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11.
公开(公告)号:US20190135977A1
公开(公告)日:2019-05-09
申请号:US16092864
申请日:2017-04-28
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Paul Dean SYBERT , Tony FARRELL , Rob BOONMAN , Robert Dirk VAN DE GRAMPEL , Mark Adrianus Johannes VAN DER MEE
Abstract: A copolycarbonate comprises first repeating units, second repeating units different from the first repeating units, and third repeating units different from the first and second repeating units; and wherein the first repeating units are phthalimidine carbonate units, the second repeating units are carbonate units of the formula (I) wherein Rc and Rd are each independently a C1-12 alkyl, C2-12 alkenyl, C3-8 cycloalkyl, or C1-12 alkoxy, each R6 is independently C1-3 alkyl or phenyl; Xa is a C6-12 polycyclic aryl, C3-18 mono- or polycycloalkylene, C3-18 mono- or polycycloalkylidene, -(Q1)x-G-(Q2)y- group wherein Q1 and Q2 are each independently a C1-3 alkylene, G is a C3-10 cycloalkylene, x is 0 or 1, and y is 1; and m and n are each independently 0 to 4; and the third repeating units are carbonate units (II) wherein Re and Rf are each independently C1-12 alkyl, C2-12 alkenyl, C3-8 cycloalkyl, or C1-12 alkoxy, a and b are each independently integers of 0 to 4, and Xb is a single bond, —0—, —S—, —S(0)-, —S(0)2—, —C(0)—, or C1-32 bridging hydrocarbon group, provided that Xb is not a phthalimidine group or Xa.
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公开(公告)号:US20190055400A1
公开(公告)日:2019-02-21
申请号:US16079237
申请日:2017-02-22
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Abstract: The present disclosure relates to articles formed from composition comprising a melt polycarbonate component and an interfacial polycarbonate component. The resulting articles exhibit mechanical properties improving upon articles formed from polycarbonate prepared according to conventional melt polymerization processes.
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13.
公开(公告)号:US20190388669A1
公开(公告)日:2019-12-26
申请号:US16480801
申请日:2018-01-29
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Maria Dolores MARTINEZ CANOVAS , Mark Adrianus Johannes VAN DER MEE , Robert Dirk VAN DE GRAMPEL , Johannes DE BROUWER , Herwig JUSTER
Abstract: A microneedle comprising a shaft has a proximal end and a distal end and, optionally, a capillary space within said shaft, said capillary space (i) connecting said proximal and distal ends or (ii) extending from the distal end of the shaft and connecting with one or more external openings positioned between the proximal end and distal end or (iii) performing the functions of both (i) and (ii). The microneedle includes a polymer mixture that includes (a) polycarbonate, (b) polycarbonate-polysiloxane copolymer and (c) mold release agent.
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公开(公告)号:US20190284390A1
公开(公告)日:2019-09-19
申请号:US16061504
申请日:2016-12-12
Applicant: SABIC Global Technologies B.V.
Inventor: Tamara Marijke EGGENHUISEN , Roland Sebastian ASSINK , Eduardus Ludovicus Louisa BROEKAART , Robert Dirk VAN DE GRAMPEL
Abstract: A molded article includes a polycarbonate resin and a colorant, and the molded article, when tested using a 3 mm color plaque, includes a color difference delta E (dE*) of less than about 0.6 following molding under abusive molding conditions as compared to a reference article molded under standard processing conditions. The molded article may include a color difference delta b (db*) of less than about 0.3 after being molded under the abusive molding conditions. The molded article may also exhibit a shift in wavelength of maximum absorbance of less than about 5 nm after being molded under the abusive molding conditions and/or a difference in absorbance intensity of less than about 15% after being molded under the abusive molding conditions as compared to a reference article molded under standard processing conditions. Methods for forming a molded article in accordance with the above are also described.
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公开(公告)号:US20190284365A1
公开(公告)日:2019-09-19
申请号:US16061473
申请日:2016-12-12
Applicant: SABIC Global Technologies B.V.
Inventor: Tamara Marijke EGGENHUISEN , Roland Sebastian ASSINK , Eduardus Ludovicus Louisa BROEKAART , Robert Dirk VAN DE GRAMPEL
IPC: C08K5/00
Abstract: A molded article includes a polycarbonate resin, an ultraviolet (UV) absorbing component, a heat stabilizer component, and a colorant. The molded article, when tested using a 2.5 mm color plaque, includes a color difference delta E* (dE*) of less than about 0.6 following molding under abusive molding conditions as compared to a reference article molded under standard processing conditions. The molded article may include a color difference delta b* (db*) of less than about 0.3 after being molded under the abusive molding conditions as compared to a reference article molded under standard processing conditions. The UV absorbing component may include a benzotriazole compound. Methods for forming a molded article in accordance with the above are also described.
