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公开(公告)号：US07025941B1
公开(公告)日：2006-04-11
申请号：US09664539
申请日：2000-09-18
CPC分类号： B01J8/0278 , B01J8/008 , B01J8/0285 , B01J12/007 , B01J2208/00407 , B01J2208/00415 , B01J2208/00716 , C01B3/323 , C01B3/38 , C01B3/382 , C01B2203/00 , C01B2203/0244 , C01B2203/066 , C01B2203/0844 , C01B2203/085 , C01B2203/1223 , C01B2203/142 , C01B2203/1604 , C01B2203/1619 , C01B2203/82
摘要： A reactor system for reacting a hydrocarbon or hydrocarbon derivative charging material comprises a catalyst-coated reaction chamber, to which a reaction educt stream can be fed through a reaction chamber inlet, and electric heating means. The reaction chamber inlet has a flat, electrically heatable, catalyst-coated, and reaction educt stream-permeable heater, which covers at least partially the inlet cross section of the reaction chamber inlet and through which the educts for reacting the charging material can be fed at least in a start operating phase of the reactor system. An electric heater may be provided in front of the reaction chamber inlet, for the purpose of heating at least one reaction educt in a start operating phase and there are means for point-by-point injection of at least one reaction educt, heated in the heater, into the reaction chamber.
摘要翻译： 用于使烃或烃衍生物填充材料反应的反应器系统包括催化剂涂覆的反应室，反应流体流可以通过反应室入口和电加热装置进料。 反应室入口具有平坦的，电可加热的，催化剂涂覆的和反应流体流可渗透的加热器，其至少部分地覆盖反应室入口的入口横截面，并且通过该加热器可以将用于使充电材料反应的离子 至少在反应堆系统的起动操作阶段。 可以在反应室入口的前面设置电加热器，用于在起始操作阶段加热至少一个反应离子，并且存在用于逐点注入至少一个在 加热器，进入反应室。
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公开(公告)号：US06447736B1
公开(公告)日：2002-09-10
申请号：US09206379
申请日：1998-12-07
申请人： Rainer Autenrieth , Stefan Boneberg , Andreas Christen , Dietmar Heil , Barbara Strobel , Steffen Wieland , Detlef zur Megede
发明人： Rainer Autenrieth , Stefan Boneberg , Andreas Christen , Dietmar Heil , Barbara Strobel , Steffen Wieland , Detlef zur Megede
IPC分类号： B01J800
CPC分类号： H01M8/0631 , B01B1/005 , B01J19/249 , B01J2219/0002 , B01J2219/2453 , B01J2219/2462 , B01J2219/2492 , C01B3/323 , C01B3/382 , C01B3/48 , C01B3/583 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0838 , C01B2203/0844 , C01B2203/0866 , C01B2203/1223 , C01B2203/1288 , C01B2203/143 , C01B2203/1604 , C01B2203/82
摘要： A system for the water vapor reforming of a hydrocarbon includes a modular reactor unit of the plate stack and/or tube bundle type that, in an integrated manner, contains an evaporator, a prereforming unit, a main reformer, a CO removal unit and a catalytic burner unit. The evaporator and the main reformer are in a thermal contact with the catalytic burner unit and, the prereforming unit is in a thermal contact with the CO removal unit.
摘要翻译： 用于烃的水蒸气重整的系统包括板堆叠和/或管束型的模块化反应器单元，其以整体方式包含蒸发器，预成型单元，主重整器，CO去除单元和 催化燃烧器单元。 蒸发器和主重整器与催化燃烧器单元热接触，并且预成型单元与CO去除单元热接触。
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公开(公告)号：US06355589B1
公开(公告)日：2002-03-12
申请号：US09600399
申请日：2000-09-13
IPC分类号： B01J2034
CPC分类号： B01J37/18 , B01J37/14 , C01B3/326 , C01B2203/1076 , Y02P20/52
摘要： A process for pretreating a catalyst material for catalysing a chemical reaction in a reactor, in particular for a reforming catalyst material for catalysing a methanol reforming reaction to obtain hydrogen, includes (1) subjecting the catalyst material to a hydrogen-containing gas mixture in a forming step, and (2) subsequently subjecting the catalyst material to an oxygen-containing gas mixture in a deactivating step.
