Methods of Making Metal-Organic Framework Composites

    公开(公告)号:US20230087627A1

    公开(公告)日:2023-03-23

    申请号:US17904552

    申请日:2021-01-19

    Abstract: Provided herein are methods of making an adsorbent bed useful as a micro-reactor, or a catalytic and/or separation device. The adsorbent bed comprises a metal-organic framework composite. In the present methods, one or more metal-organic frameworks in powder form are mixed in a liquid to produce a metal-organic framework suspension or other type of metal-organic framework coating. A monolith is coated with the suspension or coating to provide the metal-organic framework composite having at least one metal-organic framework coating layer deposited on and bounded to the monolith. The metal-organic framework composite produced has a BET surface area of about 1 m2/g to about 300 m2/g and/or a comparative BET surface area of about 40% to about 100% relative to the metal-organic framework monolith, and pore size between about 1 nm and about 50 nm.

    Marine fuel compositions
    222.
    发明授权

    公开(公告)号:US11603502B2

    公开(公告)日:2023-03-14

    申请号:US17454359

    申请日:2021-11-10

    Abstract: Provided are marine fuels or fuel blending compositions, methods of making such fuels or compositions and methods of potentially reducing the life cycle carbon intensity of marine fuels or a fuel blending compositions. The marine fuel or fuel blending composition disclosed herein includes at least 20 vol % of a resid-containing fraction, and from 5 vol % to 80 vol % of one or more renewable fuel blending components. The one or more renewable fuel blending components includes one or more fatty acid alkyl esters. Optionally the one or more renewable fuel blending components may include gas-to-liquid hydrocarbons from renewable synthesis gas, hydrotreated natural fat or oil, hydrotreated waste cooking oil, hydrotreated tall oil, pyrolysis gas oil, or combinations thereof. Optionally, the resulting marine fuel or fuel blending composition can have a BMCI−TE difference value of 15 or less.

    Processes for polymerizing internal olefins and compositions thereof

    公开(公告)号:US11591419B2

    公开(公告)日:2023-02-28

    申请号:US16705319

    申请日:2019-12-06

    Abstract: The present disclosure provides base stocks and processes for producing such basestocks by polymerizing internal olefins. The present disclosure further provides base stocks, comprising low molecular weight polyolefin products, having one or more of improved flow, low temperature properties, and thickening efficiency. The present disclosure further provides polyolefin products useful as base stocks and or diesel fuel. In at least one embodiment, a process includes introducing a feedstream comprising C4-C30 internal-olefins with a catalyst system comprising a nickel diimine catalyst optionally in the presence of a solvent. The method includes obtaining a C6-C100 polyolefin product having one or more of a carbon fraction of epsilon-carbons of from about 0.08 to about 0.3, as determined by 13C NMR spectroscopy, based on the total carbon content of the polyolefin product.

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