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11.
公开(公告)号:US20210213690A1
公开(公告)日:2021-07-15
申请号:US17267975
申请日:2019-08-20
Applicant: Toray Industries, Inc.
Inventor: Masayuki Koshi , Shoma Ishida , Yoshihiro Naruse
Abstract: A method produces thermoplastic resin-impregnated sheet-shaped reinforcing fiber bundle obtained by impregnating reinforcing fibers made from continuous fibers with a thermoplastic resin, said method including: an application step in which a sheet-shaped reinforcing fiber bundle obtained by arranging reinforcing fibers made from continuous fibers in one direction is passed through an application section which retains thermoplastic resin, and the thermoplastic resin is applied to the sheet-shaped reinforcing fiber bundle to constitute a thermoplastic resin-impregnated sheet-shaped reinforcing fiber bundle; a further impregnation step in which the applied thermoplastic resin is further impregnated into the inside of the thermoplastic resin-impregnated sheet-shaped reinforcing fiber bundle; and a shaping step in which the thermoplastic resin-impregnated sheet-shaped reinforcing fiber bundle is shaped and solidified by cooling.
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公开(公告)号:US10066084B2
公开(公告)日:2018-09-04
申请号:US14763188
申请日:2014-02-19
Applicant: Toray Industries, Inc.
Inventor: Katsuhiro Miyoshi , Takashi Shimada , Takafumi Hashimoto , Tetsuya Ohara , Yoshihiro Naruse
Abstract: A stampable sheet includes a resin and carbon fiber sheet including fiber bundles of discontinuous carbon fibers, wherein the carbon fiber sheet includes fiber bundles having a bundle width of 50 μm or greater and opened fibers ranging from fiber bundles having a bundle width less than 50 μm to fibers obtained by opening to the single-fiber level. When the direction along which the opened fibers have been oriented most is a 0° direction and the range of from the 0° to 90° direction is divided into angular zones, the distribution curve showing the proportion of the number of fiber bundles in each angular zone to that in all angular zones and the distribution curve showing the proportion of the number of opened fibers in each angular zone to that in all angular zones are reverse to each other in terms of gradient of the 0° to 90° direction.
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公开(公告)号:US09896563B2
公开(公告)日:2018-02-20
申请号:US14866367
申请日:2015-09-25
Applicant: Toray Industries, Inc.
Inventor: Yoshihiro Naruse , Satoshi Kondo , Shuichi Nonaka , Keishi Miwa , KaKuji Murakami
CPC classification number: C08J9/36 , A61K8/02 , A61K8/0208 , A61Q1/12 , A61Q19/00 , A61Q19/08 , C08J9/28 , C08J2323/12 , C08J2367/03 , C08J2377/02 , C08J2381/04 , D21H13/10 , Y10T428/298
Abstract: A spongelike structure or a powder having fibers three-dimensionally arranged therein with high dispersibility, whose apparent density can be designed depending on the purpose or utility, as well as a process producing it. A fiber dispersion in which fibers having a number mean diameter in a predetermined range are dispersed in a dispersion medium, and this fiber dispersion is dried to remove the dispersion medium, thereby, a spongelike structure and a powder are produced.
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公开(公告)号:US09481770B2
公开(公告)日:2016-11-01
申请号:US14403677
申请日:2013-05-15
Applicant: Toray Industries, Inc.
Inventor: Yoshihiro Naruse , Katsuhiro Miyoshi , Takashi Shimada , Takafumi Hashimoto , Tetsuya Ohara
CPC classification number: C08J5/06 , B32B2250/05 , B32B2260/046 , B32B2262/106 , B32B2305/076 , B32B2305/28 , B32B2307/54 , C08J5/042 , C08J2377/02
Abstract: A carbon fiber composite material which includes a carbon fiber sheet as a reinforcing material and a thermoplastic resin as a matrix resin, the carbon fiber sheet exhibiting a work per areal weight of 1×10−3 to 30×10−3 [(N·mm)/(g/m2)] in a tensile test using a specimen having a width of 25 mm. The carbon fiber composite material exhibits excellent flowability in molding and ensures excellent moldability even when molded into a complicated shape. Further, the composite material can yield a molded product which has high mechanical properties with minimized dispersion, thus being suitable for press molding.