摘要翻译： 用于预处理用于催化反应器中的化学反应的催化剂材料的方法，特别是用于催化甲醇重整反应以获得氢的重整催化剂材料的方法包括（1）将催化剂材料经受含氢气体混合物 以及（2）随后在去活化步骤中使催化剂材料经受含氧气体混合物。
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14.发明授权公开(公告)号：US06268075B1
公开(公告)日：2001-07-31
申请号：US09212289
申请日：1998-12-16
IPC分类号： C01B302
CPC分类号： H01M8/0631 , B60L11/1885 , B60L2240/36 , C01B3/323 , C01B3/384 , C01B3/501 , C01B2203/0405 , C01B2203/047 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , H01M8/0612 , H01M2250/20 , Y02P20/128 , Y02T90/32 , Y02T90/34
摘要： The invention relates to a process for operating a system for the water vapor reforming of a hydrocarbon, having an evaporator, a reforming reactor, a membrane module connected behind, and a catalytic burner device. According to the invention, a first part of the catalytic burner device is in thermal contact with the reforming reactor, and a second part of the burner device is in thermal contact with the evaporator. According to the process, a heating operation is carried out during the cold start of the system, in which, in a first operating phase, at least the evaporator and the reforming reactor are heated by the catalytic burner device, and in a second operating phase, a hydrocarbon/water vapor mixture is prepared in the evaporator at a water/hydrocarbon ratio which is higher than in the normal operation and is fed to the reactor, the substance mixture emerging from the reactor being fed by way of the membrane module to the catalytic burner device.
摘要翻译： 本发明涉及一种用于操作具有蒸发器，重整反应器，后面连接的膜组件和催化燃烧器装置的烃的水汽重整系统的方法。 根据本发明，催化燃烧器装置的第一部分与重整反应器热接触，并且燃烧器装置的第二部分与蒸发器热接触。 根据该过程，在系统的冷启动期间进行加热操作，其中在第一操作阶段中，至少蒸发器和重整反应器由催化燃烧器装置加热，并且在第二操作阶段 在蒸发器中以比正常操作高的水/烃比制备烃/水蒸气混合物并将其进料到反应器中，从反应器中排出的物质混合物通过膜组件进料至 催化燃烧装置。
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公开(公告)号：US06254848B1
公开(公告)日：2001-07-03
申请号：US09475274
申请日：1999-12-30
申请人： Rainer Autenrieth , Barbara Strobel
发明人： Rainer Autenrieth , Barbara Strobel
IPC分类号： C01B302
CPC分类号： C01B3/38 , B01J8/0438 , B01J19/249 , B01J2208/00309 , B01J2208/00716 , B01J2219/2453 , B01J2219/2466 , B01J2219/2477 , B01J2219/2479 , B01J2219/2481 , B01J2219/2485 , C01B3/323 , C01B3/583 , C01B2203/0233 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0838 , C01B2203/1223 , C01B2203/141 , C01B2203/1604
摘要： A system for generating a high-hydrogen gas comprises a reformer for the catalytic water vapor reforming of a water vapor/fuel mixture while supplying thermal energy; a gas purification stage for removing carbon monoxide from the high-hydrogen gas while releasing heat; and devices for transmitting thermal energy from the gas purification stage into the reformer. The reaction rates in the reformer and in the gas purification stage are designed such that a defined temperature level is set automatically by the coupling of the two reactions.
摘要翻译： 用于产生高氢气的系统包括用于在提供热能的同时进行水蒸汽/燃料混合物的催化水蒸气重整的重整器; 用于在释放热量的同时从高氢气中除去一氧化碳的气体净化级; 以及用于将热能从气体净化级传输到重整器中的装置。 在重整器和气体净化阶段中的反应速率被设计成使得通过两个反应的耦合自动设定定义的温度水平。
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16.发明授权
公开(公告)号：US5935277A
公开(公告)日：1999-08-10
申请号：US876390
申请日：1997-06-16
申请人： Rainer Autenrieth , Dietmar Heil , Wolfgang Weger , Uwe Benz
发明人： Rainer Autenrieth , Dietmar Heil , Wolfgang Weger , Uwe Benz
IPC分类号： B01J8/00 , B01J8/06 , C01B3/32 , C01B3/38 , H01M8/0612
CPC分类号： H01M8/0631 , B01J8/002 , B01J8/008 , B01J8/06 , C01B3/323 , C01B3/38 , B01J2208/00132 , B01J2208/0069 , B01J2208/00884 , C01B2203/0233 , C01B2203/066 , C01B2203/0833 , C01B2203/1011 , C01B2203/1076 , C01B2203/1082 , C01B2203/1223
摘要： In a reforming reactor suitable particularly for the water vapor reforming of methanol in mobile applications such as vehicles, a reaction space is filled with a catalyst pellet fill and has a movable reaction space wall which exerts a position-fixing pressure onto the catalyst pellet fill. According to the invention, a filling device is provided through which catalyst material can be filled from the outside into the reaction space through a passage opening formed in one of the reaction space walls.
