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    Catalyst for improving the performance of liquid hydrocarbon fuel
    252.
    发明授权
    Catalyst for improving the performance of liquid hydrocarbon fuel 失效
    用于提高液态烃燃料性能的催化剂

    公开(公告)号：US06297187B1

    公开(公告)日：2001-10-02

    申请号：US09485788

    申请日：2000-02-16

    Applicant: Katsuyoshi Yamagata

    Inventor： Katsuyoshi Yamagata

    IPC: B01J3100

    CPC classification number: B01J21/18 ,  B01J23/30 ,  B01J31/06 ,  B01J37/0009

    Abstract: The present invention provides a method of making a catalyst for improving the performance of liquid hydrocarbon fuel. The treating agent for improving the performance of liquid hydrocarbon fuel is made by preparing a resin or a rubber composition having 100 parts by weight of a resin or a rubber component, 15 to 60 parts by weight of a carbon source having a particle size of not more than 0.5 mm and containing anthracite in amount not less than 62.5%, to 85 parts by weight of a silicon dioxide source having a particle size of not more 0,5 mm and containing quartz sand in an amount not less than 8-% and 5 to 15 parts by weight of glass fiber having an average fiber length of 6 to 12 &mgr;m, press molding the composition to obtain a molded article, and aging the molded article.

    Abstract translation: 本发明提供一种制备用于提高液态烃燃料性能的催化剂的方法。 用于提高液体烃燃料性能的处理剂通过制备具有100重量份树脂或橡胶组分的树脂或橡胶组合物制备，15至60重量份的不具有颗粒尺寸的碳源 大于0.5mm，含有不少于62.5％的无烟煤，85重量份粒径不大于0.5mm的二氧化硅源，并且含有不小于8-％的石英砂，以及 平均纤维长度为6〜12μm的玻璃纤维为5〜15重量份，对该组合物进行压制成型，得到成形品，并使成型品老化。

    Catalyst for polymerization or copolymerization of olefin
    253.
    发明授权
    Catalyst for polymerization or copolymerization of olefin 失效
    用于烯烃聚合或共聚的催化剂

    公开(公告)号：US06291385B1

    公开(公告)日：2001-09-18

    申请号：US09268552

    申请日：1999-03-15

    Applicant: Young-Sub Lee ,  Youn-Kyung Kang

    Inventor： Young-Sub Lee ,  Youn-Kyung Kang

    IPC: B01J3100

    CPC classification number: B01J21/063 ,  B01J21/10 ,  B01J37/03 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08F4/651 ,  C08F4/6567 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/08

    Abstract: The present invention relates to a catalyst for polymerization or copolymerization of an olefin. The catalyst is produced by first reacting a mixture of a magnesium compound and an aluminum compound with an ester compound which has at least one hydroxy group and a silane compound which has at least one alkoxy group, and next reacting with a titanium compound. The catalyst may be used in the polymerization or copolymerization of ethylene and propylene. The catalyst is believed to have the following formula: a{Mg(OR1)jX12−j}b{Al(OR2)kX23−k}c{(ExED)1Ti(OR3)m(ED)(n4)−m−n} where, R1˜R3=hydrocarbon group, X1˜X2=halogen atoms, ExED=silane compounds comprising an alkoxy group, ED=an ester compound having at least one hydroxy group and a hydrogen of the hydroxy group is removed, and 0

    Abstract translation: 本发明涉及一种用于烯烃聚合或共聚的催化剂。 催化剂通过首先使镁化合物和铝化合物的混合物与具有至少一个羟基的酯化合物和具有至少一个烷氧基的硅烷化合物反应，然后与钛化合物反应来制备。 催化剂可用于乙烯和丙烯的聚合或共聚。 认为催化剂具有下式：其中，R1〜R3 =烃基，X1〜X2 =卤素原子，ExED =含烷氧基的硅烷化合物，ED =具有至少一个羟基的酯化合物和氢 除去羟基，0

    Supported catalyst component for ethylene polymerization and copolymerization
    254.
    发明授权
    Supported catalyst component for ethylene polymerization and copolymerization 失效
    用于乙烯聚合和共聚的负载催化剂组分

    公开(公告)号：US06288005B1

    公开(公告)日：2001-09-11

    申请号：US08314568

    申请日：1994-09-28

    Applicant: Bor-Ping E. Wang ,  Elliot I. Band ,  Ronald A. Epstein

    Inventor： Bor-Ping E. Wang ,  Elliot I. Band ,  Ronald A. Epstein

    IPC: B01J3100

    CPC classification number: C08F10/00 ,  C08F4/6565

    Abstract: A catalyst component, adapted for use in the polymerization and copolymerization of ethylene, is formed by reaction of an organomagnesium compound with a metal oxide support to form a supported organomagnesium composition, reaction of the supported organomagnesium composition and a tetraalkyl silicate, contact of the resulting product with a chlorinating reagent, and treatment of the product from the previous step with liquid titanium halide.