Abstract translation: 作为增强材料的碳纤维片和作为基质树脂的热塑性树脂的碳纤维复合材料,所述碳纤维片的每面重为1×10-3〜30×10-3 [(N· mm)/(g / m 2)]在使用宽度为25mm的试样的拉伸试验中。 碳纤维复合材料在成型时表现出优异的流动性,并且即使在模制成复杂形状时也确保优异的成型性。 此外,复合材料可以产生具有高机械性能并且最小化分散体的模制产品,因此适合于压制成型。
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公开(公告)号:US20150183941A1
公开(公告)日:2015-07-02
申请号:US14403677
申请日:2013-05-15
Applicant: Toray Industries, Inc.
Inventor: Yoshihiro Naruse , Katsuhiro Miyoshi , Takashi Shimada , Takafumi Hashimoto , Tetsuya Ohara
IPC: C08J5/06
CPC classification number: C08J5/06 , B32B2250/05 , B32B2260/046 , B32B2262/106 , B32B2305/076 , B32B2305/28 , B32B2307/54 , C08J5/042 , C08J2377/02
Abstract: A carbon fiber composite material which includes a carbon fiber sheet as a reinforcing material and a thermoplastic resin as a matrix resin, the carbon fiber sheet exhibiting a work per areal weight of 1×10−3 to 30×10−3 [(N·mm)/(g/m2)] in a tensile test using a specimen having a width of 25 mm. The carbon fiber composite material exhibits excellent flowability in molding and ensures excellent moldability even when molded into a complicated shape. Further, the composite material can yield a molded product which has high mechanical properties with minimized dispersion, thus being suitable for press molding.
Abstract translation: 作为增强材料的碳纤维片和作为基质树脂的热塑性树脂的碳纤维复合材料,所述碳纤维片的每面重为1×10-3〜30×10-3 [(N· mm)/(g / m 2)]在使用宽度为25mm的试样的拉伸试验中。 碳纤维复合材料在成型时表现出优异的流动性,并且即使在模制成复杂形状时也确保优异的成型性。 此外,复合材料可以产生具有高机械性能并且最小化分散体的模制产品,因此适合于压制成型。
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16.
公开(公告)号:US12104044B2
公开(公告)日:2024-10-01
申请号:US17433647
申请日:2020-04-03
Applicant: Toray Industries, Inc.
Inventor: Shoma Ishida , Koji Suzuki , Yoshihiro Naruse
IPC: C08K7/14 , B33Y70/10 , C08L35/02 , C08L61/02 , C08L81/04 , B33Y10/00 , B33Y80/00 , C08K3/04 , C08K3/40
CPC classification number: C08K7/14 , B33Y70/10 , C08L35/02 , C08L61/02 , C08L81/04 , B33Y10/00 , B33Y80/00 , C08K3/04 , C08K3/40 , C08L2205/16 , C08L2207/04
Abstract: A fiber-reinforced thermoplastic resin filament for a 3D printer is formed by impregnating a thermoplastic resin into a plurality of continuous reinforcing fibers, wherein: an average value S of a roundness parameter s of a cross section is 60% to 100%, the average value S being evaluated by (i) taking a photograph of the cross section perpendicular to the axial direction of the filament, (ii) drawing an inscribed circle and a circumscribed circle of the filament in a cross-sectional image and determining the diameter length of each, (iii) calculating the roundness parameter s defined by equation (1), and (iv) repeating (i)-(iii) at a plurality of locations on the filament and calculating the average value S of the roundness parameter s; and the coefficient of variation of the diameter length of the circumscribed circle is 0% to 10%.
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公开(公告)号:US11739185B2
公开(公告)日:2023-08-29
申请号:US17258234
申请日:2019-07-09
Applicant: Toray Industries, Inc.
