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公开(公告)号：US08680211B2
公开(公告)日：2014-03-25
申请号：US13640429
申请日：2011-04-21
IPC分类号： C08G65/32
CPC分类号： C08G18/4261 , C08G18/4866 , C08G63/42 , C08G63/672 , C08G63/914 , C08G65/2603 , C08G65/2663 , C08G65/2672 , C08G65/2678 , C08G2101/0025 , C08J9/141 , C08J2375/06
摘要： A process for preparing a hybrid polyester-polyether polyol comprises contacting a carboxyl group-containing component and an epoxide, optionally in the presence of one or more of a double metal cyanide catalyst, a superacid catalyst, a metal salt of a superacid catalyst and/or a tertiary amine catalyst, under conditions such that a hybrid polyester-polyether polyol is formed. The hybrid polyester-polyether polyol offers the advantages of both ester and ether functionalities when used in a polyurethane formulation, thus enhancing physical properties. The process results in products having narrow polydispersity, a low acid number and unsaturation, and reduced byproduct formation, particularly when the double metal cyanide catalyst is employed.
摘要翻译： 制备混合聚酯 - 聚醚多元醇的方法包括任选地在一种或多种双金属氰化物催化剂，超酸催化剂，超酸催化剂的金属盐和/或其中的一种或多种的存在下使含羧基的组分和环氧化物接触， 或叔胺催化剂，在形成混合聚酯 - 聚醚多元醇的条件下进行。 当用于聚氨酯配方时，混合聚酯 - 聚醚多元醇具有酯和醚官能团的优点，从而提高物理性能。 该方法产生具有窄多分散性，低酸值和不饱和度的产物，以及减少的副产物形成，特别是当使用双金属氰化物催化剂时。
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12.发明授权1,3- or 1,4-bis(aminomethyl)cyclohexane-initiated polyols and rigid polyurethane foam made therefrom 有权1,3-或1,4-双（氨基甲基）环己烷引发的多元醇和由其制成的硬质聚氨酯泡沫公开(公告)号：US08318828B2
公开(公告)日：2012-11-27
申请号：US12993434
申请日：2009-06-05
IPC分类号： C08G18/00
CPC分类号： C08G18/482 , C08G18/4829 , C08G18/5021 , C08G18/7664 , C08G65/2627 , C08G2101/0025 , C08G2101/005 , C08J9/14 , C08J2203/14 , C08J2375/08 , C08L83/00
摘要： Polyether polyols are initiated with 1,3- or 1,4-bis(aminomethyl)cyclohexanes. The polyols are useful in making rigid polyurethane foams, especially foams for pour-in-place applications, where they give a good combination of low k-factor and short demold times.
摘要翻译： 聚醚多元醇由1,3-或1,4-双（氨基甲基）环己烷引发。 多元醇可用于制造刚性聚氨酯泡沫，特别是用于浇注应用的泡沫，其中它们提供低k因子和短脱模时间的良好组合。
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公开(公告)号：US20120028064A1
公开(公告)日：2012-02-02
申请号：US12804805
申请日：2010-07-29
申请人： Margarita Perello , Harmut Kühn , Jürgen Dombrowski , Francois M. Casati , Etienne Lazarus , Gerold Lohmüller
发明人： Margarita Perello , Harmut Kühn , Jürgen Dombrowski , Francois M. Casati , Etienne Lazarus , Gerold Lohmüller
CPC分类号： C08F236/10 , C04B24/2641 , C04B24/2688 , C04B28/02 , C04B2103/0057 , C04B2111/00672 , C08F212/08 , C08L25/08 , C08L29/04 , D21H17/36 , D21H17/37 , D21H19/20 , D21H19/58 , D21H19/60 , Y10T428/31895 , C08F2/24 , C08F222/02 , C08F220/06 , C04B14/06 , C04B24/383
摘要： Polymer powders comprising in copolymerized form a) one or more vinyl aromatic comonomers, b) one or more 1,3-diene comonomers, c) from 0.1 to 15 percent, based on the total comonomer weight, of one or more comonomers selected from the group consisting of ethylenically unsaturated mono- and dicarboxylic acids and their salts, wherein at least 75 percent of the total number of carboxylic groups present in the polymer are located at the surface of the polymer particles in the powder and at least 75 percent of the carboxylic groups located at the surface of the polymer particles in powder are present in their salt form, and d) from 0 to 40 percent, based on the total comonomer weight, of one or more additional comonomers have an excellent redispersibility in water.
