Abstract:
Methods for making anodes for lithium ion devices are provided. The methods include milling germanium powder, carbon, and boron carbide powder to form a nano-particle mixture having a particle size of 20 to 100 nm; adding an emulsion of tungsten carbide nano-particles having a particle size of 20 to 60 nm to the mixture to form an active material; and adding a polymeric binder to the active material to form the anode, wherein the weight percentage of the germanium in the anode is between 5 to 80 weight % of the total weight of the anode, the weight percentage of boron in the anode is between 2 to 20 weight % of the total weight of the anode and the weight percentage of tungsten in the anode is between 5 to 20 weight % of the total weight of the anode.
Abstract:
An anode material for a lithium ion device includes an active material including germanium and boron. The weight percentage of the germanium is between about 45 to 80 weight % of the total weight of the anode material and the weight percentage of the boron is between about 2 to 20 weight % of the total weight of the anode material. The active material may include carbon at a weight percentage of between 0.5 to about 5 weight % of the total weight of the anode material. Additional materials, methods of making and devices are taught.
Abstract:
A system and method for fast charging of a lithium-ion battery, including: continuously monitoring a state of charge (SOC) of the lithium-ion battery; during a normal mode of operation and upon detecting that the battery is at the predetermined low charge level, discontinuing the discharge; upon detecting that the battery is connected to a charger, providing charging rate of at least 4C for at least part of charging; and upon detecting that the battery, while connected to the charger is at the predetermined high charge level, discontinue the charging, wherein the predetermined low charge level and the predetermined high charge level define a consumable capacity of the battery, wherein the consumable capacity is below 50% of the full capacity of the battery.
Abstract:
Cathodes for a fast charging lithium ion battery, processes for manufacturing thereof and corresponding batteries are provided. Cathode formulations comprise cathode material having an olivine-based structure, binder material, and monomer material selected to polymerize into a conductive polymer upon partial delithiation of the cathode material during at least a first charging cycle of a cell having a cathode made of the cathode formulation. When the cathode is used in a battery, polymerization is induced in-situ (in-cell) during first charging cycle(s) of the battery to provide a polymer matrix which is evenly dispersed throughout the cathode.
Abstract:
Improved anodes and cells are provided, which enable fast charging rates with enhanced safety due to much reduced probability of metallization of lithium on the anode, preventing dendrite growth and related risks of fire or explosion. Anodes and/or electrolytes have buffering zones for partly reducing and gradually introducing lithium ions into the anode for lithiation, to prevent lithium ion accumulation at the anode electrolyte interface and consequent metallization and dendrite growth. Various anode active materials and combinations, modifications through nanoparticles and a range of coatings which implement the improved anodes are provided.
Abstract:
Improved anodes and cells are provided, which enable fast charging rates with enhanced safety due to much reduced probability of metallization of lithium on the anode, preventing dendrite growth and related risks of fire or explosion. Anodes and/or electrolytes have buffering zones for partly reducing and gradually introducing lithium ions into the anode for lithiation, to prevent lithium ion accumulation at the anode electrolyte interface and consequent metallization and dendrite growth. Various anode active materials and combinations, modifications through nanoparticles and a range of coatings which implement the improved anodes are provided.
Abstract:
An anode material for a lithium ion device includes an active material including silicon nanoparticles and boron carbide nanoparticles. The boron carbide nanoparticles are at least one order of magnitude smaller than the silicon nanoparticles. The weight percentage of the silicon is between about 4 to 35 weight % of the total weight of the anode material and the weight percentage of the boron carbide is between about 2.5 to about 25.6% of the total weight of the anode material. The active material may include carbon at a weight percentage of between 5 to about 60 weight % of the total weight of the anode material. Additional materials, methods of making and devices are taught.
Abstract:
Active materials for anodes for lithium ion devices are disclosed. An active may comprise germanium nano-particles having a particle size of 20 to 100 nm, wherein the weight percentage of the germanium is between 72 to 96 weight % of the total weight of the active material; boron carbide nano-particles having a particle size of 20 to 100 nm, wherein the weight percentage of boron in the active material is between 3 to 6 weight % of the total weight of the active material; and tungsten carbide nano-particles having a particle size of 20 to 60 nm, wherein the weight percentage of tungsten in the active material is between 6 to 25 weight % of the total weight of the active material.
Abstract:
Electrolytes, anodes, lithium ion cells and methods are provided for preventing lithium metallization in lithium ion batteries to enhance their safety. Electrolytes comprise up to 20% ionic liquid additives which form a mobile solid electrolyte interface during charging of the cell and prevent lithium metallization and electrolyte decomposition on the anode while maintaining the lithium ion mobility at a level which enables fast charging of the batteries. Anodes are typically metalloid-based, for example include silicon, germanium, tin and/or aluminum. A surface layer on the anode bonds, at least some of the ionic liquid additive to form an immobilized layer that provides further protection at the interface between the anode and the electrolyte, prevents metallization of lithium on the former and decomposition of the latter.
Abstract:
Improved anodes and cells are provided, which enable fast charging rates with enhanced safety due to much reduced probability of metallization of lithium on the anode, preventing dendrite growth and related risks of fire or explosion. Anodes and/or electrolytes have buffering zones for partly reducing and gradually introducing lithium ions into the anode for lithiation, to prevent lithium ion accumulation at the anode electrolyte interface and consequent metallization and dendrite growth. Various anode active materials and combinations, modifications through nanoparticles and a range of coatings which implement the improved anodes are provided.