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公开(公告)号：US08956441B2
公开(公告)日：2015-02-17
申请号：US13660888
申请日：2012-10-25
Applicant: Shell Oil Company
Inventor： Justus Theodorus Gerardus Te Braake , Maarten Bracht , Desmond Andrew Bungku , Wouter David Van De Graaf , Xander Linders , Sivakumar Sadasivan Vijayakumari
IPC: B01D53/047 , B01D53/04 , C10K1/32 , C10G2/00 , B01D53/22
CPC classification number: B01D53/04 , B01D53/047 , B01D53/229 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2253/116 , B01D2256/10 , B01D2256/16 , B01D2257/502 , B01D2259/40001 , B01D2259/40007 , B01D2259/4062 , B01D2259/414 , C10G2/32 , C10G2300/1022 , C10G2300/4081 , C10K1/32
Abstract: A method for producing a gas comprising at least 80 vol % carbon monoxide from a Fischer-Tropsch off-gas comprises: (1) feeding Fischer-Tropsch off-gas through a column comprising an adsorbent bed at high pressure and discharging effluent; (2) reducing the pressure in the column and the bed slightly; (3) rinsing the column and the adsorbent bed with methane or a mixture of methane and carbon dioxide; (4) reducing the pressure of the column and adsorbent bed to a low pressure; (5) rinsing the column and adsorbent bed with a mixture of hydrogen and nitrogen; (6) pressurizing the column and adsorbent bed to a high pressure using a mixture of hydrogen and nitrogen. The product stream obtained in step (3) comprising at least 80 vol % carbon monoxide can be sent as feed to a Fischer-Tropsch reaction. In an embodiment, a gas comprising at least 80 vol % hydrogen is also produced.
Abstract translation: 一种从费 - 托废气中生产包含至少80体积％一氧化碳的气体的方法包括：（1）在高压下通过包含吸附剂床的塔进料费 - 托废气并排出流出物; （2）稍微降低柱和床的压力; （3）用甲烷或甲烷和二氧化碳的混合物冲洗塔和吸附床; （4）将柱和吸附剂床的压力降低到低压; （5）用氢和氮的混合物冲洗柱和吸附剂床; （6）使用氢和氮的混合物将塔和吸附剂床加压至高压。 包含至少80体积％一氧化碳的步骤（3）中获得的产物流可作为进料送入费 - 托反应。 在一个实施方案中，也产生包含至少80体积％氢气的气体。
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公开(公告)号：US10239013B2
公开(公告)日：2019-03-26
申请号：US15305523
申请日：2015-04-20
Applicant: SHELL OIL COMPANY
IPC: B01D53/047 , C07C7/12 , C07C7/05 , C07C7/04 , C07C7/00
Abstract: The invention relates to a process for recovering methane from a gas stream comprising methane and ethylene, comprising a sorption step which comprises contacting the gas stream comprising methane and ethylene with a sorption agent which has a lower affinity for methane than for ethylene, resulting in sorption of ethylene and 0 to 90% of the methane by the sorption agent and in a gas stream comprising methane in an amount of 10 to 100% based on the amount of methane in the gas stream that is subjected to the sorption step; and a desorption step which comprises desorbing sorbed ethylene and optionally sorbed methane resulting in a gas stream comprising ethylene and optionally methane.
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公开(公告)号：US09828305B2
公开(公告)日：2017-11-28
申请号：US14439267
申请日：2013-10-29
Applicant: SHELL OIL COMPANY
Inventor： Antonius Gijsbertus Johannes Kloth , Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C1/20 , C07C4/06 , C10G45/08 , C10G45/12 , C10G65/12 , C10G2300/1011 , C10G2300/104 , C10G2300/1044 , C10G2300/1051 , C10G2300/1059 , C10G2300/1081 , C10G2300/1085 , C10G2400/02 , C10G2400/20 , C10G2400/22 , Y02P30/42 , C07C11/02
Abstract: The invention provides a process for the preparation of an olefinic product, comprising: (a) reacting an oxygenate feedstock, in a reaction zone in the presence of a molecular sieve catalyst, at a temperature from 350 to 1000° C., to produce a reaction effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the reaction effluent stream by means of an indirect heat exchange to a temperature greater than the dew point temperature of reaction effluent stream; (c) further rapidly cooling the reaction effluent stream to a temperature lower than the dew point temperature of the reaction effluent stream by direct injection of an aqueous liquid into the reaction effluent stream, to form a first quench effluent stream; and (d) separating the first quench effluent stream into a first liquid quench effluent stream and a first gaseous quench effluent stream, comprising the olefinic product.