    Abstract translation: 适用于乙烯聚合和共聚的催化剂组分是通过有机镁化合物与金属氧化物载体的反应形成负载的有机镁组合物，负载的有机镁组合物与硅烷四烷基酯的反应形成的， 产品与氯化试剂，并用前面的步骤用液体卤化钛处理产物。

    Highly activated bimetallic complexes and polymerization process
    255.
    发明授权
    Highly activated bimetallic complexes and polymerization process 有权
    高活性双金属络合物和聚合过程

    公开(公告)号：US06284698B1

    公开(公告)日：2001-09-04

    申请号：US09528787

    申请日：2000-03-17

    Applicant: Eugene Y. Chen ,  Shaoguang S. Feng ,  David D. Graf ,  Jasson T. Patton ,  David R. Wilson

    Inventor： Eugene Y. Chen ,  Shaoguang S. Feng ,  David D. Graf ,  Jasson T. Patton ,  David R. Wilson

    IPC: B01J3100

    CPC classification number: C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F2410/03 ,  C08F4/6592

    Abstract: Catalyst compositions comprising 1) one or more bimetallic Group 3-6 or Lanthanide metal complexes corresponding to the formula:  wherein: M and M′ are independently Group 3, 4, 5, 6, or Lanthanide metals; L is a divalent group (or trivalent group if bound to Q) having up to 50 nonhydrogen atoms and containing an aromatic &pgr;-system through which the group is bound to M, said L also being bound to Z; L′ is a monovalent group or a divalent group (if bound to L″ or Q), or a trivalent group (if bound to both L″ and Q) having up to 50 nonhydrogen atoms and containing an aromatic &pgr;-system through which the group is bound to M′; L″ is a monovalent group or a divalent group (if bound to L′ or Q), or a trivalent group (if bound to both L′ and Q) having up to 50 nonhydrogen atoms and containing an aromatic &pgr;-system through which the group is bound to M′, or L″ is a moiety comprising boron or a member of Group 14 of the Periodic Table of the Elements, and optionally also comprising nitrogen, phosphorus, sulfur or oxygen, said L″ having up to 20 non-hydrogen atoms; Z is a moiety comprising boron or a member of Group 14 of the Periodic Table of the Elements, and also comprising nitrogen, phosphorus, sulfur or oxygen, said Z having up to 20 non-hydrogen atoms; X, X′ and X″ are as defined in the specification; Q is a divalent anionic ligand group bound at one terminus to either Z or L and bound at the remaining terminus to either L′ or L″, said Q having up to 20 nonhydrogen atoms; and x, x′, and x″ are independently integers from 0 to 3; and 2) one or more activating cocatalysts; wherein activating cocatalyst component 2) causes both metal centers, M and M′, of the one or more bimetallic metal complexes 1) to be catalytically active for the polymerization of addition polymerizable monomers.

    Abstract translation: 催化剂组合物包含1）一种或多种对应于下式的双金属组3-6或镧系元素金属络合物：其中：M和M'独立地为第3,4,5,6族或镧系金属; L为二价基团（或三价 基团如果结合Q）具有多达50个非氢原子并且含有基团与M结合的芳族π系统，所述L也与Z结合; L'是一价基团或二价基团（如果与 L“或Q）或三价基团（如果与L”和Q两者结合），其具有多达50个非氢原子并且含有该基团通过其与M'结合的芳族π系统; L“是 一价基团或二价基团（如果与L'或Q键合）或三价基团（如果与L'和Q两者结合）具有多达50个非氢原子并含有芳族π-系统，通过该基团键合该基团 M'或L“是包含元素周期表第14族的硼或元素的部分，并且任选地也包含氮，磷 所述L“具有多达20个非氢原子; Z是包含元素周期表第14族的硼或元素的部分，并且还包含氮，磷，硫或氧， 所述Z具有至多20个非氢原子; X，X'和X“如说明书中所定义; Q是在一个末端与Z或L结合的二价阴离子配体基团，并在剩余的末端结合至 L'或L“，所述Q具有至多20个非氢原子; 和x，x'独立地为0至3的整数; 和2）一种或多种活化助催化剂;其中活化助催化剂组分2）使得一种或多种双金属金属络合物1）的金属中心M和M'两者对于可加聚单体的聚合具有催化活性。

