ANTI-SCORCH COMPOSITIONS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME

    公开(公告)号:US20120178865A1

    公开(公告)日:2012-07-12

    申请号:US13497537

    申请日:2009-09-29

    IPC分类号: C08K3/06 C08F236/20 C08L81/04

    摘要: The invention provides a composition comprising at least the following: A) interpolymer comprising, in polymerized form, ethylene, an α-olefm and a nonconjugated polyene; B) sulfur; C) at least one phase transfer catalyst (PTC) selected from the group consisting of the following: Formula (1), wherein each R group is, independently, an alky group having from 4 to 32 carbon atoms, and X is a halogen ion; Formula (2), Wherein the R group is an alky group having from 4 to 32, and X is a halogen ion; Formula (3), wherein R1 is the alky group having from 1 to 4 carbon atoms, R2 is an alkyl group having from 1 to 32 carbon atoms, and X is a halogen ion; and combinations of (1), (2) and (3); and D) at least one primary accelerator selected from the group consisting of the following: Formula (a), wherein R is H, or a heterocyclic substituent; Formula (b), wherein M is Zn2+, K+, Na+, Cu2+ or an alkyl ammonium; Formula (c), wherein R′ and R″ are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocyclic substituent, or wherein R′ and R″ together form a cyclic structure; Formula (d), wherein R, R′, R″ and R′″ are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocyclic substituent; or wherein R and R′ are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocyclic substituent, and R″ and R′″ together form a cyclic structure; or wherein R″ and R′″ are each, independently, H, an alkyl, a cyclic alkyl, an aromatic, or a heterocyclic substituent, and R and R′ together form a cyclic structure; or wherein R″ and R′″ together form a cyclic structure, and R and R′ together form a cyclic structure; and combinations thereof.