摘要翻译： 包含共聚形式的聚合物粉末a）一种或多种乙烯基芳族共聚单体，b）一种或多种1,3-二烯共聚单体，c）基于总共聚单体重量，0.1至15％的一种或多种共聚单体选自 由烯键式不饱和单羧酸和二羧酸及其盐组成的组，其中聚合物中存在的羧基总数的至少75％位于粉末中聚合物颗粒的表面，并且至少75％的羧酸 位于粉末中的聚合物颗粒表面的基团以其盐形式存在，并且d）基于总共聚单体重量，d）0至40％的一种或多种另外的共聚单体在水中具有优异的再分散性。
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公开(公告)号：US20100286298A1
公开(公告)日：2010-11-11
申请号：US12863486
申请日：2009-01-13
CPC分类号： C08J9/0061 , C08G18/4829 , C08G18/6696 , C08G18/7621 , C08G2101/0008 , C08G2101/0083 , C08J2375/04 , C08J2427/00 , C08J2431/00 , C08J2433/00 , C08L75/04 , C08L2666/06 , C08L2666/04
摘要： Polyurethane foams of improved resilience properties can be produced from: a) a polyisocyanate, b) a polyether polyol or polyester polyol, c) a blowing agent, d) one or more optional additives or auxiliary compounds, and e) a redispersible polymer powder based on a homopolymer or copolymer of one or more monomers from the group consisting of vinyl esters of un-branched or branched alkylcarboxylic acids having from 1 to 15 carbon atoms, methacrylic esters and acrylic esters of alcohols having from 1 to 15 carbon atoms, vinylaromatics, olefins, dienes and vinyl halides.
摘要翻译： 具有改善回弹性能的聚氨酯泡沫体可由以下产生：a）多异氰酸酯，b）聚醚多元醇或聚酯多元醇，c）发泡剂，d）一种或多种任选的添加剂或辅助化合物，以及e）可再分散聚合物粉末基 在由具有1至15个碳原子的非支化或支化烷基羧酸的乙烯基酯组成的组中的一种或多种单体的均聚物或共聚物，具有1至15个碳原子的醇的甲基丙烯酸酯和丙烯酸酯，乙烯基芳烃， 烯烃，二烯和乙烯基卤化物。
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15.发明授权Catalyst system for use in producing carboxylic acid blown polyurethane foams 失效用于生产羧酸泡沫聚氨酯泡沫的催化剂体系
公开(公告)号：US4473666A
公开(公告)日：1984-09-25
申请号：US575247
申请日：1984-01-30
CPC分类号： C08J9/08 , C08G18/1816 , C08G18/1875 , C08G18/2027 , C08J2375/04
摘要： A catalyst system and process are provided for producing polyurethane foams using a carboxylic acid blowing agent, wherein an organic polyol and an organic polyisocyanate are contacted with a catalyst system comprising a dialkylcyclohexylamine and an N-substituted alkoxyalkyl piperazine.
摘要翻译： 提供催化剂体系和方法，用于使用羧酸发泡剂生产聚氨酯泡沫，其中有机多元醇和有机多异氰酸酯与包含二烷基环己胺和N-取代烷氧基烷基哌嗪的催化剂体系接触。
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公开(公告)号：US4456696A
公开(公告)日：1984-06-26
申请号：US435843
申请日：1982-10-21
CPC分类号： C08J9/145 , C08G18/1825 , C08G18/1875 , C08J2375/04
摘要： Polyurethane foams with excellent physical properties are obtained by using a catalyst composition of a tertiary amine and 2-ethylhexanoic acid.
摘要翻译： 通过使用叔胺和2-乙基己酸的催化剂组合物获得具有优异物理性能的聚氨酯泡沫。
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公开(公告)号：US4421673A
公开(公告)日：1983-12-20
申请号：US252634
申请日：1981-04-09
CPC分类号： C08J9/145 , C08G18/1825 , C08G18/1875 , C08J2375/04
摘要： Polyurethane foams with excellent physical properties can be obtained by using a partial salt between N,N-dimethylaminopropane-1,3-diamine (DMAPA) and a branched octanoic acid.
