公开(公告)号：US5998084A

公开(公告)日：1999-12-07

申请号：US749854

申请日：1996-11-15

Applicant: Andreas Elsaesser ,  Raimund Haas ,  Guenter Hultzsch ,  Peter Lehmann ,  Rudolf Neubauer ,  Rudolf Zertani

Inventor： Andreas Elsaesser ,  Raimund Haas ,  Guenter Hultzsch ,  Peter Lehmann ,  Rudolf Neubauer ,  Rudolf Zertani

IPC: G03F7/004 ,  B41N1/14 ,  B41N3/03 ,  G03F7/00 ,  G03F7/022 ,  G03F7/023 ,  G03F7/075 ,  G03F7/30

CPC classification number: B41N3/038 ,  G03F7/0226

Abstract: A positive-working, radiation-sensitive recording material capable of being used for the production of planographic printing plates, comprising: an aluminum support and a radiation-sensitive layer coated thereon, whereinthe aluminum support has been grained in nitric acid, then cleaned in sulfuric acid, anodized in sulfuric acid, and subsequently hydrophilized with a compound comprising at least one unit with a phosphonic acid or phosphonate group; andthe radiation-sensitive layer comprisesa) a radiation-sensitive 1,2-naphthoquinone-2-diazide-4- or -5-sulfonic acid ester of a polycondensate having phenolic hydroxy groups, said polycondensate being obtained by reacting a phenolic compound with an aldehyde or ketone,b) a novolak or a polycondensation product obtained by reacting a polyphenol with an aldehyde or ketone, as an alkali-soluble resin,c) a vinyl-type polymer comprising at least one unit having a lateral hydroxyphenyl group,d) a clathrate-forming compound,e) a low-molecular weight compound which comprises at least one acidic hydrogen atom, andf) silica gel particles having a maximum diameter of 15 .mu.m.

Abstract translation: 能够用于生产平版印刷版的正面工作的辐射敏感记录材料，包括：铝载体和涂覆在其上的辐射敏感层，其中铝载体已经在硝酸中粒化，然后在 硫酸，在硫酸中阳极氧化，随后用包含至少一个具有膦酸或膦酸酯基团的单元的化合物亲水化; 辐射敏感层包括a）具有酚羟基的缩聚物的辐射敏感的1,2-萘醌-2-二叠氮化物-4-或-5-磺酸酯，所述缩聚物是通过使酚类化合物与 醛或酮，b）通过使多酚与醛或酮反应得到的酚醛清漆或缩聚产物作为碱溶性树脂，c）包含至少一个具有侧羟基苯基单元的乙烯基型聚合物，d ）包合物形成化合物，e）包含至少一个酸性氢原子的低分子量化合物，和f）最大直径为15μm的硅胶颗粒。

公开(公告)号：US5753404A

公开(公告)日：1998-05-19

申请号：US558580

申请日：1995-10-31

Applicant: Andreas Elsaesser ,  Otfried Gaschler ,  Werner Frass ,  Klaus-Peter Konrad

Inventor： Andreas Elsaesser ,  Otfried Gaschler ,  Werner Frass ,  Klaus-Peter Konrad

IPC: G03F7/115 ,  G03F7/021 ,  G03F7/11

CPC classification number: G03F7/115

Abstract: A photosensitive recording material is described which has a layer base, a negative-working photosensitive layer containing a diazonium salt and a water-insoluble polymeric binder which is soluble or swellable in aqueous alkaline solutions, and a discontinuous top layer which forms a rough surface and which is composed of particles of a water-insoluble polymer which is dispersible in water in the presence of anionic or anionic/nonionic dispersants and which has a content of free acid groups or acid groups neutralized by salt formation of less than 0.8 mmol/g, the mean height of the particles being 2 to 6 .mu.m, the maximum height less than 10 .mu.m, the mean horizontal diameter less than 40 .mu.m, the maximum diameter less than 80 .mu.m and the number of particles being 100 to 10,000 per cm.sup.2. The material is suitable for the production of planographic printing plates and requires only short vacuum times in a vacuum-operated copying frame. The material can be developed without residue after exposure, the rough surface remaining intact at the image areas.