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公开(公告)号:US20190225797A1
公开(公告)日:2019-07-25
申请号:US16327669
申请日:2017-07-28
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Maria Dolores MARTINEZ CANOVAS , Mark Adrianus Johannes Van Der Mee , Robert Dirk VAN DE GRAMPEL , Erhard BRUSS , Rob BOONMAN
Abstract: Automotive articles include a polycarbonate-siloxane copolymer including: from about 49.5 wt % to about 97.95 wt % of at least one polycarbonate polymer; from about 2.0 wt % to about 49.5 wt % of at least one polycarbonate-siloxane copolymer; and from about 0.05 wt % to about 1.0 wt % of at least one release agent. The composition exhibits a melt volume flow rate of at least about 25 cm3/10 min, a ductile/brittle transition temperature of less than or equal to 10° C., and high gloss after metallization. Methods of forming an article include: forming a thermoplastic composition, and injection molding, extruding, rotational molding, blow molding or thermoforming the thermoplastic composition in a mold to form the article. Such compositions and methods may be used to form articles including, but not limited to, automotive bezels and reflectors.
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17.
公开(公告)号:US20190185664A1
公开(公告)日:2019-06-20
申请号:US16327639
申请日:2017-07-28
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Maria Dolores MARTINEZ CANOVAS , Mark Adrianus Johannes VAN DER MEE , Robert Dirk VAN DE GRAMPEL , Erhard BRUSS , Rob BOONMAN
CPC classification number: C08L69/00 , C08G64/085 , C08K5/11 , C08L83/04 , C08L2201/02 , C23C18/1641 , C08K5/103 , C08L83/10
Abstract: Thermoplastic compositions include a polycarbonate-siloxane copolymer comprising: from about 49.5 wt % to about 97.95 wt % of at least one polycarbonate polymer; from about 2.0 wt % to about 49.5 wt % of at least one polycarbonate-siloxane r copolymer; and from about 0.05 wt % to about 1.0 wt % of at least one release agent. The composition exhibits a melt volume flow rate of at least about 25 cm3/10 min, a ductile/brittle transition temperature of less than or equal to 10° C., and high gloss after metallization and/or a substantial tensile yield strength retention improvement when exposed to sunscreen. Methods of forming an article include: forming a mixture comprising the thermoplastic composition, and injection molding, extruding, rotational molding, blow molding or thermoforming the mixture in a mold to form the article. Such compositions and methods may be used to form articles including, but not limited to, automotive bezels and housings in consumer devices.
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公开(公告)号:US20180194907A1
公开(公告)日:2018-07-12
申请号:US15741521
申请日:2016-06-27
Applicant: SABIC Global Technologies B.V.
Inventor: Domenico LA CAMERA , Erik SCHWARTZ , Robert Dirk VAN DE GRAMPEL , Ronald LUIJTEN
IPC: C08J3/24 , C08J3/28 , C08K3/04 , C08K5/101 , C08K5/3492 , C08K7/14 , C08L27/18 , C08L69/00 , C08L71/12 , C08L77/00 , C08L79/08 , C08L83/04
CPC classification number: C08J3/247 , C08J3/24 , C08J3/28 , C08J5/005 , C08J5/042 , C08J5/043 , C08K3/041 , C08K3/042 , C08K5/0025 , C08K5/092 , C08K5/101 , C08K5/20 , C08K5/3417 , C08K5/34924 , C08K5/526 , C08K7/14 , C08L27/18 , C08L67/02 , C08L69/00 , C08L71/123 , C08L77/00 , C08L77/02 , C08L77/06 , C08L79/08 , C08L83/04 , C08L2205/16
Abstract: The disclosure concerns compositions comprising: from about 40 wt. % to about 99.5 wt. % of a polymer base resin; N from 0 wt. % to about 60 wt. % of a reinforcing filler; from 0 wt. % to about 25 wt. % of a lubricant; and from about 0.05 wt. % to about 6 wt. % of a cross-linking agent; wherein the composition is treated to induce cross-linking, wherein the combined weight percent value of all components does not exceed 100 wt % and wherein the composition shows improved tensile fatigue versus a corresponding composition without the cross-linking agent.
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