摘要翻译： 在适用于诸如车辆的移动应用中特别适用于甲醇的水汽重整的重整反应器中，反应空间填充有催化剂颗粒填充物，并且具有向催化剂颗粒填充物施加位置固定压力的可移动的反应空间壁。 根据本发明，提供一种填充装置，催化剂材料可以通过该填充装置通过形成在反应空间壁之一中的通道开口从外部填充到反应空间中。
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公开(公告)号：US06696027B1
公开(公告)日：2004-02-24
申请号：US09048984
申请日：1998-03-27
IPC分类号： B01J806
CPC分类号： H01M8/0631 , B01J8/003 , B01J8/008 , B01J8/12 , B01J2208/00132 , B01J2208/0069 , C01B3/323
摘要： A reformation reactor that can be used especially for steam reformation of methanol for generating hydrogen in motor vehicles operated by fuel cells. A gas stream to be reformed is conducted through a reaction chamber into which a charge of a catalyst material is added. A catalyst supply container connected with the reaction chamber is so arranged that the catalyst material is automatically added from the supply container to the reaction chamber.
摘要翻译： 一种可用于燃料电池运行的机动车辆中用于产生氢气的甲醇蒸汽重整的重整反应器。 将要重整的气流通过加入催化剂材料的反应室进行。 与反应室连接的催化剂供给容器被布置成使得催化剂材料从供应容器自动添加到反应室。
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公开(公告)号：US06646413B2
公开(公告)日：2003-11-11
申请号：US09987444
申请日：2001-11-14
IPC分类号： H01M1044
CPC分类号： B60L11/1881 , Y02T90/34
摘要： A fuel cell system includes a fuel cell unit having an anode side and a cathode side, anode-side feeding and outflow lines for the supply of fuel and removal of anode-side exhaust, and cathode-side feeding and outflow lines for the supply of oxygen and removal of cathode-side exhaust. The fuel cell system also includes means for electrically switching the fuel cell unit on and off depending on the available quantity of fuel.
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19.发明授权Flame colorant additive for methanol for the operation of a fuel cell system 失效用于甲醇的火焰着色剂添加剂用于燃料电池系统的操作公开(公告)号：US06521364B1
公开(公告)日：2003-02-18
申请号：US09716999
申请日：2000-11-22
申请人： Rainer Autenrieth
发明人： Rainer Autenrieth
IPC分类号： H01M800
CPC分类号： C10L1/003 , C10L1/1225 , C10L1/1881 , H01M8/02 , H01M8/0612
摘要： A flame colorant additive for methanol for the operation of a fuel cell system includes at least one of (1) NaCl; (2) an organic compound of an element of the first principal group or of the second principal group of the periodic table of elements; and/or (3) an organic compound of an element of the third secondary group or of the ninth secondary group of the periodic table of elements.
摘要翻译： 用于燃料电池系统操作的用于甲醇的火焰着色剂添加剂包括以下中的至少一种：（1）NaCl; （2）元素周期表第一主族或第二主族元素的有机化合物; 和/或（3）元素周期表第三二级元件或第九仲
子元素的有机化合物。-
公开(公告)号：US06423435B1
公开(公告)日：2002-07-23
申请号：US09517527
申请日：2000-03-02
IPC分类号： H01M804
CPC分类号： C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0288 , C01B2203/0405 , C01B2203/041 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/0495 , C01B2203/066 , C01B2203/0844 , C01B2203/0883 , C01B2203/1247 , C01B2203/1288 , C01B2203/142 , C01B2203/146 , C01B2203/147 , C01B2203/148 , C01B2203/16 , C01B2203/82 , H01M8/04029 , H01M8/04097 , H01M8/04156 , H01M8/0612 , H01M8/0662 , H01M2300/0082
摘要： A fuel cell system has at least one fuel cell and a hydrogen generating arrangement for feeding the fuel cell anode with a hydrogen-containing product gas from a conversion reaction of a hydrocarbon starting substance or hydrocarbon derivative with of water fed supplied by way of a water feeding system. Water recovery devices are provided for condensing water out of the process gas supplied by the hydrogen generating arrangement, and/or out of the cathode waste gas carried away from the fuel cell cathode, and returning the condensed-out water into the water feeding system.
摘要翻译： 燃料电池系统具有至少一个燃料电池和氢生成装置，用于从烃起始物质或烃衍生物与通过水供给的水的转化反应将含有氢的产物气体供给燃料电池阳极 喂养系统。 提供水回收装置，用于将由氢气发生装置供应的工艺气体中的水和/或从燃料电池阴极携带的阴极废气中的水冷凝，并将冷凝的水返回给水系统。
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