Coating compositions prepared with an acrylic modified ethylene-vinyl acetate polymer
    11.
    发明授权
    Coating compositions prepared with an acrylic modified ethylene-vinyl acetate polymer 有权
    用丙烯酸改性的乙烯 - 乙酸乙烯酯聚合物制备的涂料组合物

    公开(公告)号:US06174960B1

    公开(公告)日:2001-01-16

    申请号:US09227751

    申请日:1999-01-08

    CPC classification number: C09D131/04 C08L43/04 Y10T428/31663 C08L2666/04

    Abstract: A non-aqueous—organic-solvent-free coating composition having increased block resistance comprising an acrylic modified ethylene-vinyl acetate (EVA) polymer blend, wherein the acrylic polymer is prepared by emulsion polymerizing at least one ethylenically unsaturated non-carboxy functional monomer, from 0.01 to 2 pphm of a sterically hindered alkoxylated silane monomer, and at least one anionic surfactant, and the ethylene-vinyl acetate polymer is prepared by emulsion polymerizing ethylene and vinyl acetate.

    Abstract translation: 一种具有增加的抗粘连性的非水有机 - 无溶剂涂料组合物,其包含丙烯酸改性的乙烯 - 乙酸乙烯酯(EVA)聚合物共混物,其中丙烯酸聚合物通过乳液聚合至少一种烯属不饱和非羧基官能单体, 0.01至2pphm的空间位阻烷氧基化硅烷单体和至少一种阴离子表面活性剂,并且通过将乙烯和乙酸乙烯酯乳液聚合制备乙烯 - 乙酸乙烯酯聚合物。

    Polymer hydrogenation process
    12.
    发明授权
    Polymer hydrogenation process 失效
    聚合物加氢工艺

    公开(公告)号:US4812528A

    公开(公告)日:1989-03-14

    申请号:US200954

    申请日:1988-06-01

    CPC classification number: C08C19/02

    Abstract: Selective hydrogenation of the carbon-carbon double bonds of conjugated diene copolymers is effective homogeneous solution in an organic solvent in the presence of certain divalent ruthenium carbonyl complex catalysts. The ruthenium catalysts have the general formula:Ru(CO)HA(Z).sub.3 (1)wherein A is a halogen atom, most preferably chlorine, or a hydrogen atom and Z is --PR.sub.1 R.sub.2 R.sub.3 in which R.sub.1, R.sub.2 and R.sub.3 are the same or different and are selected from alkyl and aryl groups, preferably all the phenyl group, or have the general formula:Ru(CO)XY(Z).sub.2 (2)wherein X is a carboxylate group, particularly ClCH.sub.2 COO--, Cl.sub.2 CHCOO--, Cl.sub.3 CCOO--, F.sub.3 CCOO--, CH.sub.3 COO--, C.sub.6 H.sub.5 COO-- or p--ClC.sub.6 H.sub.4 COO--, Y is a halogen atom, preferably a chlorine atom or a bromine atom, or a hydrogen atom or a carboxylate group, Z is as defined above; or have the general formula:Ru T(CO)(NO)(Z).sub.2 (3)wherein T is a halogen atom, preferably a chlorine or bromine atom, and Z is as defined above; or have the general formula:Ru T(NO)(Z).sub.2 (4)wherein T and Z are as defined above; or have the general formula:Ru H(NO)(Z).sub.3 (5)wherein Z is as defined above; or have the general formula:Ru (NO).sub.2 (Z).sub.2 (6)wherein Z is as defined above.

    Abstract translation: 共轭二烯共聚物的碳 - 碳双键的选择性氢化在某些二价钌羰基络合物催化剂的存在下,在有机溶剂中是有效的均相溶液。 钌催化剂具有以下通式:其中A是卤素原子,最优选氯或氢原子的Ru(CO)HA(Z)3(1),Z是R 1,R 2和R 3相同的-PR 1 R 2 R 3 或不同的,并且选自烷基和芳基,优选全部苯基,或具有以下通式:Ru(CO)XY(Z)2(2)其中X是羧酸酯基,特别是ClCH 2 COO-,Cl 2 CHCOO - ,Cl 3 COOO - ,F3CCOO-,CH3COO-,C6H5COO-或对CCl6H4COO-,Y是卤素原子,优选氯原子或溴原子,或氢原子或羧酸酯基,Z如上所定义; 或具有以下通式:Ru T(CO)(NO)(Z)2(3)其中T是卤素原子,优选氯或溴原子,Z如上所定义; 或具有以下通式:Ru T(NO)(Z)2(4)其中T和Z如上所定义; 或具有以下通式:Ru H(NO)(Z)3(5)其中Z如上所定义; 或具有通式:Ru(NO)2(Z)2(6)其中Z如上定义。

    CARPETS WITH SURFACTANT-STABILIZED EMULSION POLYMER CARPET BINDERS FOR IMPROVED PROCESSABILITY
    14.
    发明申请
    CARPETS WITH SURFACTANT-STABILIZED EMULSION POLYMER CARPET BINDERS FOR IMPROVED PROCESSABILITY 审中-公开
    具有表面活性剂稳定的乳液聚合物粘合剂的地毯,用于改进加工性

    公开(公告)号:US20130149487A1

    公开(公告)日:2013-06-13

    申请号:US13695851

    申请日:2011-05-03

    Abstract: Disclosed are improved carpet products made using certain types of coating compositions to secure carpet fibers to a carpet backing or substrates and/or to secure one or more carpet scrims or other layers to carpet backing. The coating compositions, which can be in the form of either precoating or skip coating compositions, are made from latex binder emulsions based on interpolymers emulsion polymerized from vinyl esters, ethylene, and a multifunctional cross-linking co-monomer such as an unsaturated silane. Such emulsions are also stabilized with surfactant emulsifiers but are substantially free of protective colloid stabilizers. The multifunctional co-monomer alters interpolymer molecular weight, branching and/or flow properties such that films formed from such interpolymers exhibit relatively low elongation values. When the emulsion binder exhibits such non-elongating film-forming characteristics, the carpet coating composition made from such binders can be easily processed without build-up on carpet processing apparatus. Such binder emulsions which are stabilized substantially only with surfactant emulsifiers, and not with protective colloids, also have excellent compatibility with other coating composition components.

