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公开(公告)号:US09708447B2
公开(公告)日:2017-07-18
申请号:US14701704
申请日:2015-05-01
Applicant: SABIC Global Technologies B.V.
Inventor: Jean-Francois Morizur , Paul Dean Sybert , Peter Johnson , Thomas L. Evans , James Franklin Hoover , Amanda Marie Flores
CPC classification number: C08G64/1666 , C08G64/14 , C08G79/04 , C08L69/00 , C08L2205/03 , C08L83/10 , C08L23/0884 , C08L67/02 , C08L25/06 , C08L33/12 , C08L51/04 , C08L55/02
Abstract: Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive containing a photoactive group derived from a monofunctional benzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.
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公开(公告)号:US20170015783A1
公开(公告)日:2017-01-19
申请号:US15301248
申请日:2015-04-03
Applicant: SABIC Global Technologies B.V.
Inventor: Amanda Marie Flores , Jacob LaBelle , Peter James Zuber , Kim R. Choate
CPC classification number: C08G64/14 , C08J3/24 , C08J3/28 , C08J2369/00 , C08L69/00 , C08L2201/02 , C08L2201/08 , C08L2203/12 , C08L2205/16 , C08L2312/06 , C09D169/00 , D01D5/04 , D01D5/06 , D01D5/18 , D01D10/00 , D01F6/64 , D10B2505/02 , D10B2505/04 , D21H13/20
Abstract: Disclosed herein are polycarbonate fibers and fibrous substrates, such as papers, containing such fibers. The polycarbonate fibers are produced from a polymeric composition comprising a cross-linkable polycarbonate containing endgroups derived from a monofunctional benzophenone or containing repeating units derived from a difunctional benzophenone. The polycarbonate fibers can be combined with other fibers to form the fibrous substrate. Upon exposure to ultraviolet light, crosslinking of the polycarbonate fibers will occur, improving various properties of the fibrous substrate.
Abstract translation: 本文公开了包含这种纤维的聚碳酸酯纤维和纤维基材,例如纸。 聚碳酸酯纤维由包含含有源自单官能二苯甲酮的端基的交联性聚碳酸酯或含有衍生自二官能二苯甲酮的重复单元的聚合物组合物制成。 聚碳酸酯纤维可与其它纤维组合以形成纤维基材。 当暴露于紫外线时,会发生聚碳酸酯纤维的交联,改善纤维基材的各种性能。
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公开(公告)号:US10131742B2
公开(公告)日:2018-11-20
申请号:US15320151
申请日:2015-06-19
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Mykhaylo Lyakhovych , Ignacio Vic Fernandez , James Franklin Hoover , Amanda Marie Flores , Jaykisor Pal
Abstract: Melt polymerization processes for producing photoactive additives are disclosed. The photoactive additives are cross-linkable polycarbonate resins formed from a benzophenone, a dihydroxy chain extender, a carbonate precursor, and a catalyst. The additives can be produced without the use of phosgene or dichloromethane, and can be cross-linked with other polymers upon exposure to UV radiation.
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公开(公告)号:US10017622B2
公开(公告)日:2018-07-10
申请号:US15321404
申请日:2015-09-15
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Amanda Marie Flores , Kaushal Gandhi
IPC: C08F2/46 , C08F2/50 , C08G61/04 , C08K3/013 , C08K3/00 , C08K5/00 , C08L69/00 , C08J7/04 , C08J3/24 , C08J3/28 , B29C45/00 , B29C47/00 , B29C49/00 , B29C51/00 , B29C35/08 , B29K69/00
CPC classification number: C08K3/013 , B29C35/0805 , B29C45/0001 , B29C48/022 , B29C49/0005 , B29C51/002 , B29C2035/0827 , B29K2069/00 , B29K2995/002 , C08J3/24 , C08J3/28 , C08J7/047 , C08J2369/00 , C08K5/0041 , C08L69/00
Abstract: Polymeric compositions having improved flame retardance properties are disclosed. The compositions comprise a cross-linkable polycarbonate resin having a photoactive group derived from a dihydroxybenzophenone, and also include a colorant. Certain colorant packages lead to an unexpected increase in crosslinking.
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公开(公告)号:US20170129997A1
公开(公告)日:2017-05-11
申请号:US15320151
申请日:2015-06-19
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Mykhaylo Lyakhovych , Ignacio Vic Fernandez , James Franklin Hoover , Amanda Marie Flores , Jaykisor Pal
CPC classification number: C08G64/307 , C08G64/04 , C08G64/14 , C08J3/24 , C08J3/28 , C08J2369/00
Abstract: Melt polymerization processes for producing photoactive additives are disclosed. The photoactive additives are cross-linkable polycarbonate resins formed from a benzophenone, a dihydroxy chain extender, a carbonate precursor, and a catalyst. The additives can be produced without the use of phosgene or dichloromethane, and can be cross-linked with other polymers upon exposure to UV radiation.