Abstract translation: 描述了一种感光记录材料，其具有层基底，含有重氮盐的负性感光层和在碱性水溶液中可溶或溶胀的水不溶性聚合物粘合剂，以及形成粗糙表面的不连续顶层和 其由在水阴离子或阴离子/非离子分散剂存在下可分散于水中的水不溶性聚合物的颗粒组成，并且其含量由少于0.8mmol / g的盐形成中和的游离酸基或酸基组成， 颗粒的平均高度为2〜6μm，最大高度小于10μm，平均水平直径小于40μm，最大直径小于80μm，颗粒数为100〜10,000 cm2。 该材料适用于生产平版印刷版，并且在真空操作的复印机架中仅需要较短的真空时间。 材料可以在曝光后无残留发育，粗糙的表面在图像区域保持完整。

公开(公告)号：US5700621A

公开(公告)日：1997-12-23

申请号：US607809

申请日：1996-02-28

Applicant: Mathias Eichhorn ,  Andreas Elsaesser

Inventor： Mathias Eichhorn ,  Andreas Elsaesser

IPC: G03F7/022 ,  C08F20/52 ,  C08F20/54 ,  C08F20/60 ,  C08K5/28 ,  C08L33/24 ,  G03F7/023 ,  G03F7/037 ,  G03F7/039 ,  G03C1/52

CPC classification number: G03F7/0233 ,  C08F20/60

Abstract: A polymer comprising repeating units of the formula ##STR1## wherein R.sup.1 , R.sup.2 and R.sup.3 are, independently of one another, hydrogen atoms or alkyl groups, X is CO or SO.sub.2, and Y and Z are, independently of one another, alkyl, alkenyl, cycloalkyl, aryl or heterocyclic radicals, or Y and Z are linked to one another and are constituents of a five-membered or six-membered hetero-cyclic ring.

Abstract translation: 包含式（I）的重复单元的聚合物，其中R 1，R 2和R 3彼此独立地为氢原子或烷基，X为CO或SO 2，Y和Z彼此独立地为氢， 烷基，烯基，环烷基，芳基或杂环基，或Y和Z彼此连接并且是五元或六元杂环的组成。

公开(公告)号：US5637441A

公开(公告)日：1997-06-10

申请号：US492148

申请日：1995-06-19

Applicant: Michael Brenk ,  Mathias Eichhorn ,  Andreas Elsaesser

Inventor： Michael Brenk ,  Mathias Eichhorn ,  Andreas Elsaesser

IPC: G03F7/09 ,  B41N3/03 ,  G03F7/00 ,  G03G5/14 ,  B32B15/08 ,  G03F7/016 ,  G03F7/023

CPC classification number: B41N3/036 ,  Y10T428/31692

Abstract: A mechanically and/or electrochemically grained and optionally anodized base material composed of aluminum or its alloys, to which a hydrophilic layer of at least one polymer containing basic and acidic groups is applied. This layer is followed by a further hydrophilic layer which contains at least one compound containing at least one phosphono group. In addition, the invention relates to a method of producing said carrier material and to photosensitive recording material for offset printing plates produced therewith.

Abstract translation: 由铝或其合金组成的机械和/或电化学颗粒和任选的阳极氧化的基材，其中施加至少一种含有碱性和酸性基团的聚合物的亲水层。 该层之后是另外的亲水层，其含有至少一种含有至少一个膦酰基的化合物。 此外，本发明涉及一种生产所述载体材料的方法和用于制造的胶版印刷用感光记录材料。

公开(公告)号：US5436106A

公开(公告)日：1995-07-25

申请号：US273071

申请日：1994-07-11

Applicant: Dieter Mohr ,  Martin Benzing ,  Juergen Mertes ,  Guenter Hultzsch ,  Ine Gramm ,  Manfred Michel ,  Andreas Elsaesser ,  Shane Hsieh ,  David L. Siegfried