    Method for preparing a catalyst suitable for polymerizing an olefin
    257.
    发明授权
    Method for preparing a catalyst suitable for polymerizing an olefin 有权
    制备适于聚合烯烃的催化剂的方法

    公开(公告)号：US06268306B1

    公开(公告)日：2001-07-31

    申请号：US09524515

    申请日：2000-03-13

    Applicant: Vladimir A Zakharov ,  Gennadii D. Bukatov ,  Sergei A. Sergeev

    Inventor： Vladimir A Zakharov ,  Gennadii D. Bukatov ,  Sergei A. Sergeev

    IPC: B01J3100

    CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F4/6565 ,  C08F2500/15 ,  C08F2500/18

    Abstract: A polymerization catalyst obtained by contacting metallic magnesium with an aromatic halide, RX, under conditions effective to obtain a first reaction product and solid residual products is disclosed. The first reaction product is then separated from the solid residual products. A silane compound containing an alkoxy or aryloxy group is added to the first reaction product between −20° C. to 20° C. to obtain a precipitate which is purified to obtain a second reaction product. Subsequently, the second reaction product is contacted with a halogenized titanium compound, such as, titanium tetrachloride, to obtain a further reaction product. The polymerization catalyst is obtained by purifying the further reaction product. In the aromatic halide, R represents an aromatic group containing from 6 to 20 carbon atoms and X represents a halide. An electron dopor such as dibutyl phthalate may also be present during the titanium addition.

    Abstract translation: 公开了在有效获得第一反应产物和固体残余物的条件下使金属镁与芳族卤化物RX接触获得的聚合催化剂。 然后将第一反应产物与固体残余物分离。 将含有烷氧基或芳氧基的硅烷化合物在-20℃至20℃下加入到第一反应产物中，得到沉淀，将其纯化得到第二反应产物。 随后，将第二反应产物与卤化钛化合物如四氯化钛接触，以获得另外的反应产物。 通过纯化另外的反应产物获得聚合催化剂。 在芳香族卤化物中，R表示含有6〜20个碳原子的芳香族基团，X表示卤化物。 在添加钛的过程中，也可存在邻苯二甲酸二丁酯等电子掺杂剂。

    Heterogeneous metallocene catalyst
    259.
    发明授权
    Heterogeneous metallocene catalyst 有权
    异质金属茂催化剂

    公开(公告)号：US06235671B1

    公开(公告)日：2001-05-22

    申请号：US09292039

    申请日：1999-04-14

    Applicant: Ian McKay ,  Alison Ciupa ,  P. Scott Chisholm

    Inventor： Ian McKay ,  Alison Ciupa ,  P. Scott Chisholm

    IPC: B01J3100

    CPC classification number: B01J31/143 ,  B01J23/007 ,  B01J31/1805 ,  B01J31/2295 ,  B01J31/26 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65912 ,  C08F10/00 ,  C08F210/16 ,  C08F4/65916 ,  C08F4/6592 ,  C08F210/08 ,  C08F2500/03

    Abstract: A heterogeneous catalyst for olefin polymerization is prepared by spray drying a mixture of a metallocene catalyst, a cocatalyst and a hydrotalcite. It Preferred hydrotalcites are magnesium-aluminum hydroxy carbonates. The catalysts are very active for ethylene polymerization. The hydrotalcite used in this invention are generally defined by the formula: (Mg1−x Alx(OH)2)n+An−x/n·m H2O wherein X is from 0 to 0.5, m is from 0 to 20 and An− is an anion having a charge of n. Preferred hydrotalcites are those in which the anion A is a carbonate and which have been dried of adsorbed water.

    Abstract translation: 通过喷雾干燥茂金属催化剂，助催化剂和水滑石的混合物来制备用于烯烃聚合的非均相催化剂。 优选的水滑石是羟基碳酸镁铝。 催化剂对于乙烯聚合是非常有活性的。 本发明中使用的水滑石通常由下式定义：其中X为0至0.5，m为0至20，An-为负电荷为n的阴离子。 优选的水滑石是阴离子A是碳酸盐并且已被吸附的水干燥的那些。

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