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    Method For Preparation Of 1- Alkene-Acrylate Based Copolymers
    11.
    发明申请
    Method For Preparation Of 1- Alkene-Acrylate Based Copolymers 有权
    1-烯烃 - 丙烯酸酯共聚物的制备方法

    公开(公告)号：US20100113723A1

    公开(公告)日：2010-05-06

    申请号：US12225174

    申请日：2007-03-13

    申请人： Yoo-Young Jung ,  Byoung-ho Jeon ,  Bae-kun Shin ,  Ki-soo Lee ,  Yong-gyu Han

    发明人： Yoo-Young Jung ,  Byoung-ho Jeon ,  Bae-kun Shin ,  Ki-soo Lee ,  Yong-gyu Han

    IPC分类号： C08F4/06 ,  C08F4/12

    CPC分类号： C08F222/10 ,  C08F210/02 ,  C08F220/12 ,  C08F220/14 ,  C08F220/18 ,  C08F210/14

    摘要： The present invention provides a method for preparation of an 1-alkene-acrylate based copolymer comprising a step of a radical polymerization reaction of 1-alkene and acrylate based monomer under presence of a metal oxide or Lewis acid, and a method for preparation of an alkene-acrylate based copolymer comprising reacting alkene with an acrylate based monomer under presence of a metal oxide. In the method of preparation according to the present invention, the process is simple and properties of the copolymer can be easily controlled by preparing the copolymer in a mild condition of 100° C. or less and 200 bar or less. In addition, the amount of the polar group of the copolymer prepared by the method is so high that the copolymer can be used for transparent optical products. Since the alkene-acrylate based copolymer prepared by the method is a random copolymer of ethylene and a polar monomer and the amount of the polar group of the polar monomer so high that the crystallinity of the ethylene monomer does not remain in the copolymer, the ethylene-acrylate based copolymer is not affected from a transparency of the polymer and thus may be used for optical products.

    摘要翻译： 本发明提供一种制备1-烯烃 - 丙烯酸酯基共聚物的方法，其包括在金属氧化物或路易斯酸存在下，1-烯烃和丙烯酸酯类单体的自由基聚合反应的步骤，以及制备 烯烃 - 丙烯酸酯基共聚物，其包含在金属氧化物的存在下使烯烃与丙烯酸酯基单体反应。 在根据本发明的制备方法中，该方法简单，并且通过在100℃以下且200巴以下的温和条件下制备共聚物可以容易地控制共聚物的性质。 此外，通过该方法制备的共聚物的极性基团的量非常高，使得该共聚物可用于透明光学产品。 由于通过该方法制备的基于烯烃 - 丙烯酸酯的共聚物是乙烯和极性单体的无规共聚物和极性单体的极性基团的量如此高以至于乙烯单体的结晶度不会残留在共聚物中，所以乙烯 丙烯酸酯类共聚物不受聚合物的透明性的影响，因此可以用于光学产品。

    Catalyst Component for Ethylene Polymerization, Preparation Thereof and Catalyst Comprising the Same
    12.
    发明申请
    Catalyst Component for Ethylene Polymerization, Preparation Thereof and Catalyst Comprising the Same 审中-公开
    用于乙烯聚合的催化剂组分，其制备方法和包含其的催化剂

    公开(公告)号：US20090318643A1

    公开(公告)日：2009-12-24

    申请号：US12084258

    申请日：2006-10-31

    申请人： Wei Chen ,  Zifang Guo ,  Junling Zhou ,  Hongtao Wang ,  Hongxu Yang ,  Ruixia Li ,  Ruiping Wang

    发明人： Wei Chen ,  Zifang Guo ,  Junling Zhou ,  Hongtao Wang ,  Hongxu Yang ,  Ruixia Li ,  Ruiping Wang

    IPC分类号： C08F4/12 ,  B01J31/12

    CPC分类号： C08F10/02 ,  B01J31/128 ,  C08F10/00 ,  C08F110/02 ,  C08F4/6586 ,  C08F4/6567 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F4/6565

    摘要： The present invention relates to a catalyst component for ethylene polymerization, which comprises a reaction product of a magnesium complex, at least one titanium compound, at least one alcohol compound, at least one silicon compound, and optionally an organic aluminum compound. The silicon compound is an organic silicon compound having a general formula R1xR2ySi(OR3)z, in which R1 and R2 are independently a hydrocarbyl or a halogen, R3 is a hydrocarbyl, 0≦x≦2, 0≦y≦2, 0≦z≦4, and x+y+z=4. The present invention further relates to a method for the preparation of the catalyst component and to a catalyst comprising the same. The catalysts according to the invention have virtues such as high catalytic activity, good hydrogen response, and narrow particle size distribution of polymer, and are especially suitable for a slurry process of ethylene polymerization and a combined process of ethylene polymerization, which requires a high activity of catalyst.

