Recovery of lithium from brines
    12.
    发明授权
    Recovery of lithium from brines 失效
    从盐水中回收锂

    公开(公告)号:US4116858A

    公开(公告)日:1978-09-26

    申请号:US812543

    申请日:1977-07-05

    CPC classification number: C01D15/00 B01J47/006 C01D3/145 C01F7/002

    Abstract: Lithium is preferentially extracted from brine containing Li salts along with salts of other metals, e.g. Na, Ca, Mg, K, and/or B, by contacting the brine with a particulate anion exchange resin having suspended therein a microcrystalline form of LiX.2Al(OH).sub.3, where X = halide.

    Abstract translation: 锂优先从含有Li盐的盐水以及其他金属的盐,例如, Na,Ca,Mg,K和/或B,通过使盐水与其中悬浮有微晶形式的LiX.2Al(OH)3的颗粒状阴离子交换树脂接触,其中X =卤化物。

    MAGNETIC RESIN SEPARATOR
    13.
    发明申请
    MAGNETIC RESIN SEPARATOR 有权
    磁性树脂分离器

    公开(公告)号:US20130056421A1

    公开(公告)日:2013-03-07

    申请号:US13648981

    申请日:2012-10-10

    Abstract: The invention provides a system and process for separating residual magnetic resin from a liquid stream by passing the stream through or over permanent magnets located within the stream wherein the process also includes a means for releasing any resin retained by the permanent magnets and capturing the released resin.

    Abstract translation: 本发明提供了一种用于通过使物流通过位于流内的永久磁体或将其从液态物流中分离出的残余磁性树脂的系统和方法,其中该方法还包括用于释放由永磁体保留的任何树脂并捕获释放的树脂 。

    Ion-exchange composition employing resin attachment to dispersant and
method for forming the same
    15.
    发明授权
    Ion-exchange composition employing resin attachment to dispersant and method for forming the same 失效
    使用树脂附着于分散剂的离子交换组合物及其形成方法

    公开(公告)号:US5532279A

    公开(公告)日:1996-07-02

    申请号:US221752

    申请日:1994-04-01

    Abstract: In accordance with the present invention, an ion-exchange composition has been formed which comprises synthetic resin support particles, dispersant capable of suspending the support particles in an aqueous medium to inhibit or prevent agglomeration, and fine synthetic resin layering particles. In a preferred embodiment, the complex can be formed by contacting a suitable dispersant with monomer in an aqueous solution in which the monomer is insoluble. Under suitable conditions for suspension polymerization, the monomer will polymerize to form resin support particles having dispersant irreversibly attached to those particles. The dispersant is irreversibly attached to the synthetic resin support particles, either by covalent bonding or permanent physical entanglement. The dispersant is also attached to the fine layering particles, either by covalent bonding or electrostatic forces. The result is formation of a support particle-dispersant-layering particle complex.The novel ion-exchange composition can be made by forming a synthetic resin support particle-dispersant complex in which the dispersant is irreversibly attached to the support particles. The complex can then be mixed in aqueous slurry form with fine resin layering particles under conditions suitable to form a resin support particle-dispersant-resin layering particle complex in which the resin layering particles are irreversibly attached to the dispersant. In effect, the dispersant forms an irreversible bridge between the support and layering particles.

    Abstract translation: 根据本发明,已经形成了一种离子交换组合物,其包括合成树脂载体颗粒,能够将载体颗粒悬浮在水性介质中以抑制或防止附聚的分散剂和细小的合成树脂层压颗粒。 在优选的实施方案中,络合物可以通过使合适的分散剂与单体在单体不溶的水溶液中接触来形成。 在合适的悬浮聚合条件下,单体将聚合形成具有分散剂不可逆地连接到这些颗粒上的树脂载体颗粒。 分散剂通过共价键或永久性物理缠结不可逆地附着在合成树脂载体颗粒上。 分散剂也通过共价键或静电力连接到细分层颗粒上。 结果是形成载体颗粒 - 分散剂分层颗粒复合物。 新型离子交换组合物可以通过形成其中分散剂不可逆地附着到载体颗粒上的合成树脂载体颗粒 - 分散剂络合物来制备。 然后可以在适于形成树脂分层树脂分层颗粒复合物的条件下,将复合物以水性浆液形式与细树脂分层颗粒混合,其中树脂分层颗粒不可逆地附着到分散剂上。 实际上,分散剂在载体和分层颗粒之间形成不可逆的桥。