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公开(公告)号：US09539534B2
公开(公告)日：2017-01-10
申请号：US14758452
申请日：2013-12-31
Applicant: SHELL OIL COMPANY
Inventor： Sivakumar Sadasivan Vijayakumari
IPC: B01D53/047 , C01B3/56 , C01B31/20 , C01B31/18 , C10K1/32 , C10G2/00 , B01J20/08 , B01J20/18 , B01J20/20 , B01J20/10
CPC classification number: B01D53/047 , B01D2253/102 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2253/116 , B01D2256/10 , B01D2256/16 , B01D2256/20 , B01D2256/245 , B01D2257/502 , B01D2257/504 , B01D2259/40071 , B01J20/08 , B01J20/103 , B01J20/18 , B01J20/20 , B01J2220/42 , B01J2220/606 , C01B3/56 , C01B32/40 , C01B32/50 , C10G2/32 , C10K1/32 , Y02C10/08 , Y02P20/152
Abstract: This invention concerns a method for recovering carbon monoxide and carbon dioxide from Fischer-Tropsch off-gas by feeding Fischer-Tropsch off-gas through a column comprising an adsorbent bed, and discharging effluent, optionally rinsing the column and the adsorbent bed by feeding NG and discharging effluent until at least 60% of the carbon monoxide that was present in the bed is discharged, pressurizing the column and adsorbent bed with NG, rinsing the column and the adsorbent bed by feeding NG until at least 50% of the carbon dioxide present at the commencement of this rinsing step is discharged, rinsing the column and adsorbent bed by feeding a mixture of hydrogen and nitrogen, pressurizing the column and adsorbent bed by feeding a mixture of hydrogen and nitrogen. With this method a feed comprising at least 50 vol % carbon monoxide can be produced. Furthermore, methane and carbon dioxide at a high pressure can be recovered from the Fischer-Tropsch gas. This can be fed to a gasifier or a reformer. In a preferred embodiment a gas comprising at least 80 vol % hydrogen is produced as well.
Abstract translation: 本发明涉及一种从费 - 托废气中回收一氧化碳和二氧化碳的方法，该方法是通过将费 - 托废气通过包括吸附床的塔排出，排出流出物，任选地通过进料NG漂洗该柱和吸附剂床 并排出流出物直到存在于床中的一氧化碳的至少60％排出，用NG加压柱和吸附剂床，通过进料NG冲洗柱和吸附床，直至存在至少50％的二氧化碳 在该冲洗步骤开始时排出，通过供给氢和氮的混合物冲洗柱和吸附剂床，通过供给氢和氮的混合物来加压塔和吸附剂床。 使用该方法可以生产包含至少50体积％一氧化碳的进料。 此外，可以从费 - 托气体回收高压下的甲烷和二氧化碳。 这可以被供给到气化器或重整器。 在优选的实施方案中，也产生包含至少80体积％的氢的气体。
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15.发明授权Process for the preparation of an olefinic product comprising ethylene and/or propylene 有权制备包含乙烯和/或丙烯的烯烃产物的方法公开(公告)号：US09505669B2
公开(公告)日：2016-11-29
申请号：US14655343
申请日：2013-12-24
Applicant: SHELL OIL COMPANY
Inventor： Jeroen Van Westrenen , Sivakumar Sadasivan Vijayakumari
CPC classification number: C07C1/20 , C07C4/04 , C07C7/005 , C07C2529/00 , C10G9/36 , Y02P30/42 , Y02P30/48 , C07C11/04 , C07C11/06
Abstract: The invention provides a process for the preparation of an olefinic product comprising ethylene and/or propylene comprising: a) steam cracking a paraffinic feedstock to obtain an effluent comprising olefins; b) converting an oxygenate to obtain a gaseous effluent comprising olefins; c) subjecting both effluents to water removal and compression steps, wherein the effluents are combined before the water removal step, between the water removal and the compression steps or after the compression step to obtain a combined gaseous effluent; d) removing acid gas from the combined gaseous effluent obtained in step c), wherein the combined gaseous effluent is treated with a caustic solution in a caustic tower and a non-aqueous liquid stream comprising one or more aromatic C7+ hydrocarbons is added to the caustic solution to control the formation of red oil, to obtain a treated gaseous effluent; and e) separating the olefinic product from the treated gaseous effluent.
