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    High solids polyurethane binder compositions containing grafted polyacrylate polyols
    13.
    发明授权
    High solids polyurethane binder compositions containing grafted polyacrylate polyols 失效
    含有接枝聚丙烯酸酯多元醇的高固含量聚氨酯粘合剂组合物

    公开(公告)号：US5969054A

    公开(公告)日：1999-10-19

    申请号：US888520

    申请日：1997-07-07

    申请人： Christian Wamprecht ,  Michael Sonntag ,  Dieter Margotte

    发明人： Christian Wamprecht ,  Michael Sonntag ,  Dieter Margotte

    IPC分类号： C08L51/04 ,  C08F279/02 ,  C08G18/63 ,  C09D151/04 ,  C08F8/26 ,  C08F8/30 ,  C08F220/32 ,  C08G18/62

    CPC分类号： C08G18/633 ,  C08F279/02 ,  C09D151/04

    摘要： The present invention relates to binder compositions containingA) 40 to 95 parts by weight of OH-functional graft copolymer resins prepared by copolymerizinga) 0.1 to 10 parts by weight of polybutadienes containing at least 20% of 1,2-vinyl groups,b) 5 to 30 parts by weight of aliphatic .alpha.-olefins,c) 0.1 to 35 parts by weight of glycidyl esters of .alpha.-alkylalkane-monocarboxylic acids,d) 10 to 70 parts by weight of unsaturated, aromatic monomers,e) 5 to 60 parts by weight of hydroxyalkyl esters of acrylic and/or methacrylic acid having primary hydroxyl groups,f) 0 to 50 parts by weight of (cyclo)aliphatic esters of acrylic and/or methacrylic acid,g) 0.1 to 20 parts by weight of .alpha.,.beta.-mono-olefinically unsaturated monocarboxylic or dicarboxylic acids and/or maleic acid or fumaric acid semi-esters andh) 0 to 30 parts by weight of other copolymerizable compounds andB) 5 to 60 parts by weight of polyfunctional crosslinking resins,wherein 1 to 30% by weight of the OH groups of the component A) are secondary OH groups. The present invention also relates to the use of these binder compositions for vehicle coatings, in particular automotive refinish coatings and large vehicle coatings, for wood and furniture coatings, general industrial coatings, and for coatings that provide corrosion protection.

    摘要翻译： 本发明涉及粘合剂组合物，其含有A）40〜95重量份的OH-官能接枝共聚物树脂，其通过以下方法制备：a）将0.1至10重量份含有至少20％的1,2-乙烯基的聚丁二烯，b ）5〜30重量份脂肪族α-烯烃，c）0.1〜35重量份的α-烷基烷烃 - 一元羧酸的缩水甘油酯，d）10〜70重量份的不饱和芳族单体，e）5〜 60重量份具有伯羟基的丙烯酸和/或甲基丙烯酸的羟烷基酯，f）0至50重量份的丙烯酸和/或甲基丙烯酸的（环）脂族酯，g）0.1至20重量份的 α，β-单烯属不饱和单羧酸或二羧酸和/或马来酸或富马酸半酯，和h）0至30重量份的其它可共聚的化合物和B）5至60重量份的多官能交联树脂， 其中1〜30重量％的O 组分A）的H基团是仲OH基团。 本发明还涉及这些粘合剂组合物用于车辆涂料，特别是汽车修补涂料和大型车辆涂料，用于木材和家具涂料，一般工业涂料以及提供防腐蚀涂料的用途。

    Coating resin composition based on a graft copolymerized resin and method of producing the same
    14.
    发明授权
    Coating resin composition based on a graft copolymerized resin and method of producing the same 失效
    基于接枝共聚树脂的涂料树脂组合物及其制备方法

