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    HYBRID POLYMERS
    11.
    发明申请
    HYBRID POLYMERS 审中-公开
    混合聚合物

    公开(公告)号：US20140378569A1

    公开(公告)日：2014-12-25

    申请号：US14364894

    申请日：2012-12-06

    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

    Inventor： Julio A. Abusleme ,  Fiorenza D'Aprile ,  Serena Carella

    IPC: C08G18/78 ,  C08G18/62

    Abstract: The present invention pertains to a polyurethane fluoropolymer [polymer (Fp)] obtainable by reacting: (i) at least one fluoropolymer [polymer (F)] comprising one or more recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: —R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, —RH is a C1-C10 hydrocarbon group comprising from 1 to 5 hydroxyl groups, x being an integer comprised between 1 and 5, and, optionally, comprising one or more functional groups selected from double bonds, epoxy, ester, ether and carboxylic acid groups, with (ii) at least one isocyanate compound comprising at least one isocyanate functional group [compound (I)], (iii) optionally in the presence of one or more chain extenders, said polyurethane fluoropolymer [polymer (Fp)] comprising at least one bridging group having formula (a) here below: wherein: —RH is a C1-C5 hydrocarbon group comprising from 1 to 5 urethane moieties, x being an integer comprised between 1 and 5, and, optionally, comprising one or more functional groups selected from double bonds, epoxy, ester, ether and carboxylic acid groups. The invention also pertains to a process for the manufacture of said polymer (Fp) and to uses of said polymer (Fp).

    Abstract translation: 本发明涉及可通过以下反应获得的聚氨酯氟聚合物[聚合物（Fp）]：（i）至少一种包含一种或多种衍生自至少一种（甲基）丙烯酸单体的重复单元的含氟聚合物[聚合物（F） MA）]，其中：-R1，R2和R3彼此相同或不同，独立地选自氢原子和C1-C3烃基，-RH是C1-C10 包含1至5个羟基的烃基，x是1至5的整数，并且任选地包含一个或多个选自双键，环氧基，酯，醚和羧酸基团的官能团，和（ii）在 包含至少一种异氰酸酯官能团[化合物（I）]，（iii）任选在一种或多种扩链剂存在下的至少一种异氰酸酯化合物，所述聚氨酯氟聚合物[聚合物（Fp）]]包含至少一个具有式（ a）如下：其中：-RH是C1-C5 包含1至5个氨基甲酸酯部分的烃基，x是1至5的整数，并且任选地包含一个或多个选自双键，环氧基，酯，醚和羧酸基团的官能团。 本发明还涉及制备所述聚合物（Fp）的方法和所述聚合物（Fp）的用途。

    Hybrid polymers
    15.
    发明授权
    Hybrid polymers 有权

    公开(公告)号：US10920006B2

    公开(公告)日：2021-02-16

    申请号：US14364894

    申请日：2012-12-06

    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

    Inventor： Julio A. Abusleme ,  Fiorenza D'Aprile ,  Serena Carella

    IPC: C08G18/62 ,  C08G18/76 ,  C08G18/42 ,  C08G18/10 ,  C08G18/78 ,  C08G18/32 ,  C08G18/28 ,  C08G18/75 ,  C08G18/48 ,  C08G18/65 ,  C08J5/22 ,  C08G101/00

    Abstract: The present invention pertains to a polyurethane fluoropolymer [polymer (Fp)] obtainable by reacting: (i) at least one fluoropolymer [polymer (F)] comprising one or more recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: —R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, —RH is a C1-C10 hydrocarbon group comprising from 1 to 5 hydroxyl groups, x being an integer comprised between 1 and 5, and, optionally, comprising one or more functional groups selected from double bonds, epoxy, ester, ether and carboxylic acid groups, with (ii) at least one isocyanate compound comprising at least one isocyanate functional group [compound (I)], (iii) optionally in the presence of one or more chain extenders, said polyurethane fluoropolymer [polymer (Fp)] comprising at least one bridging group having formula (a) here below: wherein: —RH is a C1-C5 hydrocarbon group comprising from 1 to 5 urethane moieties, x being an integer comprised between 1 and 5, and, optionally, comprising one or more functional groups selected from double bonds, epoxy, ester, ether and carboxylic acid groups. The invention also pertains to a process for the manufacture of said polymer (Fp) and to uses of said polymer (Fp).

    FLUOROPOLYMER COMPOSITION
    17.
    发明公开
    FLUOROPOLYMER COMPOSITION 审中-公开

    公开(公告)号：US20230272135A1

    公开(公告)日：2023-08-31

    申请号：US18043712

    申请日：2021-08-23

    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.

    Inventor： Stefana Musio ,  Serena Carella ,  Giulio Brinati

    IPC: C08F214/24

    CPC classification number: C08F214/245

    Abstract: The invention pertains to a thermoplastic fluoropolymer composition comprising one or more polymer A comprising recurring units derived from ethylene and recurring units derived from halogenated monomers selected from chlorotrifluoroethylene (CTFE) and tetrafluoroethylene (TFE) and one or more polymer B comprising recurring units derived from ethylene, recurring units derived from halogenated monomers selected from CTFE and TFE, and recurring units derived from hexafluoroisobutylene (HFIB) and/or perfluoropropylvinylether (PPVE). The resulting composition allows to manufacture films having exceptional transparency and good mechanical properties which can be used for examples as architectural films.

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