摘要:
A piezoelectric ceramic composition not containing lead, able to be sintered at ordinary pressure, and superior to the past in at least one of the properties unique to piezoelectric ceramic compositions such as the piezoelectric d31 constant, that is, a piezoelectric ceramic composition having a compound of a general formula {Lix(K1-yNay)1-x}(Nb1-z-wTazSbw)O3 where x, y, z, and w are in the ranges of 0≦x≦0.2, 0≦y≦1, 0
摘要翻译:不含铅的压电陶瓷组合物,其能够在常压下烧结,并且在压电陶瓷组合物如压电陶瓷组合物中独特的至少一个特性中优于过去,即压电陶瓷组合物 ,具有通式{Li x 1(x-1-y)Na x 1 x-x N z)的化合物的压电陶瓷组合物 (Nb 1-z w)其中x,y,z,z, z和w在0 <= x <= 0.2,0 <= y <= 1,0,0 z = 0.4和0
摘要:
An anisotropically shaped powder composed of oriented grains with a specific crystal plane {100} of each crystal grain being oriented, a related manufacturing method and a method of manufacturing a crystal oriented ceramics using such an anisotropically shaped powder are disclosed. The anisotropically shaped powder includes a principal component of an isotropic perovskite-based pentavalent metal acid alkali compound represented by a general formula (1): (KaNa1−a)(Nb1−bTab)O3 (wherein 0≦a≦0.8 and 0.02≦b≦0.4). In manufacturing the anisotropically shaped powder, a bismuth-layer-like perovskite-based compound of a specific composition is acid treated; a source of K or the like is added to the resulting acid-treated substance; and the resulting mixture is heated.
摘要翻译:本发明公开了一种各向异性粉末,其特征在于,每个晶粒的特定结晶面{100}的取向晶粒由取向晶粒构成,相关的制造方法和使用这种各向异性粉末的结晶取向陶瓷的制造方法。 各向异性粉末包括由通式(1)表示的各向同性的钙钛矿型五价金属酸性碱性化合物的主要成分:(K 1 a Na 1-a) (Nb 1-b a b b)O 3(其中0 <= a <= 0.8和0.02 <= b <= 0.4)。 在制造各向异性粉末时,将特定组成的铋层状钙钛矿型化合物进行酸处理; 向所得酸处理物质中加入K等来源; 并将所得混合物加热。
摘要:
A stacked piezoelectric element obtained by alternately stacking a piezoelectric ceramic layer and an electrode layer, wherein said electrode layer mainly comprises an electrically conducting base metal electrode material, and the region held between the electrode layer positioned at the top of each ceramic layer and the electrode layer positioned at the bottom of each ceramic layer contains a material having no piezoelectricity, in which a constituent element of said material having no piezoelectricity is uniformly dispersed so as not to have local distribution of a distributed strength exceeding 2 times the distributed strength which is distributed in a largest number of places and is not 0.
摘要:
An object of the present invention is to provide a stacked piezoelectric element with excellent durability, which exhibits an excellent piezoelectric performance irrespective of containing or not containing Pb in the ceramic layer, ensures sufficiently suppressed segregation of the electrically conducting base metal material in the ceramic layer and allows for no segregation of a strengthening substance itself. A stacked piezoelectric element obtained by alternately stacking a piezoelectric ceramic layer and an electrode layer, wherein said electrode layer mainly comprises an electrically conducting base metal electrode material, and the region held between the electrode layer positioned at the top of each ceramic layer and the electrode layer positioned at the bottom of each ceramic layer contains a material having no piezoelectricity, in which a constituent element of said material having no piezoelectricity is uniformly dispersed so as not to have local distribution of a distributed strength exceeding 2 times the distributed strength which is distributed in a largest number of places and is not 0.
