摘要:
A method for the treatment of a methanol reforming catalyst includes pre-aging the catalyst by baking it out in a dry atmosphere in order thereby to complete its inherent initial loss of volume before the start of the methanol reforming reaction. The method may be used for methanol reforming reactors in fuel-cell-operated motor vehicles.
摘要:
A system for the water vapor reforming of a hydrocarbon includes an evaporator, a prereforming unit, a main reformer, a CO removal unit and at least one catalytic burner unit. A first burner unit is in a thermal contact with the evaporator and a second burner unit is in a thermal contact with the main reformer, and the prereforming unit is in a thermal contact with the CO removal unit by way of one heat conducting separating medium. In addition, the outlet of the CO removal unit is connected with the inlet of the at least one burner unit. During a cold start, a heating-up operation is carried out during which first the two burner units are activated with an external feeding of hydrogen or hydrocarbon, and the reforming operation is started with a hydrocarbon fraction that is lower than in the normal operation. The resulting reformate gas, instead of the externally fed hydrogen or hydrocarbon, is introduced as fuel into the burner units.
摘要:
A reforming reactor system for water vapor reforming of methanol in fuel-cell operated motor vehicles has a reactor unit with a catalyst-filled reaction space and a particle filter which is arranged in a reformate gas pipe downstream of the reactor unit. The catalyst material is carried in the reaction space by a sieve below which a metallic nonwoven for catching sieved-out fragments and dust particles of the catalyst fill is situated. The particle filter contains a spun steel wool netting and/or several filter steps serially connected behind one another. The particle filter may be arranged to be exchangeable without interrupting the operation of the system. Specifically, a particle filter which has a filter body which can be changed in a gas-tight manner transversely to the gas flow and/or a cyclone filter can be used which has a closing device for the purpose of an emptying of a particle collecting pot which does not interrupt the operation.
摘要:
A method for vaporizing and/or superheating a combustible/water mixture, wherein the combustible is especially methanol, for supplying a gas generation system (2) belonging to a fuel cell installation (3). The waste-gas from the fuel cell and/or gas generation system is catalytically combusted together with a gas containing oxygen in order to produce the thermal energy required therefore. The combustible is added in a dosed manner to the volume flow from the gas containing oxygen and the waste gases of the fuel cell and/or gas generator system in the direction of flow prior to catalytic combustion.
摘要:
A reforming reactor, particularly for the water vapor reforming of methanol, with three serially arranged reactor steps, each of which is charged with a catalyst pellet fill. According to the invention, the center reactor step is maintained at a temperature which is suitable for the reforming reaction, while the two other reactor steps remain unheated. The present invention may be used as a reforming reactor for the water vapor reforming of methanol for the purpose of producing hydrogen in a fuel-cell operated motor vehicle.
摘要:
A membrane for separating hydrogen from a gas mixture is provided on at least one side with a catalyst layer for a specific catalytic combustion process. A methanol reformation system so equipped can be brought rapidly to operating temperature, with the hydrogen-separating membrane being heated directly by performing the catalytic combustion process.
摘要:
A system for steam reformation of a hydrocarbon includes a combined oxidizer/burner unit connected downstream of a reformer and in thermal contact therewith. The combined unit functions during reformation reaction operation of the reformer as a CO oxidizer and simultaneously as a catalytic burner. During reformation reaction operation, a gas containing oxygen is added to the combined oxidizer/burner unit that has an oxygen component that is greater than the oxygen component required for CO oxidation alone. The system may be used, for example, in fuel-cell-operated motor vehicles to obtain hydrogen from methanol carried in liquid form that is required for the fuel cells.
摘要:
A method for the treatment of a methanol reforming catalyst includes pre-aging the catalyst by baking it out in a dry atmosphere in order thereby to complete its inherent initial loss of volume before the start of the methanol reforming reaction. The method may be used for methanol reforming reactors in fuel-cell-operated motor vehicles.
摘要:
A method for the operation of a methanol reforming apparatus wherein, during the operation of the reforming reaction, methanol is reformed in a methanol reforming reactor using a methanol reforming catalyst. The reforming reaction is interrupted at given times for catalyst reactivation phases, during which the reactor containing the methanol reforming catalyst is flushed with hydrogen gas for the activity-regenerating treatment of the methanol reforming catalyst which loses its catalytic activity. The process may be used for the operation of methanol reforming apparatus in fuel-cell-operated motor vehicles for the production of hydrogen from liquid methanol.
摘要:
The invention provides a process for operating a system for water vapor reforming of methanol in which, in a mixture preparation step, a water vapor/methanol mixture is prepared from water and methanol and is introduced into a reforming reactor. According to the invention, the mixing ratio of the water vapor/methanol mixture is adjusted as a function of the load condition and/or load changes of the system so that a CO-concentration is obtained in the reformate which remains constant over the whole load range.