    公开(公告)号：US5811489A

    公开(公告)日：1998-09-22

    申请号：US615174

    申请日：1996-04-02

    申请人： Takayuki Shirai ,  Takaaki Ueda ,  Keiji Urata

    发明人： Takayuki Shirai ,  Takaaki Ueda ,  Keiji Urata

    IPC分类号： C08G18/62 ,  C08G18/63 ,  C09D151/04 ,  C09D151/06 ,  C08L51/06

    CPC分类号： C08G18/6275 ,  C08G18/633 ,  C09D151/04 ,  C09D151/06

    摘要： A coating resin composition, comprising a graft copolymerized resin prepared by graft polymerizing a monomer containing ethylenic unsaturated bond and a monomer containing an ethylenic unsaturated bond and a hydroxyl group, wherein the hydroxyl group content of the monomer is such that the hydroxyl group content of the graft copolymerized resin is 0.1 to 5 wt. %, onto a mixed resin of (i) a carboxyl group containing chlorinated polyolefin resin containing from 1 to 10 wt. % of .alpha.,.beta.-unsaturated carboxylic acid (anhydride) and having a chlorine content of 5 to 50 wt. %, the resin (i) being prepared by a graft polymerizing .alpha.,.beta.-unsaturated carboxylic acid (anhydride) onto a polyolefin followed by chlorination, and (ii) an oxidized chlorinated polyolefin resin containing from 5 to 50 wt. % chlorine and having a functional group index of at least 1, prepared by oxidizing and chlorinating a polyolefin, wherein the oxidizing agent for the oxidation is at least one member selected from the group consisting of air, oxygen and ozone, the weight percent ratio of resin (i) to resin (ii) ranging from 5:95 to 95:5 and wherein the mixed resins (i) and (ii) constitute from 5 to 90 wt. % of the components of the composition; and an isocyanate or alkyl-etherified amino resin as a curing agent.

    摘要翻译： PCT No.PCT / JP95 / 01483第 371日期：1996年4月2日 102（e）日期1996年4月2日PCT提交1995年7月26日PCT公布。 出版物WO96 / 04344 日期1996年2月15日一种涂料树脂组合物，其包含通过接枝聚合含有烯属不饱和键的单体和含有烯属不饱和键和羟基的单体制备的接枝共聚树脂，其中单体的羟基含量使得 接枝共聚树脂的羟基含量为0.1〜5wt。 ％的混合树脂，（i）含有1〜10重量％的氯化聚烯烃树脂的羧基的混合树脂。 ％的α，β-不饱和羧酸（酸酐），氯含量为5〜50wt。 ％，树脂（i）通过将α，β-不饱和羧酸（酸酐）接枝聚合到聚烯烃上然后氯化制备，和（ii）含有5-50wt。％的氧化的氯化聚烯烃树脂。 通过氧化和氯化聚烯烃制备的具有至少1个官能团指数的氯，其中用于氧化的氧化剂是选自空气，氧气和臭氧中的至少一种，重量百分比 树脂（i）至树脂（ⅱ）的范围为5:95至95:5，其中混合树脂（ⅰ）和（ⅱ）占5至90wt。 ％组分的组分; 和作为固化剂的异氰酸酯或烷基醚化氨基树脂。

    High solids binder compositions containing OH-functional polyacrylate graft copolymers
    15.
    发明授权
    High solids binder compositions containing OH-functional polyacrylate graft copolymers 失效
    含有OH-官能的聚丙烯酸酯接枝共聚物的高固体粘合剂组合物

    公开(公告)号：US5733973A

    公开(公告)日：1998-03-31

    申请号：US755878

    申请日：1996-12-02

    申请人： Christian Wamprecht ,  Michael Sonntag ,  Jurgen Schwindt ,  Dieter Margotte

    发明人： Christian Wamprecht ,  Michael Sonntag ,  Jurgen Schwindt ,  Dieter Margotte

    IPC分类号： C08F290/04 ,  C08F279/02 ,  C08L51/04 ,  C09D151/00 ,  C09D151/04 ,  C09D155/00 ,  C09D161/04 ,  C09D161/06 ,  C09D161/20 ,  C09D175/00 ,  C09D175/04 ,  C08G63/48

    CPC分类号： C08F279/02 ,  C08L51/04

    摘要： The present invention relates to binder compositions containing A) 40 to 95 parts by weight of OH-functional graft copolymer resins which are prepared by copolymerizing a mixture containing 0.1 to 10 parts by weight of at least one optionally functional polybutadiene having a molecular weight of 500 to 10,000 and having at least 20% by weight of side-chain 1,2-vinyl double bonds, and B) 5 to 60 parts by weight of a polyfunctional cross-linking resin selected from aminoplast resins and optionally blocked polyisocyanates, wherein the sum of the parts by weight of components A) and B) add up to 100, based on the weight of components A) and B). The present invention also relates to the use of the binder compositions according to the invention for lacquering vehicles, wood and furniture, and for preventing corrosion.