    摘要翻译： 本发明涉及一种用于乙烯聚合的催化剂组分，其包括镁络合物，至少一种钛化合物，至少一种醇化合物，至少一种硅化合物和任选的有机铝化合物的反应产物。 硅化合物是具有通式R1xR2ySi（OR3）z的有机硅化合物，其中R 1和R 2独立地是烃基或卤素，R 3是烃基，0 <= x <= 2,0 <= y < 2，0 <= z <= 4，x + y + z = 4。 本发明还涉及制备催化剂组分的方法和包含该催化剂组分的催化剂。 根据本发明的催化剂具有诸如高催化活性，良好的氢响应和聚合物的窄粒度分布等优点，并且特别适用于乙烯聚合和乙烯聚合的组合方法的浆料方法，其需要高活性 的催化剂。

    Dental adhesive composition
    14.
    发明授权
    Dental adhesive composition 有权
    牙科粘合剂组成

    公开(公告)号：US07504443B2

    公开(公告)日：2009-03-17

    申请号：US10523027

    申请日：2003-09-30

    申请人： Weiping Zeng ,  Akari Shimozono

    发明人： Weiping Zeng ,  Akari Shimozono

    IPC分类号： A61K6/08 ,  A61K6/083 ,  A61K6/00 ,  C08F4/12 ,  C08F4/52 ,  C07F5/02 ,  A61C5/00

    CPC分类号： A61K6/083 ,  A61K6/0023 ,  C08L33/04

    摘要： The dental adhesive composition of the present invention comprises a polyfunctional polymerizable monomer which is an ester compound of a polyhydric alcohol of 3 to 6 carbon atoms and plural (meth)acrylic acids and has 1 to 2 hydroxyl groups, a monofunctional (meth)acrylate having no hydroxyl group in its molecule, a polymerizable monomer containing an acid group in its molecule, an organoboron compound as a curing agent and a filler. According to the present invention, a dental adhesive composition remarkably enhanced in the curing rate with rarely affecting adhesion properties of the composition, working time and flexibility of a cured product is provided.

    摘要翻译： 本发明的牙科用粘合剂组合物包含多官能性聚合性单体，其为3〜6个碳原子的多元醇和多个（甲基）丙烯酸的酯化合物，具有1〜2个羟基，单官能（甲基）丙烯酸酯具有 其分子中没有羟基，在其分子中含有酸基的可聚合单体，作为固化剂的有机硼化合物和填料。 根据本发明，提供了一种显着提高固化速度的牙科粘合剂组合物，很少影响组合物的粘合性能，加工时间和固化产物的柔软性。

    Process for Polymerizaing 1-Hexene or Higher Alpha-Olefins
    16.
    发明申请
    Process for Polymerizaing 1-Hexene or Higher Alpha-Olefins 失效
    聚合1-己烯或更高级α-烯烃的方法

    公开(公告)号：US20080281061A1

    公开(公告)日：2008-11-13

    申请号：US10592564

    申请日：2005-03-08

    申请人： Luigi Resconi ,  Eleonora Ciaccia ,  Friederike Morhard ,  Giampaolo Pellegatti

    发明人： Luigi Resconi ,  Eleonora Ciaccia ,  Friederike Morhard ,  Giampaolo Pellegatti

    IPC分类号： C08F4/72 ,  C08F4/12 ,  C08F210/08

    CPC分类号： C08F210/14 ,  C08F4/65912 ,  Y10S526/943 ,  C08F4/65927 ,  C08F210/06 ,  C08F2500/17 ,  C08F2500/03 ,  C08F210/08

    摘要： A process for preparing a polymer containing derived units of one or more alpha olefins of formula CH2═CHW wherein W is a C3-C10 hydrocarbon radical and optionally from 0 to 81% by mol of derived units of propylene or 1-butene, comprising contacting under polymerization conditions one or more alpha olefins of formula CH2═CHW and optionally propylene or 1-butene in the presence of a catalyst system obtainable by contacting:a) a metallocene compound of formula (I) wherein M, X, L, T, R1, R7, R2 and R8 are described in the text; and(b) an alumoxane or a compound capable of forming an alkyl metallocene cation.