Inventor： Dieter Mohr ,  Martin Benzing ,  Juergen Mertes ,  Guenter Hultzsch ,  Ine Gramm ,  Manfred Michel ,  Andreas Elsaesser ,  Shane Hsieh ,  David L. Siegfried

IPC: G03F3/10 ,  G03F7/023 ,  G03F7/105 ,  G03F7/30

CPC classification number: G03F7/0233 ,  G03F3/10

Abstract: The invention relates to a positive-working colored photosensitive recording material for the production of a color test image, composed of a temporary layer carrier, a photosensitive layer containing dyestuff or pigment, binder and quinonediazide compound and an adhesive layer which can be activated by means of heat, wherein a release layer based on polyvinyl alcohol is present on the surface of the temporary layer carrier, the photosensitive layer comprises, as the quinonediazide compound, an esterification product of a compound containing one or more phenolic hydroxyl groups and o-quinonediazide-sulfonyl chloride, and, as the binder, a novolak-free phenolic polymer resin and/or a reaction product of the phenolic polymer resin with a monoisocyanate, and the adhesive layer comprises a alkali-insoluble organic polymer and an alkali-soluble polyester. The invention also relates to a process for the production of a color test image using the recording material described.

Abstract translation: 本发明涉及一种用于生产彩色试验图像的正色彩色光敏记录材料，由临时层载体，含有染料或颜料的感光层，粘合剂和醌二叠氮化合物组成，粘合剂层可通过手段 的热量，其中基于聚乙烯醇的剥离层存在于临时层载体的表面上，感光层包含作为醌二叠氮化合物的含有一个或多个酚羟基的化合物和邻醌二叠氮化物的酯化产物， 磺酰氯和作为粘合剂的无酚醛清漆的酚醛聚合物树脂和/或酚醛聚合物树脂与单异氰酸酯的反应产物，并且粘合剂层包含碱不溶性有机聚合物和碱溶性聚酯。 本发明还涉及使用所述记录材料生产彩色测试图像的方法。

公开(公告)号：US06492093B2

公开(公告)日：2002-12-10

申请号：US09362857

申请日：1999-07-29

Applicant: Otfried Gaschler ,  Andreas Elsaesser ,  Joerg Jung ,  Hans-Joachim Schlosser

Inventor： Otfried Gaschler ,  Andreas Elsaesser ,  Joerg Jung ,  Hans-Joachim Schlosser

IPC: G03C177

CPC classification number: B41C1/1008 ,  B41C1/1016 ,  B41C2201/02 ,  B41C2201/14 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  Y10S430/106 ,  Y10S430/127 ,  Y10S430/145

Abstract: The invention relates to a positive-working, radiation-sensitive mixture which contains an organic polymeric binder which is insoluble in water but soluble or at least swellable in aqueous alkaline solution and at least one IR-absorbing cyanine dye having a betaine structure or having a betaine structure and containing an anion and having the formula (I) in which R1 to R8 independently of one another, are a hydrogen or halogen atom, a sulfonate, carboxylate, phosphonate, hydroxyl, (C1-C4)alkoxy, nitro, amino, (C1-C4)alkylamino, di(C1-C4)alkylamino group or a (C6-C10)aryl group which in turn may be substituted by one or more halogen atoms and/or one or more sulfonate, carboxylate, phosphonate, hydroxyl, (C1-C4)alkoxy, nitro, amino, (C1-C4)alkylamino and/or di(C1-C4)alkylamnino groups, R9 and R10 independently of one another, are a straight-chain or branched (C1-C6)alkyl, a (C7-C6)aralkyl or a (C6-C10)aryl group, each of which in turn may be substituted by one or more halogen atoms and/or one or more sulfonate, carboxylate, phosphonate, hydroxyl, (C1-C4)alkoxy, nitro, amino, (C1-C4)alkylamino and/or di(C1-C4)alkylamino groups, R11 and R12 independently of one another, are (C1-C4)alkyl or (C6-C10)aryl groups which in turn may be substituted, Z1 and Z2 independently of one another, are a sulfur atom, a di(C1-C4)alkylmethylene group or an ethene-1,2-diyl group and A is a carbon atom or a chain having conjugated double bonds which results in the formation of a delocalized II-electron system between the quaternary nitrogen atom of the 3H-indolium, quinolinium or benzothiazolium radical and the enolate oxygen atom of the pyrimidine-2,4,6-trione radical. After imagewise exposure to a laser, the recording material prepared using this mixture can be readily developed with an aqueous alkaline solution without additional processing steps (such as post-bake or postexposure). The invention also relates to a process for the production of printing plates for offset printing from a recording material according to the invention.