    Process for insolubilizing absorbed metal ions
    16.
    发明授权
    Process for insolubilizing absorbed metal ions 失效
    不溶解吸收金属离子的方法

    公开(公告)号:US5336704A

    公开(公告)日:1994-08-09

    申请号:US17598

    申请日:1993-02-16

    Inventor: Norman B. Rainer

    Abstract: Metal cations absorbed within a hydrogel chelation polymer are insolubilized for safe disposal by treating the polymer with a precipitative anion such as carbonate, aluminate, hydroxide, phosphate, silicate, or sulfide. Further insolubilization of the metal cations may be achieved by subsequent treatment of the polymer with a water-dilutable prepolymer composition such as phenol-formaldehyde resin, then heating to cause cross-linking of the prepolymer. The hydrogel chelation polymer, containing metal sulfide formed by virtue of the insolubilization process, is useful in abstracting from water metals whose sulfides are less soluble than the metal sulfide initially within the polymer.

    Abstract translation: 通过用沉淀阴离子例如碳酸盐,铝酸盐,氢氧化物,磷酸盐,硅酸盐或硫化物处理聚合物,在水凝胶螯合聚合物内吸收的金属阳离子不溶解以便安全处理。 金属阳离子的进一步不溶化可以通过用水可稀释的预聚物组合物如苯酚 - 甲醛树脂随后处理聚合物,然后加热以引起预聚物的交联来实现。 含有由于不溶化过程形成的金属硫化物的水凝胶螯合聚合物可用于从最初在聚合物内的金属硫化物的硫化物溶解度较低的水金属中提取。

    Liquid membrane coated ion-exchange column solids
    17.
    发明授权
    Liquid membrane coated ion-exchange column solids 失效
    液膜包被的离子交换柱固体

    公开(公告)号:US4886598A

    公开(公告)日:1989-12-12

    申请号:US164659

    申请日:1988-03-07

    Applicant: Dale P. Barkey

    Inventor: Dale P. Barkey

    Abstract: This invention relates to a method for improving the performance of liquidembrane separations by coating a liquid membrane onto solid ion-exchange resin beads in a fixed bed. Ion-exchange beads fabricated from an ion-exchange resin are swelled with water and are coated with a liquid membrane material that forms a film over the beads. The beads constitute a fixed bed ion-exchange column. Fluid being treated that contains the desired ion to be trapped by the ion-exchange particle is passed through the column. A carrier molecule, contained in the liquid membrane ion-exchange material, is selected for the desired ion in the fluid. The carrier molecule forms a complex with the desired ion, transporting it through the membrane and thus separating it from the other ions. The solution is fed continuously until breakthrough occurs at which time the ion is recovered, and the bed is regenerated.

    Abstract translation: 本发明涉及通过将液膜涂布在固定床上的固体离子交换树脂珠上来提高液膜分离性能的方法。 由离子交换树脂制成的离子交换珠被水膨胀,并用在珠上形成膜的液体膜材料涂覆。 珠子构成固定床离子交换柱。 含有待被离子交换颗粒捕获的所需离子的待处理流体通过柱。 包含在液膜离子交换材料中的载体分子被选择用于流体中所需的离子。 载体分子与所需的离子形成络合物,将其输送通过膜,从而将其与其它离子分离。 连续供给溶液,直到发生突破,此时离子被回收,床被再生。

    Liquid membrane coated ion-exchange column solids
    18.
    发明授权
    Liquid membrane coated ion-exchange column solids 失效
    液膜包被的离子交换柱固体

