Monoalkylated aromatic compound production
    13.
    发明授权
    Monoalkylated aromatic compound production 有权
    单烷基化芳香族化合物生产

    公开(公告)号:US08357830B2

    公开(公告)日:2013-01-22

    申请号:US13537811

    申请日:2012-06-29

    IPC分类号: C07C2/66

    摘要: A process for producing a monoalkylated aromatic compound in an alkylation reaction zone, comprising providing upstream of said alkylation reaction zone a reactive guard bed having a catalyst of *BEA, MWW, or FAU framework structure and an alkylation feed wherein at least a portion of any reactive impurities are removed from the alkylation feed to form an effluent; and providing the effluent and a first catalytic particulate material which comprises MCM-56 and an alumina binder sized 50-60 mesh and having a ratio of surface area over volume ratio in the range of 241 to 2867 cm-1 and optionally additional alkylating agent to said alkylation reaction zone; and contacting said alkylatable aromatic compound and said alkylating agent with said catalytic particulate material in said alkylation reaction zone maintained under alkylation conditions, to form a product comprised of said monoalkylated aromatic compound.

    摘要翻译: 一种在烷基化反应区中制备单烷基化芳族化合物的方法,包括在所述烷基化反应区的上游提供具有* BEA,MWW或FAU骨架结构和烷基化进料的催化剂的反应性保护床,其中至少一部分任何 从烷基化进料中除去反应性杂质以形成流出物; 并提供流出物和第一催化颗粒材料,其包含MCM-56和尺寸为50-60目的氧化铝粘合剂,并且具有在241至2867cm -1范围内的体积比的表面积比和任选的另外的烷基化剂与 所述烷基化反应区; 以及使所述烷基化芳族化合物和所述烷基化剂与所述烷基化反应区中的所述催化颗粒材料接触,从而形成由所述单烷基化芳族化合物组成的产物。

    Molecular sieve catalyst composition, its making and use in conversion processes
    16.
    发明申请
    Molecular sieve catalyst composition, its making and use in conversion processes 有权
    分子筛催化剂组成,其制备和用途在转化过程中

    公开(公告)号:US20070249885A1

    公开(公告)日:2007-10-25

    申请号:US11818495

    申请日:2007-06-14

    IPC分类号: C07C1/00

    摘要: This invention provides methods of making molecular sieve catalyst particles, molecular sieve slurries that can be used in such methods, molecular sieve catalyst compositions and their use in catalytic hydrocarbon conversion processes. In one of its aspects, the invention provides a method of making molecular sieve catalyst particles, the method comprising the steps of: a) providing a solution or suspension of an aluminum-containing inorganic oxide precursor in a liquid medium; b) combining the solution or suspension of aluminum-containing inorganic oxide precursor with a molecular sieve, and optionally other formulating agents, to form a catalyst formulation slurry; c) aging the catalyst formulation slurry to generate in said slurry a percentage, or increase in said slurry the existing percentage, of aluminum atoms of the aluminum-containing precursor in the form of oligomers having a sharp 27Al NMR peak at 62-63 ppm; and d) forming molecular sieve catalyst particles from the catalyst formulation slurry. The catalyst compositions obtained by the methods of the present invention have improved attrition resistance, and are particularly useful in hydrocarbon conversion processes.

    摘要翻译: 本发明提供制备分子筛催化剂颗粒,可用于这些方法的分子筛浆料,分子筛催化剂组合物及其在催化烃转化方法中的应用的方法。 在其一个方面,本发明提供了制备分子筛催化剂颗粒的方法,该方法包括以下步骤:a)提供含铝无机氧化物前体在液体介质中的溶液或悬浮液; b)将含铝的无机氧化物前体的溶液或悬浮液与分子筛和任选的其它配制剂组合以形成催化剂配方浆料; c)使所述催化剂配方浆料老化以在所述浆料中产生一种百分比,或增加所述浆料中含铝前体的铝原子的现有百分比,其具有尖锐的Al 2 O 3 在62-63ppm的NMR峰; 和d)从催化剂配方浆料形成分子筛催化剂颗粒。 通过本发明的方法获得的催化剂组合物具有改善的耐磨耗性,并且在烃转化方法中特别有用。

    Monoalkylated Aromatic Compound Production
    18.
    发明申请
    Monoalkylated Aromatic Compound Production 有权
    单烷基化芳香族化合物生产

    公开(公告)号:US20130072734A1

    公开(公告)日:2013-03-21

    申请号:US13676647

    申请日:2012-11-14

    IPC分类号: C07C2/66

    摘要: A process for producing a monoalkylated aromatic compound in an alkylation reaction zone, said process comprising the steps of: (a) providing a first catalytic particulate material which comprises MCM-56 and having a ratio of surface area over surface volume ratio greater than about 79 cm−1; (b) providing said alkylation reaction zone with an alkylatable aromatic compound, an alkylating agent, and said first catalytic particulate material; and (c) contacting said alkylatable aromatic compound and said alkylating agent with said catalytic particulate material in said alkylation reaction zone maintained under alkylation conditions, to form a product comprised of said monoalkylated aromatic compound and polyalkylated aromatic compound(s).

    摘要翻译: 一种在烷基化反应区中制备单烷基化芳族化合物的方法,所述方法包括以下步骤:(a)提供包含MCM-56并具有大于约79的表面体积比的表面积比的第一催化颗粒材料 cm-1; (b)向所述烷基化反应区提供可烷基化芳族化合物,烷基化剂和所述第一催化颗粒材料; 和(c)使所述烷基化芳族化合物和所述烷基化剂与所述烷基化反应区中的所述催化颗粒材料接触,所述烷基化反应区保持在烷基化条件下,以形成由所述单烷基化芳族化合物和多烷基化芳族化合物组成的产物。