    Abstract translation: 公开了使用某些类型的涂料组合物制备的改进的地毯产品,以将地毯纤维固定到地毯背衬或基底上和/或将一个或多个地毯毯或其它层固定到地毯背衬上。 涂层组合物可以是预涂层或跳涂层组合物的形式,由基于由乙烯基酯,乙烯和多官能交联共聚单体如不饱和硅烷聚合的共聚体的胶乳粘合剂乳液制成。 这种乳液也用表面活性剂乳化剂稳定,但基本上不含保护胶体稳定剂。 多功能共聚单体改变互聚物分子量,分支和/或流动性质,使得由这种互聚物形成的薄膜表现出相对较低的伸长率值。 当乳液粘合剂显示出这种不延长的成膜特性时,可以容易地加工由这种粘合剂制成的地毯涂料组合物,而不会在地毯加工设备上堆积。 基本上仅用表面活性剂乳化剂稳定而不用保护胶体稳定的粘合剂乳液也具有与其它涂料组合物组分的优异的相容性。

    Method of making salt-sensitive binders and nonwoven webs
    15.
    发明授权
    Method of making salt-sensitive binders and nonwoven webs 失效
    制造盐敏感粘合剂和非织造纤维网的方法

    公开(公告)号:US08232345B2

    公开(公告)日:2012-07-31

    申请号:US12932290

    申请日:2011-02-23

    Abstract: A solution with a salt-sensitive polymer binder for use in fibrous webs, where the binder contains a copolymer of carboxylic acid monomer units and ethylenically unsaturated monomer units. The binder solution is prepared by emulsion-polymerizing a copolymer and then neutralizing the copolymer with base to make it water soluble. The binders provide a higher wet strength in concentrated salt solutions than in deionized water, and are particularly suitable for strengthening nonwoven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like.

    Abstract translation: 具有用于纤维网的盐敏聚合物粘合剂的溶液,其中粘合剂含有羧酸单体单元和烯属不饱和单体单元的共聚物。 通过将共聚物乳液聚合,然后用碱中和共聚物使其成为水溶性,制备粘合剂溶液。 粘合剂在浓缩盐溶液中比在去离子水中提供更高的湿强度,并且特别适合于加强一次性制品如湿巾,个人护理产品,尿布等中的非织造纤维网。

    Salt-sensitive vinyl acetate binder compositions and fibrous article incorporating same
    17.
    发明申请
    Salt-sensitive vinyl acetate binder compositions and fibrous article incorporating same 失效
    盐敏乙酸乙烯酯粘合剂组合物和掺入其的纤维制品

    公开(公告)号:US20060252876A1

    公开(公告)日:2006-11-09

    申请号:US11120372

    申请日:2005-05-03

    Abstract: A salt sensitive polymeric binder for use in fibrous webs, where the binder contains a copolymer incorporating the residue of vinyl acetate, a carboxylic acid, and a vinyl ester of a saturated aliphatic monocarboxylic acid having between 6 and 18 carbon atoms in the carboxylic acid moiety. The copolymer is neutralized at least to the extent that it is water soluble. The binders are particularly suitable for strengthening non-woven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like.

    Abstract translation: 用于纤维网的盐敏聚合物粘合剂,其中粘合剂含有在羧酸部分中含有6-18个碳原子的饱和脂族一元羧酸的残基的羧酸和羧酸残基的共聚物 。 至少将共聚物中和到水溶性的程度。 粘合剂特别适用于在一次性制品如湿巾,个人护理产品,尿布等中加强非织造纤维网。

    Carpets with surfactant-stabilized emulsion polymer carpet binders for improved processability

    公开(公告)号:US10301772B2

    公开(公告)日:2019-05-28

    申请号:US13695851

    申请日:2011-05-03

    Abstract: Disclosed are improved carpet products made using certain types of coating compositions to secure carpet fibers to a carpet backing or substrates and/or to secure one or more carpet scrims or other layers to carpet backing. The coating compositions, which can be in the form of either precoating or skip coating compositions, are made from latex binder emulsions based on interpolymers emulsion polymerized from vinyl esters, ethylene, and a multifunctional cross-linking co-monomer such as an unsaturated silane. Such emulsions are also stabilized with surfactant emulsifiers but are substantially free of protective colloid stabilizers. The multifunctional co-monomer alters interpolymer molecular weight, branching and/or flow properties such that films formed from such interpolymers exhibit relatively low elongation values. When the emulsion binder exhibits such non-elongating film-forming characteristics, the carpet coating composition made from such binders can be easily processed without build-up on carpet processing apparatus. Such binder emulsions which are stabilized substantially only with surfactant emulsifiers, and not with protective colloids, also have excellent compatibility with other coating composition components.

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