Abstract translation: 本发明提供了一种制备包含乙烯和/或丙烯的烯烃产物的方法，包括：a）蒸汽裂解链烷烃原料以获得包含烯烃的流出物; b）转化含氧化合物以获得包含烯烃的气态流出物; c）使两种废水进行除水和压缩步骤，其中在除水步骤之前，在除水和压缩步骤之间或在压缩步骤之后组合废水以获得组合的气态流出物; d）从步骤c）中得到的组合的气态流出物中除去酸性气体，其中将合并的气态流出物用苛性塔中的苛性碱溶液处理，将包含一种或多种芳族C 7 +烃的非水液体流加入到苛性碱 解决方案来控制红油的形成，得到经处理的气态流出物; 和e）从处理的气态流出物中分离出烯属产物。
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Patent Agency Ranking
公开(公告)号：US09221726B2
公开(公告)日：2015-12-29
申请号：US13727778
申请日：2012-12-27
Applicant: SHELL OIL COMPANY
CPC classification number: C07C2/66 , C07C2/864 , C07C4/06 , C07C2529/40 , C07C2529/70 , Y02P20/125 , C07C15/08
Abstract: A process preparing an aromatic product comprising xylene, the process comprising: a) cracking a feedstock to obtain a cracker effluent comprising olefins and aromatics; b) converting an oxygenate feedstock in an oxygenate-to-olefins conversion system, comprising a reaction zone in which an oxygenate feedstock is contacted with a catalyst to obtain a conversion effluent comprising benzene, toluene, xylene and olefins; c) combining at least part of the cracker effluent and at least part of the conversion effluent to obtain a combined effluent, the combined effluent comprising aromatics; d) separating at least a portion of the benzene and/or toluene from the combined effluent to form a benzene and/or toluene stream; e) separating the olefins from the combined effluent; f) separating xylene from the combined effluent to form a xylene stream; and g) recycling at least a part of the benzene and/or toluene streams as recycled aromatics to step b).
Abstract translation: 一种制备包含二甲苯的芳族产物的方法，该方法包括：a）裂化原料以获得包含烯烃和芳族化合物的裂化器流出物; b）转化含氧化合物至烯烃转化体系中的含氧化合物原料，其包含其中含氧化合物原料与催化剂接触的反应区，以获得包含苯，甲苯，二甲苯和烯烃的转化流出物; c）将至少部分裂化器流出物和至少部分转化流出物混合以获得组合的流出物，所述组合流出物包含芳族化合物; d）将苯和/或甲苯的至少一部分与合并的流出物分离以形成苯和/或甲苯料流; e）从合并的流出物中分离烯烃; f）从合并的流出物中分离二甲苯以形成二甲苯流; 和g）将至少一部分苯和/或甲苯物流作为再循环芳烃回收至步骤b）。
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公开(公告)号：US20150158799A1
公开(公告)日：2015-06-11
申请号：US14368523
申请日：2012-12-20
Applicant: SHELL OIL COMPANY
Inventor： Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
IPC: C07C29/141 , C07C45/50
CPC classification number: C07C29/141 , C07C1/20 , C07C1/22 , C07C4/06 , C07C29/16 , C07C45/505 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2529/40 , C07C2529/83 , C07C2529/84 , C07C2529/85 , Y02P30/42
Abstract: The present invention provides a process for the production of alcohols, which process comprises the steps of: (a) reacting an oxygenate and/or olefinic feed in a reactor in the presence of a molecular sieve catalyst to form an effluent comprising olefins, comprising propylene; (b) separating the effluent comprising olefins as obtained in step (a) into at least a first olefinic product fraction comprising propylene and a second olefinic product fraction; (c) subjecting at least part of the first olefinic product fraction as obtained in step (b) to a hydroformylation process to form aldehydes; (d) hydrogenating at least part of the aldehydes as obtained in step (c) to form alcohols; (e) separating at least part of the alcohols as obtained in step (d) into at least a first product fraction of alcohols and a second product fraction of alcohols; and (f) recycling at least part of the first or second product fraction of alcohols to step (a).
Abstract translation: 本发明提供了一种生产醇的方法，该方法包括以下步骤：（a）在分子筛催化剂存在下使反应器中的含氧化合物和/或烯烃进料反应，以形成包含烯烃的流出物，其包含丙烯 ; （b）将步骤（a）中获得的包含烯烃的流出物分离成至少包含丙烯和第二烯属产物馏分的第一烯烃产物级分; （c）将步骤（b）中获得的至少部分第一烯属产物级分进行加氢甲酰化过程以形成醛; （d）氢化步骤（c）中获得的至少部分醛以形成醇; （e）将步骤（d）中获得的至少一部分醇分离成至少第一产物级分的醇和第二产物级分的醇; 和（f）将至少部分第一或第二产物级分的醇再循环到步骤（a）。
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18.发明申请公开(公告)号：US20140357919A1
公开(公告)日：2014-12-04
申请号：US14360855
申请日：2012-11-28
Inventor： Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: B01J29/90 , B01D53/1493 , B01D53/28 , B01D2252/2023 , B01D2256/12 , B01J29/40 , B01J29/85 , B01J38/12 , C07C1/20 , C07C1/22 , C07C4/06 , C07C2523/02 , C07C2523/04 , C07C2529/40 , C07C2529/70 , Y02P20/584 , Y02P30/42 , C07C11/02
Abstract: The present invention relates to a process for the oxidative regeneration of a deactivated catalyst comprising molecular sieve to provide a regenerated molecular sieve catalyst, wherein said deactivated catalyst is from one or both of an oxygenate to olefin process and a olefin cracking process, said regeneration process comprising at least the steps of providing a regeneration gas stream comprising oxidant; treating the regeneration gas stream with a liquid adsorbent stream comprising an ethylene glycol in a contaminant absorption zone to remove at least a part of one or more of any water, any alkali metal ion and any alkaline earth metal ion present in the regeneration gas stream to provide a treated regeneration gas stream comprising oxidant; regenerating a deactivated catalyst comprising molecular sieve with the treated regeneration gas stream to provide a regenerated catalyst comprising regenerated molecular sieve.
