摘要:
Ceramic structures such as catalyst supports or combustion exhaust filters that incorporate combinations of high temperature phase change materials, and methods for determining the thermal history of such ceramic structures, by disposing the phase change materials on or within the structures and subsequently detecting the presence or absence of phase changes in the materials after exposure to high temperatures.
摘要:
Porous, non-microcracked cordierite ceramic bodies having high strength, high strain tolerance, and high thermal shock resistance are produced from cordierite powder batch mixtures of controlled powder particle size fired according to a schedule that prevents objectionable cordierite grain growth, maintaining a small cordierite crystalline domain size in order to minimize or prevent microcracking in the product.
摘要:
A diesel particulate filter comprising a plugged, wall-flow honeycomb filter body composed of cordierite and having a plurality of parallel end-plugged cell channels traversing the body from a frontal inlet end to an outlet end thereof, wherein the filter exhibits a CTE (25–800° C.) of less than 13×10−7/° C., a bulk filter density of less than 0.60 g/cm3, a median pore diameter, d50, of less than 25 micrometers, a porosity and pore size distribution that satisfy the relationship Pm≦3.75, wherein Pm is equal to 10.2474{1/[(d50)2(% porosity/100)]}+0.0366183(d90)−0.00040119(d90)2+0.468815(100/% porosity)2+0.0297715(d50)+1.61639(d50−d10)/d50, wherein d10, and d90 are pore diameters at 10% and 90% of the pore size distribution on a volumetric basis, and d10
摘要:
A method of protecting metal bodies, such as components of a thermal cracking furnace, against formation of carbon deposits, and the furnace components so protected, the method comprising producing an adherent, seamless coat on the metal surface, the coating comprising a layer of combined metal oxides within the MgO.Cr2O3 system.
摘要:
Porous, non-microcracked cordierite ceramic bodies having high strength, high strain tolerance, and high thermal shock resistance are produced from cordierite powder batch mixtures of controlled powder particle size fired according to a schedule that prevents objectionable cordierite grain growth, maintaining a small cordierite crystalline domain size in order to minimize or prevent microcracking in the product.
摘要:
An apparatus and method to passivate porous ceramic articles containing microcracks as described herein. The method includes circulating a fluid including a passivator through the porous ceramic article and depositing at least a portion of the passivator on the porous ceramic article.
摘要:
A diesel particulate filter comprising a plugged, wall-flow honeycomb filter body composed of cordierite and having a plurality of parallel end-plugged cell channels traversing the body from a frontal inlet end to an outlet end thereof, wherein the filter exhibits a CTE (25-800° C.) of less than 13×10−7/° C., a bulk filter density of less than 0.60 g/cm3, a median pore diameter, d50, of less than 25 micrometers, a porosity and pore size distribution that satisfy the relationship Pm≦3.75, wherein Pm is equal to 10.2474{1/[(d50)2(%porosity/100)]}+0.0366183(d90)−0.00040119(d90)2+0.468815(100/%porosity)2+0.0297715(d50)+1.61639(d50−d10)/d50, wherein d10, and d90 are pore diameters at 10% and 90% of the pore size distribution on a volumetric basis, and d10
摘要:
Porous ceramic catalyst supports or filters to be provided with catalyst coatings via oxide washcoating processes are pre-coated with cross-linked polymer barrier layers to prevent washcoat nanoparticle intrusion into the microcracked and/or microporous surfaces of the ceramics, the barrier coatings being formed by thermally cross-linking hydrocarbon polymers that are vaporizable at moderate washcoat stabilization or catalyst activation temperatures and that preferentially block the micropore/microchannel pore volume of the article.
摘要:
A method of increasing the selective desulfurization of naphtha feed streams that includes: combining a naphtha feed stream with a hydrogen containing gas to form a combined feed stream and reacting the combined feed stream over a monolithic honeycomb catalyst bed containing hydrodesulfurization catalyst components to give a desulfurized naphtha. In conducting such an illustrative embodiment, the percent desulfurization of the naphtha is preferably greater than about 50% and the percent olefin hydrogenation of the naphtha is preferably less than about 50%. The monolithic honeycomb catalyst bed of one alternative and illustrative embodiment preferably has a channel density of about 25 to 1600 cells per square inch; a channel size from about 0.1 to 10 mm; and a channel wall thickness of about 0.01 to about 2.0 mm. The illustrative method should be carried out such that the octane number (R+M/2) of the naphtha feed stream is reduced by no more than 3.0 at 95% desulfurization and preferably no more than 1.5. The hydrodesulfurization catalyst components include a powdered refractory oxide and transition metal catalyst compounds. Alternatively the hydrodesulfurization catalyst components may be impregnated into the monolithic honeycomb catalyst bed itself. Preferable hydrodesulfurization catalyst components include a Group VIII metal containing compound and a Group VIB metal containing compound. Alternatively the hydrodesulfurization catalyst components may further include a phosphorous promoter.
摘要:
Substantially non-microcracked, porous, cordierite ceramic honeycomb bodies are provided. Although exhibiting moderately high thermal expansion (CTE) between 7×10−7 to 16×10−7/° C. (25-800° C.), the honeycomb bodies exhibit relatively high thermal shock parameter (TSP), such as TSR≧525° C. by virtue of a high MOR/E ratio, and/or low Eratio=ERT/E1000° C. and well interconnected porosity, as witnessed by a relatively high pore connectivity factor (PCF). A method of manufacturing the honeycomb ceramic structure is also provided.