compounds XVIII,a4) styrene sulfonic acid or vinylbenzenesulfonic acid which carries an alkyl group of 1 to 4 carbon atoms on the ring, andb) from 0 to 50% by weight based on X, of at least one compound XIX selected from the group consisting ofb1) an ester XX ofa) an .alpha.,.beta.-unsaturated carboxylic acid XXI andb) an alkyl alcohol XXII of 1 to 25 carbon atoms,b2) an ester XXIII ofa) vinyl alcohol andb) a saturated carboxylic acid XXIV of 1 to 4 carbon atoms,b3) vinyl chloride,b4) styrene or vinylbenzenes, which carry an alkyl group of 1 to 4 carbon atoms on the benzene ring, in the presence of a compound XXV which contains an N-oxyl radical function,polymer I containing from 10 to 90% by weight of II and in total from 10 to 90% by weight of X.The polymer may be used as dispersing resins for pigment-containing coatings.
摘要:
A cleaner composition which comprises at least one surfactant, at least one builder and at least one nitrogen-containing polymer is described. The nitrogen-containing polymer is, for example, an alkoxylated polyvinylamine, an alkoxylated, acylated or alkylated polyaminoamide or a polyurethane-urea with tertiary amino groups. The nitrogen-containing polymers facilitate soil release.
摘要:
Disclosed is a dispersant obtainable by reacting (i) a di- or polyfunctional isocyanate with (ii) an HX-terminated polymeric compound, where X is COO, O, S or NR1 and R1 is H or C1-C6-alkyl; and either (iii) an HY-terminated homopolymer of a monomer selected from the group consisting of N-vinylamides, N-vinyllactams and vinyl- or allyl-substituted nitrogenous heterocycles or copolymer of one or more of the monomers mentioned and optionally further monomers, where Y is COO, O, S or NR2 and R2 is H or C1-C6-alkyl; or (iv) an HY-functional organic phosphonic ester, where Y is as defined above. The dispersant is especially useful for dispersing pigments and for preparing inkjet inks.
摘要:
Continuous recovery of raw materials from coated films and apparatus for this purpose and film material recovered therewith. Large amounts of coated films can be fed to a continuous recycling process in which any pigments present in the coating and the substrate material are recovered. The treatment is carried out at room temperature in an alkaline medium consisting of soft soap, organic solvent and/or water, with or without the use of a catalyst. The solvent is recycled. After the first treatment stage, the film shreds can be treated in a second stage with a solvent/water mixture similarly to the first stage, and thorough final washing in a water or solvent circulation is effected in a third stage. The recovered film shreds are dried, pressed, milled and brought to the desired shape in a plastics agglomerator, and the recovered pigments are dried under reduced pressure (FIG. 1). The process and apparatus can be used with advantage for any type of substrate or printed media, for example for magnetic substrates, photographic substrates, printing plates, pigment-free substrates.
摘要:
Polyurethanes I obtained by reacting1) an isocyanate II as defined in the specification with2) a compound V which is suitable as chain extender, obtained bya) reacting a polyhydric alcohol VI withb1) a compound VII, which includes an epoxy function and, in addition, an alcohol-reactive functional group, to form a compound VIII, and reacting a compound VIII with an .alpha.,.beta.-olefinically unsaturated carboxylic acid IX to give a compound X orb2) an .alpha.,.beta.-olefinically unsaturated carboxylic acid IX, to give a compound X andc) reacting a compound X with an amine XI having at least one primary amino which is reactive toward the .alpha.,.beta. multiple bond of IX,the sum of the number of isocyanato-reactive aminos and hydroxyls of the compound V being greater than the number of isocyanate groups of the compound II. The polyurethanes are useful as binders or binder components for pigment0free or pigment-containing coatings.