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公开(公告)号：US08765828B2
公开(公告)日：2014-07-01
申请号：US12863486
申请日：2009-01-13
IPC分类号： C08G18/28
CPC分类号： C08J9/0061 , C08G18/4829 , C08G18/6696 , C08G18/7621 , C08G2101/0008 , C08G2101/0083 , C08J2375/04 , C08J2427/00 , C08J2431/00 , C08J2433/00 , C08L75/04 , C08L2666/06 , C08L2666/04
摘要： Polyurethane foams of improved resilience properties can be produced from: a) a polyisocyanate, b) a polyether polyol or polyester polyol, c) a blowing agent, d) one or more optional additives or auxiliary compounds, and e) a redispersible polymer powder based on a homopolymer or copolymer of one or more monomers from the group consisting of vinyl esters of un-branched or branched alkylcarboxylic acids having from 1 to 15 carbon atoms, methacrylic esters and acrylic esters of alcohols having from 1 to 15 carbon atoms, vinylaromatics, olefins, dienes and vinyl halides.
摘要翻译： 具有改善回弹性能的聚氨酯泡沫体可由以下产生：a）多异氰酸酯，b）聚醚多元醇或聚酯多元醇，c）发泡剂，d）一种或多种任选的添加剂或辅助化合物，以及e）可再分散聚合物粉末基 在由具有1至15个碳原子的非支化或支化烷基羧酸的乙烯基酯组成的组中的一种或多种单体的均聚物或共聚物，具有1至15个碳原子的醇的甲基丙烯酸酯和丙烯酸酯，乙烯基芳烃， 烯烃，二烯和乙烯基卤化物。
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公开(公告)号：US20130035467A1
公开(公告)日：2013-02-07
申请号：US13640429
申请日：2011-04-21
CPC分类号： C08G18/4261 , C08G18/4866 , C08G63/42 , C08G63/672 , C08G63/914 , C08G65/2603 , C08G65/2663 , C08G65/2672 , C08G65/2678 , C08G2101/0025 , C08J9/141 , C08J2375/06
摘要： A process for preparing a hybrid polyester-polyether polyol comprises contacting a carboxyl group-containing component and an epoxide, optionally in the presence of one or more of a double metal cyanide catalyst, a superacid catalyst, a metal salt of a superacid catalyst and/or a tertiary amine catalyst, under conditions such that a hybrid polyester-polyether polyol is formed. The hybrid polyester-polyether polyol offers the advantages of both ester and ether functionalities when used in a polyurethane formulation, thus enhancing physical properties. The process results in products having narrow polydispersity, a low acid number and unsaturation, and reduced byproduct formation, particularly when the double metal cyanide catalyst is employed.
摘要翻译： 制备混合聚酯 - 聚醚多元醇的方法包括任选地在一种或多种双金属氰化物催化剂，超酸催化剂，超酸催化剂的金属盐和/或其中的一种或多种的存在下使含羧基的组分和环氧化物接触， 或叔胺催化剂，在形成混合聚酯 - 聚醚多元醇的条件下进行。 当用于聚氨酯配方时，混合聚酯 - 聚醚多元醇具有酯和醚官能团的优点，从而提高物理性能。 该方法产生具有窄多分散性，低酸值和不饱和度的产物，以及减少的副产物形成，特别是当使用双金属氰化物催化剂时。
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公开(公告)号：US08236866B2
公开(公告)日：2012-08-07
申请号：US12599998
申请日：2008-05-07
IPC分类号： C08G18/28
CPC分类号： C08G18/4891 , C08G18/10 , C08G18/3275 , C08G18/4009 , C08G18/4812 , C08G18/4816 , C08G18/4829 , C08G18/4837 , C08G18/61 , C08G18/6681 , C08G18/721 , C08G18/7664 , C08G2101/005 , C08G2101/0083
摘要： A high resilience (HR) polyurethane foam comprising the reaction product of (1) at least one polyisocyanate comprising at least about 5 weight percent of at least one methylene diphenyl diisocyanate isomer, derivative or a combination thereof and (2) an admixture of at least one natural oil based polyol and at least one additional polyol which is not a natural oil based polyol, wherein the admixture comprises at least about 10 weight percent natural oil based polyol and at least about 40 weight percent additional polyol having an equivalent weight of at least about 1700 Daltons; and the foam has a resiliency indicated by a ball rebound of at least 40 percent as measured according to the procedures of ASTM D 3574, Test H.
摘要翻译： 高弹性（HR）聚氨酯泡沫，其包含（1）至少一种包含至少约5重量％的至少一种亚甲基二苯基二异氰酸酯异构体，衍生物或其组合的至少一种多异氰酸酯的反应产物和（2）至少 一种天然油基多元醇和至少一种不是天然油基多元醇的另外的多元醇，其中所述混合物包含至少约10重量％的天然油基多元醇和至少约40重量％的额外的多元醇，其当量重量至少为 约1700道尔顿; 并且根据ASTM D 3574测试H的程序，泡沫具有由至少40％的球回弹所示的弹性。
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