    公开(公告)号:US4747949A

    公开(公告)日:1988-05-31

    申请号:US922426

    申请日:1986-10-23

    Applicant: Dale P. Barkey

    Inventor: Dale P. Barkey

    Abstract: This invention relates to a method for improving the performance of liquid membrane separations by coating a liquid membrane onto solid ion-exchange resin beads in a fixed bed. Ion-exchange beads fabricated from an ion-exchange resin are swelled with water and are coated with a liquid membrane material that forms a film over the beads. The beads constitute a fixed bed ion-exchange column. Fluid being treated that contains the desired ion to be trapped by the ion-exchange particle is passed through the column. A carrier molecule, contained in the liquid membrane ion-exchange material, is selective for the desired ion in the fluid. The carrier molecule forms a complex with the desired ion, transporting it through the membrane and thus separating it from the other ions. The solution is fed continuously until breakthrough occurs at which time the ion is recovered, and the bed is regenerated.

    Abstract translation: 本发明涉及通过将液膜涂布在固定床上的固体离子交换树脂珠上来提高液膜分离性能的方法。 由离子交换树脂制成的离子交换珠被水膨胀,并用在珠上形成膜的液体膜材料涂覆。 珠子构成固定床离子交换柱。 含有待被离子交换颗粒捕获的所需离子的待处理流体通过柱。 包含在液膜离子交换材料中的载体分子对流体中所需的离子是选择性的。 载体分子与所需的离子形成络合物,将其输送通过膜,从而将其与其它离子分离。 连续供给溶液,直到发生突破,此时离子被回收,床被再生。

    Production of powdered resin and the powdered resin so produced
    19.
    发明授权
    Production of powdered resin and the powdered resin so produced 失效
    生产粉末状树脂和如此生产的粉状树脂

    公开(公告)号:US4404346A

    公开(公告)日:1983-09-13

    申请号:US176732

    申请日:1980-08-05

    CPC classification number: B01J47/006 C08J3/12 C08J2327/04

    Abstract: Powdered synthetic polymeric resin is produced by swelling or shrinking resin particles by contact with water or an organic solvent to introduce strain within the particles and comminuting the swollen or shrunk particles by grinding them in a rotary attrition mill. This process is particularly useful for the production of powdered resins for oral consumption, for example powdered cholestyramine resin, since particle sizes such that 90% by weight and/or number is below 30 microns in average particle diameter in the wet swollen state may be achieved.

    Abstract translation: 粉碎的合成聚合物树脂通过与水或有机溶剂接触而使树脂颗粒膨胀或收缩来在颗粒内引入应变,并通过在旋转磨耗机中研磨它们来粉碎膨胀或收缩的颗粒。 该方法对于生产用于口服消费的粉末状树脂,例如粉状考来烯胺树脂是特别有用的,因为可以实现在湿膨胀状态下平均粒径为90重量%和/或数量小于30微米的粒径 。

    Magnesium aluminate anion exchangers
    20.
    发明授权
    Magnesium aluminate anion exchangers 失效
    铝酸镁阴离子交换剂

    公开(公告)号:US4326961A

    公开(公告)日:1982-04-27

    申请号:US183907

    申请日:1980-09-04

    Abstract: Preparations and uses are shown for novel crystalline aluminates which conform generally to the empirical formulaMgA.sub.a.sup.V Z.sub.b.sup.v .multidot.nAl(OH).sub.3 .multidot.mH.sub.2 OwhereA and Z represent negative-valence ions or radicals selected from the group comprising hydroxyl, halide, inorganic acid, and organic acid,n is a value of from about 1 to about 2,v is a negative valence of 1, 2, or 3,a and b each have values of from zero to 2, with (va)+(vb) equal to 2, and with m being a value of zero or more.

    Abstract translation: 显示了新型结晶铝酸盐的制备和用途,其通常符合经验式MgAaVZbvxnAl(OH)3·xH2O,其中A和Z表示负价离子或选自羟基,卤化物,无机酸和有机酸的基团,n为 值为约1至约2,v为1,2或3的负数,a和b各自具有0至2的值,其中(va)+(vb)等于2,并且与m 值为零或以上。

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