    摘要翻译： 一种制备含有一种或多种式CH 2 -CH 2的α-烯烃的衍生单元的聚合物的方法，其中W是C 3 -C 10 丙烯或1-丁烯的衍生单元的0至81摩尔％，包括在聚合条件下接触一种或多种式CH 2 -CH 2的α-烯烃和任选的丙烯或1 其中M，X，L，T，R 1，R 7，R 2，R 2，R 3，R 3， / SUP>和R＆gt; 8在文中描述; 和（b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

    Process For Polymerizaing 1-Hexene or Higher Alpha-Olefins
    17.
    发明申请
    Process For Polymerizaing 1-Hexene or Higher Alpha-Olefins 失效
    聚合1-己烯或更高级α-烯烃的方法

    公开(公告)号：US20080281060A1

    公开(公告)日：2008-11-13

    申请号：US10592563

    申请日：2005-03-08

    申请人： Luigi Resconi ,  Eleonora Ciaccia ,  Friederike Morhard ,  Giampaolo Pellegatti

    发明人： Luigi Resconi ,  Eleonora Ciaccia ,  Friederike Morhard ,  Giampaolo Pellegatti

    IPC分类号： C08F4/12 ,  C08F4/72 ,  C08F210/08

    CPC分类号： C08F210/14 ,  C08F4/65912 ,  Y10S526/943 ,  C08F4/65927 ,  C08F210/08 ,  C08F2500/17 ,  C08F2500/03 ,  C08F210/06

    摘要： A process for preparing a polymer containing derived units of one or more alpha olefins of formula CH2═CHW wherein W is a C3-C10 hydrocarbon radical and optionally from 0 to 81% by mol of derived units of propylene or 1-butene, comprising contacting under polymerization conditions one or more alpha olefins of formula CH2═CHW and optionally propylene or 1-butene in the presence of a catalyst system obtainable by contacting: a) a metallocene compound of formula (I)  wherein M, X, L, T1, T2, T3 and R1 are described in the text; and (b) an alumoxane or a compound capable of forming an alkyl metallocene cation.

    摘要翻译： 一种制备含有一种或多种式CH 2 -CH 2的α-烯烃的衍生单元的聚合物的方法，其中W是C 3 -C 10 丙烯或1-丁烯的衍生单元的0至81摩尔％，包括在聚合条件下接触一种或多种式CH 2 -CH 2的α-烯烃和任选的丙烯或1 在一种催化剂体系存在下，该催化剂体系可以通过以下方式获得：a）其中M，X，L，T 1，T 2，O 2的式（I）的茂金属化合物， 本文中描述了T 3和R 1; 和（b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

    METHOD FOR PRODUCING FUNCTIONALIZED CIS-1,4-POLYDIENES HAVING HIGH CIS-1,4-LINKAGE CONTENT AND HIGH FUNCTIONALITY
    18.
    发明申请
    METHOD FOR PRODUCING FUNCTIONALIZED CIS-1,4-POLYDIENES HAVING HIGH CIS-1,4-LINKAGE CONTENT AND HIGH FUNCTIONALITY 有权
    生产具有高CIS-1,4链接内容和高功能性的官能化CIS-1,4-聚异戊二烯的方法

    公开(公告)号：US20080182954A1

    公开(公告)日：2008-07-31

    申请号：US11964848

    申请日：2007-12-27

    申请人： Steven Luo ,  Junko Kurazumi ,  Yoichi Ozawa ,  Timothy L. Tartamella ,  Mark Smale

    发明人： Steven Luo ,  Junko Kurazumi ,  Yoichi Ozawa ,  Timothy L. Tartamella ,  Mark Smale

    IPC分类号： C08F36/08 ,  C08F4/12

    CPC分类号： C08C19/44 ,  B60C1/00 ,  B60C1/0016 ,  B60C1/0025 ,  C08L15/00 ,  Y10S525/902 ,  Y10T152/10495

    摘要： This invention relates to a method for producing functionalized cis-1,4-polydienes having a combination of a high cis-1,4-linkage content and a high functionality, the resulting polymers and the vulcanized products containing the polymers. The functionalized cis-1,4-polydienes of the present invention are produced by a method comprising the steps of: (1) preparing a reactive polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst in the presence of less than 20% by weight of organic solvent based on the total weight of monomer, organic solvent, and resulting polymer, where the lanthanide-based catalyst is the combination of or reaction product of (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a halogen-containing compound; and (2) contacting the reactive polymer with a functionalizing agent.

    摘要翻译： 本发明涉及具有高顺式-1,4-键含量和高官能度组合的官能化顺式-1,4-聚二烯的方法，所得聚合物和含有聚合物的硫化产物。 本发明的官能化顺式-1,4-聚二烯通过包括以下步骤的方法制备：（1）通过将共轭二烯单体与镧系元素基催化剂在少于20％ 基于单体，有机溶剂和所得聚合物的总重量的有机溶剂的重量，其中镧系元素基催化剂是（a）镧系元素化合物，（b）铝氧烷，（c） 除铝氧烷以外的有机铝化合物，和（d）含卤素化合物; 和（2）使反应性聚合物与官能化剂接触。