    摘要翻译： 本发明涉及粘合剂组合物，其包含A）40至95重量份的OH-官能的接枝共聚物树脂，其通过将含有0.1至10重量份的至少一种分子量为500的任意官能的聚丁二烯 至10,000重量％，并且具有至少20重量％的侧链1,2-乙烯基双键，和B）5至60重量份选自氨基塑料树脂和任选的封端多异氰酸酯的多官能交联树脂，其中总和 的组分A）和B）的重量份，基于组分A）和B）的重量加起来为100。 本发明还涉及根据本发明的粘合剂组合物用于涂漆车辆，木材和家具以及用于防止腐蚀的用途。

    Water-dilutable air-drying binders, a process for producing them and their use in air-drying binders
    16.
    发明授权
    Water-dilutable air-drying binders, a process for producing them and their use in air-drying binders 失效
    水可稀释的空气干燥粘合剂，其制备方法及其在空气干燥粘合剂中的用途

    公开(公告)号：US5322909A

    公开(公告)日：1994-06-21

    申请号：US949307

    申请日：1992-09-22

    申请人： Franz-Josef Rankl ,  Aurel Blaga ,  Heinrich Stolzenbach ,  Hans-Peter Patzschke ,  Siegfried Kowalzick ,  Franjo Gol

    发明人： Franz-Josef Rankl ,  Aurel Blaga ,  Heinrich Stolzenbach ,  Hans-Peter Patzschke ,  Siegfried Kowalzick ,  Franjo Gol

    IPC分类号： C09D151/04 ,  C08C19/22 ,  C08C19/28 ,  C08F279/02 ,  C09D151/00 ,  C08F8/46 ,  C08F8/30

    CPC分类号： C08C19/28 ,  C08C19/22 ,  C08F279/02

    摘要： A binder, neutralizable with bases, for producing siccativated aqueous coating agents, based on a polydiene resin partially crosslinked with bis(2-oxazoline), with an acid number of 50 to 100, that is obtainable by anhydrous reaction ofA. 40 to 80 wt % of one or several polydiene oils with a weight-average molecular weight of 300 to 5000,B. 5 to 25 wt % of one or several .alpha.,.beta.-ethylenically unsaturated carboxylic acids,C. 1 to 10 wt % of one or several bis(2-oxazoline)s andD. 0 to 20 wt % of one or several physically curing resins and/or ethylenically unsaturated monomers,transfer into an aqueous medium and reaction withE. 1 to 40 wt % of one or several ethylenically unsaturated monomers in presence of an oil-soluble, free-radical-forming polymerization initiator and optionally a polymerization regulator,wherein each of the above percentages by weight relates to the sum of components A, B, C, D, and E. A process for production of the binder and its use in aqueous coating agents.

    摘要翻译： 基于用双重（2-恶唑啉）部分交联的聚二烯树脂制备酸洗水性涂料的粘合剂，其酸值为50至100，可通过A.40至80的无水反应获得 重量百分比的一种或多种重均分子量为300-5000的聚二烯烃油，B.5-25％重量的一种或几种α，β-烯键式不饱和羧酸，C 1至10重量％的一种或多种 几种双（2-恶唑啉）和D.0至20重量％的一种或几种物理固化树脂和/或烯键式不饱和单体，转移到水性介质中并与E.1至40重量％的一种或多种烯键式 在油溶性形成自由基的聚合引发剂和任选的聚合调节剂存在下的不饱和单体，其中上述重量百分比中的每一种与组分A，B，C，D和E的总和相关。一种方法 用于生产粘合剂及其在水性涂料中的应用 代理商

    Water-based paint composition
    18.
    发明授权
    Water-based paint composition 失效
    水性油漆组成

    公开(公告)号：US4692483A

    公开(公告)日：1987-09-08

    申请号：US855644

    申请日：1986-04-25

    申请人： Yasuyuki Tsuchiya ,  Hiroyuki Sakamoto

    发明人： Yasuyuki Tsuchiya ,  Hiroyuki Sakamoto

    IPC分类号： C09D151/04 ,  C09D191/00 ,  C08K3/20 ,  C08L37/00 ,  C08L83/00

    CPC分类号： C09D191/005 ,  C09D151/04

    摘要： A water-based paint composition comprising:(A) a reaction product prepared by reacting a butadiene-based polymer and/or a drying oil with an .alpha.,.beta.-unsaturated dicarboxylic acid anhydride followed by reacting with water, a primary monoalcohol or a dialkylamine; and(B) a modified epoxy resin with acrylic acid, methacrylic acid or unsaturated fatty acid, or a modified phenol resin with glycidyl acrylate or methacrylate, components (A) and(B) being dispersed in an aqueous medium containing a base.

    摘要翻译： 一种水性涂料组合物，其包含：（A）通过使丁二烯基聚合物和/或干性油与α，β-不饱和二羧酸酐反应而制备的反应产物，随后与水，一级一元醇或二烷基胺 ; 和（B）具有丙烯酸，甲基丙烯酸或不饱和脂肪酸的改性环氧树脂或具有丙烯酸酯或甲基丙烯酸缩水甘油酯的改性酚醛树脂，组分（A）和（B）分散在含有碱的水性介质中。