公开(公告)号：US06197472B1

公开(公告)日：2001-03-06

申请号：US09532324

申请日：2000-03-21

Applicant: Klaus-Peter Konrad ,  Andreas Elsaesser ,  Frank Fischer ,  John Kynaston Davies

Inventor： Klaus-Peter Konrad ,  Andreas Elsaesser ,  Frank Fischer ,  John Kynaston Davies

IPC: G03F7021

CPC classification number: G03F7/105

Abstract: The present invention relates to a recording material having a substrate and a negative-working, radiation-sensitive layer which contains a diazonium salt, metal-free colored pigments dispersed in an organic polymeric binder, transparent spacer pigments having a pore volume of more than 1.0 ml/g and a polymeric binder. The predispersal of the colored pigments is achieved by milling with an organic polymeric binder containing hydroxyl groups, some or all of which have been reacted with a di- or polycarboxylic anhydride so that the binder has an acid number of from 20 to 200. Printing plates in which the printing parts have a clearly visible contrast relative to the substrate can be produced from the recording material.

Abstract translation: 本发明涉及一种记录材料，其具有底物和负性辐射敏感层，其含有重氮盐，分散在有机聚合物粘合剂中的无金属着色颜料，孔体积大于1.0的透明间隔颜料 ml / g和聚合物粘合剂。 着色颜料的前体是通过用含有羟基的有机聚合物粘合剂研磨来实现的，其中一些或全部已经与二羧酸酐或多元羧酸酐反应，使得粘合剂的酸值为20-200。印刷板 其中可以从记录材料产生印刷部件相对于基板具有清晰可见的对比度。

公开(公告)号：US5972572A

公开(公告)日：1999-10-26

申请号：US185030

申请日：1998-11-03

Applicant: Klaus Peter Konrad ,  Steffen Denzinger ,  Andreas Elsaesser

Inventor： Klaus Peter Konrad ,  Steffen Denzinger ,  Andreas Elsaesser

IPC: G03F7/32 ,  G03C5/30

CPC classification number: G03F7/322

Abstract: A developer for irradiated, radiation-sensitive recording materials, in particular for the production of offset printing plates, which contains water, a compound which is alkaline in aqueous solution and a copolymer which acts as an emulsifier and has units of (I) a hydrophobic vinyl compound which has alkyl radicals having up to 30 carbon atoms and (II) a hydrophilic, ethylenically unsaturated carboxylic acid. Some of the carboxyl groups of the copolymer are esterified with reaction products of (A) (C.sub.1 -C.sub.30)alkanols, (C.sub.8 -C.sub.25)alkanoic acids, (C.sub.1 -C.sub.12)alkylphenols or di(C.sub.1 -C.sub.20)alkylamines with (B) (C.sub.2 -C.sub.4)alkylene oxides or tetrahydrofuran.

Abstract translation: 用于辐射敏感记录材料的显影剂，特别是用于生产胶版印刷版，其中含有水，在水溶液中呈碱性的化合物和作为乳化剂的共聚物，并具有（I）疏水性 具有至多30个碳原子的烷基的乙烯基化合物和（II）亲水性烯属不饱和羧酸。 共聚物的一些羧基用（A）（C1-C30）链烷醇，（C8-C25）链烷酸，（C1-C12）烷基酚或二（C1-C20）烷基胺与（B）的反应产物酯化， （C 2 -C 4）环氧烷烃或四氢呋喃。

公开(公告)号：US5378584A

公开(公告)日：1995-01-03

申请号：US924750

申请日：1992-08-04

Applicant: Hans W. Frass ,  Ernst-August Hackmann ,  Klaus Joerg ,  Dietmar Koenneke ,  Rudolf Neubauer ,  Andreas Elsaesser

