摘要:
A process for treating a substrate comprises utilizing at least one aqueous formulation comprising (A) at least one acrylate-based binder without interpolymerization of any comonomer capable of detaching, per mole, one equivalent of formaldehyde on exposure to a temperature in the range from 100 to 250° C., (B) at least one carbodiimide, (C) at least one diol, triol or polyol.
摘要:
An aqueous dispersion comprising a polyurethane synthesized from a) organic diisocyanates b) dihydroxy compounds having a molar weight of 500 to 5000 g/mol and comprising no ionic group or group that can be converted to an ionic group c) mono- to trihydric alcohols additionally comprising an ionic group d) if appropriate, further compounds other than a) to c), wherein the polyurethane comprises less than 0.6% by weight of urea groups (calculated with a molar weight of 56 g/mol), the ionic group of c) has been at least partly neutralized with an alkali metal cation, and the reaction of compounds a), b), c), and d) does not take place in the presence of a catalyst containing a metal-carbon bond.
摘要:
The present invention relates to microcapsule dispersions comprising microcapsules in a hydrophobic solvent, wherein the microcapsules have a capsule core, comprising at least one water-soluble organic substance in solution in a hydrophilic solvent, and a capsule shell, obtainable bya) interfacial polyaddition of at least one di-, oligo- and/or polyisocyanate with at least one reagent carrying at least one isocyanate-reactive group andb) subsequent aftertreatment of the primary product microcapsules with at least one compound selected from the group consisting of amines, alcohols and amino alcohols having a molecular weight of at least 150 g/mol andc) if appropriate, subsequent aftertreatment with at least one further aftertreatment reagent.
摘要:
Aqueous dispersions comprising a polyurethane composed of a) diisocyanates, b) diols of which b1) from 10 to 100 mol %, based on the total amount of diols (b), have a molecular weight of from 500 to 5000, and b2) from 0 to 90 mol %, based on the total amount of diols (b), have a molecular weight of from 60 to 500 g/mol, c) monomers other than the monomers (a) and (b), containing at least one isocyanate group or at least one isocyanate-reactive group and further carrying at least one hydrophilic group or potentially hydrophilic group by means of which the polyurethane is made dispersible in water, d) if desired, further, polyfunctional compounds other than the monomers (a) to (c), containing reactive groups which are alcoholic hydroxyl groups, primary or secondary amino groups or isocyanate groups, and e) if desired, monofunctional compounds which are other than the monomers (a) to (d) and contain a reactive group which is an alcoholic hydroxyl group, a primary or secondary amino group or an isocyanate group, obtainable by reacting the monomers a), b), c), and, where used, d) and e) in the presence of a cesium salt.
摘要:
The invention relates to mixtures containing (A) an isocyanurate and/or biuret of 1,6-diisocyanatohexane (IIDI), (B) an isocyanurate of 1-isocyanato-3,5,5-trimethyl-5-isocyanaLomethyl-cyclohexane (IPDI), (C) at least one emulsifier, which can be obtained by reacting a diisocyanate (C2) selected from tetramethylenediisocyanate, dodecamethylenediisocyanate, 1,4-diiso-cyanatocyclohexane, 4,4′-di(isocyanatocyclohexyl)methane, trimethylhexandiisocyanate, tetramethylhexandiisocyanate, 2,4 or 2,6 toluylenediisocyanate and the isomer mixtures thereof, tetratnethylxylylenediisocyanate, p-xylylenediisocyanate, 2,4′ or 4,4′ diiso-cyanatodiphenylmethane and a mixture of at least two of said diisocyanates having at least one component (C1) which contains at least one group which can react with isocyanate groups and at least one hydrophile group, and (D) optionally a solvent.
摘要:
Aqueous latent-crosslinking polyurethane dispersions, comprisingI) a disperse phase (P.I) includingIa) polyurethanes (PUR.Ia) carrying not only groups which render the polyurethane dispersible in water but also groups with a C--C double bond which is activated by a carbonyl attached directly to it, orIb) a mixture ofa polyurethane (PUR.Ib) carrying groups which render the polyurethane dispersible in water but no groups with a C--C double bond which is activated by carbonyl attached directly to it, anda compound (V.I) different from the polyurethanes PUR.Ia and PUR.Ib, which carries groups with a C--C double bond which is activated by a carbonyl attached directly to it, andII) a compound havingon average at least 2 hydrogens present as amino function,a solubility in water of more than 1 g/l (25.degree. C.) anda number-average molecular weight (M.sub.n) of from 200 to 1,000,000 (compound II).
摘要:
Aqueous dispersions containing a polyurethane built up from a) diisocyanates having 4 to 30 carbon atoms, b) diols, of which b.1) from 10 to 100 mol %, based on the total amount of the diols (b), have a molecular weight of from 500 to 5000 and are built up from b1.1) (C.sub.4 - to C.sub.30 -alkyl)succinic acid and/or (C.sub.4 - to C.sub.30 -alkenyl)succinic acid, b1.2) from 0 to 60 mol %, based on component (b1.1), of a dicarboxylic acid which is different from component (b1.1), and b1.3) a diol having a molecular weight of from 60 to 500 g/mol, b.2) from 0 to 90 mol %, based on the total amount of the diols (b), have a molecular weight of from 60 to 500 g/mol, and b.3) from 0 to 90 mol %, based on the total amount of the diols (b), have a molecular weight of from 500 to 5000 g/mol and are different from (b1), c) monomers which are different from the monomers (a) and (b) and contain at least 2 isocyanate groups or at least 2 isocyanate-reactive groups and which in addition carry at least one hydrophilic group or a potentially hydrophilic group, thus achieving the water-dispersibility of polyurethanes, d) if desired, further polyfunctional compounds which are different from the monomers (a) to (c) and contain reactive groups which are alcoholic hydroxyl groups, primary or secondary amino groups or isocyanate groups, and e) if desired, monofunctional compounds which are different from the monomers (a) to (c) and contain one reactive group, which is an alcoholic hydroxyl group, a primary or secondary amino group or an isocyanate group.
摘要:
Polyurethanes suitable as coating materials or components thereof are essentially composed of A) a.sub.1) from 40 to 100 mol % of bis(4-isocyanatocyclohexyl)methane, the trans/trans content of (a.sub.1) being up to 18 mol %, based on the amount of (a.sub.1), and a.sub.2) from 0 to 60 mol % of further polyfunctional aliphatic, cycloaliphatic, araliphatic or aromatic isocyanates of 4 to 30 carbon atoms and B) b.sub.1) from 20 to 100 mol % of a nonaromatic diol and b.sub.2) from 0 to 80 mol % of further polyfunctional compounds having reactive groups which can react with the isocyanate groups (A), the reactive groups being hydroxyl or primary or secondary amino groups.
摘要:
The present invention relates to a process for producing a water-absorbing material comprising the steps of a) spray-coating water-absorbing polymeric particles with an elastic film-forming polymer in a fluidized bed reactor in the range from 00 C to 1500 C and b) heat-treatment of the coated particles at a temperature above 50° C., wherein in step b) the duration of the heat-treatment is chosen that the CS-SFC value of the obtained polymeric particles is at least 10% of the optimum CS-SFC value, and the water-absorbing material obtainable by this process.
摘要:
A process for producing sterile nonwovens comprises a textile fabric composed of a fiber web being impregnated with an aqueous dispersion comprising a polyurethane, then dried and irradiated with .gamma.-rays.