摘要:
A multilayered piezoelectric element and a method of producing the multilayered piezoelectric element are disclosed. The multilayered piezoelectric element is made of piezoelectric ceramic layers and electrode formation layers which are alternately laminated. The piezoelectric ceramic layers are made of crystal oriented ceramic as polycrystalline material. The crystal oriented ceramic is made mainly of an isotropic perovskite type compound in which the specific {100} crystal plane of each of crystal grains that form the polycrystalline material is oriented. The electrode formation layers have electrode parts forming inner electrodes containing a conductive metal. The isotropic perovskite type compound is expressed by a general formula (1): [Agh{Lix(K1-yNay)1-x}1-h]j(Nb1-z-wTazSbw)O3-k (1), where 0≦x≦0.2, 0≦y≦1, 0≦z≦0.4, 0≦w≦0.2, x+z+w>0, 0
摘要:
A method of manufacturing a crystal oriented ceramics is disclosed. The method comprises preparing step, mixing step, shaping step and sintering method. At least one of anisotropically shaped powder, used as raw material, and a compact, formed by shaping step, is selected to have an orientation degree of 80% or more with a full width at half maximum (FWHM) of 15° or less according to a rocking curve method. A microscopic powder, having an average grain diameter one-third or less that of anisotropically shaped powder, is prepared for mixing therewith to prepare raw material mixture. The raw material mixture is shaped into the compact so as to allow oriented planes of anisotropically shaped powder to be oriented in a nearly identical direction. In a sintering step, anisotropically shaped powder and microscopic powder are sintered with each other to obtain the crystal oriented ceramics.
摘要:
A laminate type dielectric device is formed by alternately laminating dielectric ceramic layers and electrode layers and integrally baking the laminate product. The electode layers are mainly made of an electrically conductive base metal material having greater standard Gibbs free energy for the formation of a metal oxide at a baking temperature than that of the ceramic material constituting the dielectric ceramic layers. Segregation of the materials including the electrically conductive base metal material does not occur at portions sandwiched between adjacent positive and negative electrode layers among the dielectric ceramic layers.
摘要:
An integrally fired, laminated electromechanical transducing element, fabricated using an inexpensive electrode material and having the electrode characteristic at least equivalent to that of the Ag—Pd electrode, is disclosed. Especially, in the integrally fired, laminated electromechanical transducing element according to the invention, (A) the rigidity of the internal electrode layers is low and the internal stress generated at the time of expansion or contraction of the ceramic layers is small, (B) the antimigration characteristic is superior, (C) the charge loss is small, the heat conductivity is high and the heat radiation characteristic is superior, and/or (D) the bonding strength between the ceramic layers and the electrode layers is high. The integrally fired, laminated electromechanical transducing element (1) according to the invention comprises, for example, an integrally fired laminate member fabricated by integrally firing a plurality of the ceramic layers (11) of piezoelectric ceramic or electrostrictive ceramic and the internal electrode layers (21, 22) interposed between the ceramic layers (11). The main component of the internal electrode layers (21, 22) is a base metal having a rigidity of not more than 160 GPa.
摘要:
A piezoelectric ceramic composition, having a tetragonal perovskite structure and represented by a general formula PbaSrb(ZrcTidSbeMnf)O3 wherein Pb and Sr are assumed to occupy A site, Zr, Ti, Sb and Mn are assumed to occupy B site, and a molar ratio of A site/B site atoms of (a+b)/(c+d+e+f) is more than 1.00 to 1.03, preferably 0.01 to 0.03.
摘要翻译:假设具有四方钙钛矿结构并由通式PbaSrb(ZrcTidSbeMnf)O3表示)的压电陶瓷组合物,其中假定Pb和Sr占据A位,Zr,Ti,Sb和Mn占B位,摩尔比 (a + b)/(c + d + e + f)的A位点/ B位原子大于1.00〜1.03,优选为0.01〜0.03。
摘要:
This invention provides a stacked ceramic body that prevents reaction between components of dielectric layers and components of electrode layers of an unsintered stacked body during sintering and in which both components do not easily form a liquid phase, and a production method of such a stacked ceramic body. A print portion 13 is formed on a green sheet 1, 12 containing lead by use of an electrode paste consisting of copper oxide as its main component. A desired number of print sheets 10 are stacked to give an unsintered stacked body 15. Degreasing is conducted in an atmosphere to degrease organic components. The print portion 13 is subjected to reducing treatment in a reducing atmosphere containing hydrogen and is converted to a print portion 13 containing copper as its main component. The unsintered stacked body 15 is sintered in a reducing atmosphere. Dielectric layers containing lead and electrode layers for applying a voltage to the dielectric layers are alternately stacked, and an oxidation portion containing copper is formed in the proximity of a surface of the electrode layer. A thickness of the oxidation portion in a stacking direction is 0.5 to 2 μm and a copper content in the oxidation portion is 1 to 30 wt %.