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公开(公告)号:US20170113407A1
公开(公告)日:2017-04-27
申请号:US15317361
申请日:2015-06-16
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Keith E. Cox , Thomas Hocker , Jean-Francois Morizur , Thomas L. Evans , Amanda Marie Flores , Peter Johnson , Jeroen Visjager , Malvika Bihari
CPC classification number: B33Y70/00 , B29C64/106 , B29C2035/0827 , B33Y10/00
Abstract: Methods of making articles using additive manufacturing processes are disclosed. The article is built up from a multitude of layers. At least one layer includes a modeling material comprising a cross-linkable polycarbonate resin containing a photoactive group derived from a benzophenone. When exposed to an effective dosage of ultraviolet radiation, the modeling material crosslinks. This improves various properties of the final article.
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公开(公告)号:US09315675B2
公开(公告)日:2016-04-19
申请号:US14734565
申请日:2015-06-09
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Amanda Marie Flores , Vandita Pai-Paranjape
IPC: C08L69/00 , C08K3/22 , F21V7/22 , C09D5/33 , C08K5/42 , C08K5/3447 , C08K5/357 , C08K5/3475 , C08K9/02 , C08K9/08 , F21V29/85 , C08K9/06 , C09D169/00 , F21K99/00 , F21V9/06 , F21V13/04 , F21V29/00 , F21Y101/02
CPC classification number: C08K5/3447 , C08K3/22 , C08K5/3475 , C08K5/357 , C08K5/42 , C08K9/02 , C08K9/06 , C08K9/08 , C09D5/004 , C09D169/00 , F21K9/60 , F21V7/22 , F21V9/06 , F21V13/04 , F21V29/20 , F21V29/85 , F21Y2115/10 , C08L69/00
Abstract: In an embodiment, a polycarbonate composition comprises: polycarbonate; 7 wt % to 20 wt % titanium dioxide, based upon a total weight of the polycarbonate composition; an optional flame retardant; and an optional UV stabilizer. A plaque formed from the polycarbonate composition has a reflectance of greater than or equal to 95%, as determined by reflectance measurements using a Gretag Macbeth Coloreye spectrophotometer (D65 light source, 10 degree observer, UV included) made at a wavelength of 680 nm. In an embodiment, a polycarbonate composition comprises: a polycarbonate; 7 to 20 wt % titanium dioxide; a flame retardant; and an optional UV stabilizer; wherein the polycarbonate composition has a maximum reflectance of greater than or equal to 95%. The melt volume rate as determined at 300° C. using a 1.2 kilogram weight, in accordance with ASTM D1238-04 is from 5 to 30 grams per 10 minutes.
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公开(公告)号:US10087286B2
公开(公告)日:2018-10-02
申请号:US15320411
申请日:2015-06-19
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: James Franklin Hoover , Peter Johnson , Amanda Marie Flores , Jean-Francois Morizur
Abstract: Crosslinkable polycarbonate resins having improved properties are disclosed. The crosslinkable polycarbonate resins are formed from a reaction of at least a benzophenone, a first dihydroxy chain extender, and a carbonate precursor, and may include a second dihydroxy chain extender as well.
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公开(公告)号:US10066056B2
公开(公告)日:2018-09-04
申请号:US15319896
申请日:2015-06-19
Applicant: SABIC Global Technologies B.V.
Inventor: Amanda Marie Flores , James Franklin Hoover
Abstract: Polymeric compositions having improved flame retardance properties are disclosed. The compositions comprise a cross-linkable polycarbonate resin having a photoactive group derived from a benzophenone, a bromine source, and optionally a non-brominated and non-chlorinated flame retardant. The composition contains a minimum amount of bromine. Articles formed from the compositions have robust flame retardance properties and enhanced chemical resistance.
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公开(公告)号:US20170198113A1
公开(公告)日:2017-07-13
申请号:US15321404
申请日:2015-09-15
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Amanda Marie Flores , Kaushal Gandhi
IPC: C08K3/00 , C08L69/00 , C08J7/04 , C08J3/24 , B29C35/08 , B29C45/00 , B29C47/00 , B29C49/00 , B29C51/00 , C08K5/00 , C08J3/28
CPC classification number: C08K3/013 , B29C35/0805 , B29C45/0001 , B29C47/0004 , B29C49/0005 , B29C51/002 , B29C2035/0827 , B29K2069/00 , B29K2995/002 , C08J3/24 , C08J3/28 , C08J7/047 , C08J2369/00 , C08K5/0041 , C08L69/00
Abstract: Polymeric compositions having improved flame retardance properties are disclosed. The compositions comprise a cross-linkable polycarbonate resin having a photoactive group derived from a dihydroxybenzophenone, and also include a colorant. Certain colorant packages lead to an unexpected increase in crosslinking.
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