Abstract translation: 本发明涉及包含分子筛的失活催化剂的氧化再生方法，以提供再生分子筛催化剂，其中所述失活催化剂是含氧化合物与烯烃方法中的一种或两种以及烯烃裂解方法，所述再生过程 至少包括提供包含氧化剂的再生气流的步骤; 在污染物吸收区中用包含乙二醇的液体吸附剂流处理再生气流，以将再生气流中存在的任何水，任何碱金属离子和任何碱土金属离子中的一种或多种中的一种或多种除去至 提供包含氧化剂的经处理的再生气流; 使经处理的再生气流再生包含分子筛的失活催化剂以提供包含再生分子筛的再生催化剂。
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19.发明授权Process for the preparation of an olefinic product comprising ethylene and/or propylene 有权制备包含乙烯和/或丙烯的烯烃产物的方法公开(公告)号：US08895792B2
公开(公告)日：2014-11-25
申请号：US14136047
申请日：2013-12-20
Applicant: Shell Oil Company
Inventor： Sivakumar Sadasivan Vijayakumari , Jeroen Van Westrenen
CPC classification number: C07C1/22 , C07C1/20 , C07C11/04 , C07C11/06 , C07C29/74 , C07C29/76 , C07C31/04 , C07C2529/40 , C07C2529/70 , C07C2529/83 , C07C2529/84 , C07C2529/85 , Y02P30/42 , C07C11/02
Abstract: An oxygenate to olefins (OTO) process, comprising the steps of: (i) purifying an oxygenate feedstream comprising one or more ionic contaminants by contacting the feedstream with a membrane, resulting in the formation of a retentate and a permeate separated by the membrane, which permeate is a purified oxygenate stream which contains a lower ionic contaminant concentration than the original oxygenate feedstream; (ii) introducing the purified oxygenate stream into an oxygenate to olefins reaction zone; and (iii) contacting the purified oxygenate stream with a molecular sieve catalyst in the oxygenate to olefins reaction zone to form a product stream comprising olefins.
Abstract translation: 一种含氧化合物至烯烃（OTO）方法，包括以下步骤：（i）通过使进料流与膜接触，纯化含有一种或多种离子污染物的含氧物原料流，导致形成由膜分离的渗余物和渗透物， 该渗透物是纯化的含氧化合物流，其含有比原始含氧化合物进料流更低的离子污染物浓度; （ii）将纯化的含氧物流引入含氧化合物至烯烃反应区; 和（iii）将纯化的含氧物流与含氧化合物中的分子筛催化剂接触到烯烃反应区，以形成包含烯烃的产物流。
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公开(公告)号：US10220347B2
公开(公告)日：2019-03-05
申请号：US15322503
申请日：2015-06-29
Applicant: SHELL OIL COMPANY
IPC: B01D53/02 , B01D53/047 , C07C7/12 , C07C7/13
Abstract: The invention relates to a process for recovering methane from a gas stream comprising methane and ethylene, comprising: a sorption step which comprises contacting the gas stream comprising methane and ethylene with a sorption agent which has a lower affinity for methane than for ethylene, wherein the gas stream comprising methane and ethylene also comprises a compound for which the sorption agent has a lower affinity than for methane and ethylene, resulting in sorption of ethylene and methane by the sorption agent and in a gas stream comprising the compound for which the sorption agent has a lower affinity than for methane and ethylene; a first desorption step which comprises desorbing part of the sorbed methane resulting in a gas stream comprising methane in an amount of 1 to 99.9% based on the amount of methane in the gas stream that is subjected to the sorption step; and a second desorption step which comprises desorbing sorbed compounds resulting in a gas stream comprising the desorbed compounds.
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