Abstract:
Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive that is a cross-linkable polycarbonate resin containing a photoactive group derived from a dihydroxybenzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.
Abstract:
A polycarbonate containing composition comprising a peak melt viscosity of at least 8,000 poise when measured using a parallel plate melt rheology test at a heating rate of 10° C./min at a temperature of between about 350° C. to about 450° C., and wherein a molded article of the composition has a UL 94 V0 rating at a thickness of 1.0 mm, 1.5 mm, 2.0 mm, or between 1.0 mm and 2.0 mm is disclosed.
Abstract:
Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive containing a photoactive group derived from a monofunctional benzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.
Abstract:
In one embodiment, a light emitting device comprises: a lighting element located in a housing, wherein the housing is formed from a polymer composition comprising: a polymer material; and a coated conversion material. The coated conversion material is selected from a coated conversion material, coated yttrium aluminum garnet (YAG) doped with rare earth elements, coated terbium aluminum garnet doped with rare earth elements, coated silicate (BOSE) doped with rare earth elements; coated nitrido silicates doped with rare earth elements; coated nitride orthosilicate doped with rare earth elements, coated oxonitridoaluminosilicates doped with rare earth elements; as well as combinations comprising at least one of the foregoing. After the coated conversion material has been exposed to an excitation source, the coated conversion material has a luminescence lifetime of less than 10−4 seconds when the excitation source is removed.
Abstract:
A poly(siloxane) copolymer composition comprising: a first polymer comprising a first repeating unit, and a poly(siloxane) block unit, a second polymer different from the first polymer and comprising of bromine; and optionally, one or more third polymers different from the first polymer and second polymer; wherein siloxane units are present in the composition in an amount of at least 0.3 wt %, and bromine is present in the composition in an amount of at least 7.8 wt %, each based on the sum of the wt % of the first, second, and optional one or more third polymers; and further wherein an article molded from the composition has an OSU integrated 2 minute heat release test value of less than 65 kW-min/m2 and a peak heat release rate of less than 65 kW/m2, and an E662 smoke test Dmax value of less than 200.
Abstract:
Provided herein are high flow and ductile thermoplastic resin compositions for the formation of thin wall devices and devices with desirable impact strengths. These compositions are useful in the manufacture of various shaped, formed and/or molded devices.
Abstract:
Processes for increasing the chemical resistance of a surface of a formed article are disclosed. The formed article is produced from a polymeric composition comprising a photoactive additive containing photoactive groups derived from a monofunctional benzophenone. The surface of the formed article is then exposed to ultraviolet light to cause crosslinking of the photoactive additive and produce a crosslinked surface. The crosslinking enhances the chemical resistance of the surface. Various means for controlling the depth of the crosslinking are also discussed.
Abstract:
In one embodiment, a device can comprise: a light emitting diode located in a housing. The housing is formed from a polymer composition comprising: a polymer material, wherein the polymer material comprises at least one of polyolefins, polyesters, cyanoacrylate, cellulose triacetate, ethyl vinyl acetate, propyl vinyl acetate, polyvinylbutyral, polyvinyl chloride, polycarbonate, polyethylene naphthalate, polyurethane, thermoplastic polyurethane, polyamide, polymethyl methacrylate, polystyrene, cellulose nitrate, and combinations comprising at least one of the foregoing polymer materials; and a coated conversion material wherein the coated conversion material comprises an inorganic material that converts radiation of a certain wavelength and re-emits of a different wavelength. The coated conversion material can have a coating comprising at least one of a silicone oil and amorphous silica and, after the coated conversion material has been exposed to an excitation source, it can have a luminescence lifetime of less than 10−4 seconds when the excitation source is removed.
Abstract:
In some embodiments, a composition comprises a bisphenol-A polycarbonate, wherein a molded article of the bisphenol-A polycarbonate has transmission level greater than or equal to 90.0% at 2.5 mm thickness as measured by ASTM D1003-00 and a yellow index (YI) less than or equal to 1.5 as measured by ASTM D1925. In some embodiments, light emitting device comprises: a lighting element located in a housing. The housing is formed from a plastic composition comprising: the polycarbonate composition and a conversion material. After the conversion material has been exposed to an excitation source, the conversion material has a luminescence lifetime of less than 10−4 seconds when the excitation source is removed.
Abstract:
Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive containing a photoactive group derived from a monofunctional benzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.