Inventor: Masayuki Koshi , Naoya Ouchiyama , Yoshihiro Naruse
IPC: C08L81/02 , C08J5/04 , C08K3/04 , C08L101/12
CPC classification number: C08J5/042 , C08K3/04 , C08L101/12
Abstract: A fiber-reinforced polymer alloy substrate, in which continuous reinforcing fibers are arranged in parallel and are impregnated with a polymer alloy, is characterized in that: a polymer alloy obtained by combining thermoplastic resins of at least two types is used as the polymer alloy; the fiber volume content is in the range of 40 to 70% by volume; and the dispersion parameter D of the fibers is 90% or more. In the obtained fiber-reinforced polymer alloy substrate, the reinforcing fibers are dispersed with high uniformity, and high mechanical properties and heat resistance are stably exhibited with low variation.
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18.
公开(公告)号:US20220145047A1
公开(公告)日:2022-05-12
申请号:US17433647
申请日:2020-04-03
Applicant: Toray Industries, Inc.
Inventor: Shoma Ishida , Koji Suzuki , Yoshihiro Naruse
Abstract: A fiber-reinforced thermoplastic resin filament for a 3D printer is formed by impregnating a thermoplastic resin into a plurality of continuous reinforcing fibers, wherein: an average value S of a roundness parameter s of a cross section is 60% to 100%, the average value S being evaluated by (i) taking a photograph of the cross section perpendicular to the axial direction of the filament, (ii) drawing an inscribed circle and a circumscribed circle of the filament in a cross-sectional image and determining the diameter length of each, (iii) calculating the roundness parameter s defined by equation (1), and (iv) repeating (i)-(iii) at a plurality of locations on the filament and calculating the average value S of the roundness parameter s; and the coefficient of variation of the diameter length of the circumscribed circle is 0% to 10%.
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公开(公告)号:US20210277194A1
公开(公告)日:2021-09-09
申请号:US17258234
申请日:2019-07-09
Applicant: Toray Industries, Inc.
Inventor: Masayuki Koshi , Naoya Ouchiyama , Yoshihiro Naruse
IPC: C08J5/04 , C08K3/04 , C08L101/12
Abstract: A fiber-reinforced polymer alloy substrate, in which continuous reinforcing fibers are arranged in parallel and are impregnated with a polymer alloy, is characterized in that: a polymer alloy obtained by combining thermoplastic resins of at least two types is used as the polymer alloy; the fiber volume content is in the range of 40 to 70% by volume; and the dispersion parameter D of the fibers is 90% or more. In the obtained fiber-reinforced polymer alloy substrate, the reinforcing fibers are dispersed with high uniformity, and high mechanical properties and heat resistance are stably exhibited with low variation.
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公开(公告)号:US09616154B2
公开(公告)日:2017-04-11
申请号:US14377051
申请日:2013-01-29
Applicant: Toray Industries, Inc.
Inventor: Tomoyuki Horiguchi , Kosaku Takeuchi , Yoshihiro Naruse , Kazuhiro Tanahashi , Makito Yokoe , Kohei Yamashita
IPC: A61L31/04 , A61L24/04 , A61L15/22 , A61L15/42 , A61L24/00 , A61L26/00 , C08K7/00 , C08L33/26 , C08J5/04 , C08K3/08 , D01D5/36 , D01F6/90 , D01F6/92 , D01F8/12 , D01F8/14
CPC classification number: A61L31/041 , A61L15/225 , A61L15/42 , A61L24/001 , A61L24/0094 , A61L24/043 , A61L26/0095 , A61L2420/06 , C08J5/046 , C08J2333/26 , C08J2367/02 , C08J2371/02 , C08K7/00 , C08K2003/0812 , C08L33/26 , C08L77/00 , C08L2205/16 , D01D5/36 , D01F6/90 , D01F6/92 , D01F8/12 , D01F8/14 , C08L67/04
Abstract: A stimuli-responsive material includes a stimuli-responsive polymer, fibers and water, wherein the fibers have a number average diameter of 1 to 900 nm and are present in the stimuli-responsive material in a dispersed state; and a medical material and an anti-adhesive material, each of which includes a stimuli-responsive material including a stimuli-responsive polymer, fibers and water, wherein the fibers have a number average diameter of 1 to 900 nm and are present in the stimuli-responsive material in a dispersed state.
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