Inventor： Hans W. Frass ,  Ernst-August Hackmann ,  Klaus Joerg ,  Dietmar Koenneke ,  Rudolf Neubauer ,  Andreas Elsaesser

IPC: G03F7/00 ,  G03F7/004 ,  G03F7/022 ,  G03F7/115 ,  G03F7/023 ,  G03F7/30

CPC classification number: G03F7/004 ,  G03F7/0226 ,  G03F7/115

Abstract: A radiation-sensitive recording material, in particular for producing planographic printing plates, is disclosed. The material is composed of a layer support and a positive-working, radiation-sensitive layer having a rough surface containing at least one 1,2-quinonediazide as a radiation-sensitive compound, a polycondensate or polymer as a binder insoluble in water and soluble or swellable in aqueous-alkaline solutions, a dye and a filler. At a layer weight of 3 g/m.sup.2 or less, the radiation-sensitive layer comprises a silicic acid product having a mean grain size in the range from 3 to 5 .mu.m with an exclusion limit of 15 .mu.m as a filler in such a quantity that it exhibits a Bekk smoothness in the range from 20 to 100 seconds (determined according to DIN 53 107, Method A). The layer additionally comprises a surfactant having polysiloxane units. The recording material shows good copying properties and technical printing properties, such as an advantageous evacuation time, screen evenness, low susceptibility to air occlusions, good resolving power and a good coating structure. The invention also relates to a process for producing a planographic printing plated, using the recording material according to the invention.

Abstract translation: 公开了一种辐射敏感记录材料，特别是用于生产平版印刷版的材料。 该材料由具有粗糙表面的层载体和正性辐射敏感层组成，其具有至少一种作为辐射敏感性化合物的1,2-醌二叠氮化物，作为不溶于水和可溶性的粘合剂的缩聚物或聚合物 或在水性碱性溶液中溶胀，染料和填料。 在3g / m 2以下的层重量下，辐射敏感层包含平均粒度在3〜5μm的硅酸产品，排阻极限为15μm作为填料， 其表现为Bekk平滑度在20至100秒的范围内（根据DIN 53 107，方法A确定）。 该层还包含具有聚硅氧烷单元的表面活性剂。 记录材料具有良好的复印性能和技术打印性能，例如有利的抽真空时间，屏幕均匀性，对空气阻塞的低敏感性，良好的分辨能力和良好的涂层结构。 本发明还涉及使用根据本发明的记录材料来生产平版印刷电镀的方法。

公开(公告)号：US5348833A

公开(公告)日：1994-09-20

申请号：US939909

申请日：1992-09-04

Applicant: Dieter Mohr ,  Martin Benzing ,  Juergen Mertes ,  Guenter Hultzsch ,  Ine Gramm ,  Manfred Michel ,  Andreas Elsaesser ,  Shane Hsieh ,  David L. Siegfried

Inventor： Dieter Mohr ,  Martin Benzing ,  Juergen Mertes ,  Guenter Hultzsch ,  Ine Gramm ,  Manfred Michel ,  Andreas Elsaesser ,  Shane Hsieh ,  David L. Siegfried

IPC: G03F3/10 ,  G03F7/023 ,  G03F7/105 ,  G03F7/11

CPC classification number: G03F7/0233 ,  G03F3/10

Abstract: The invention relates to a positive-working colored photosensitive recording material for the production of a color test image, composed of a temporary layer carrier, a photosensitive layer containing dyestuff or pigment, binder and quinonediazide compound and an adhesive layer which can be activated by means of heat, wherein a release layer based on polyvinyl alcohol is present on the surface of the temporary layer carrier, the photosensitive layer comprises, as the quinonediazide compound, an esterification product of a compound containing one or more phenolic hydroxyl groups and o-quinonediazide-sulfonyl chloride, and, as the binder, a novolak-free phenolic polymer resin and/or a reaction product of the phenolic polymer resin with a monoisocyanate, and the adhesive layer compresses a alkali-insoluble organic polymer and an alkali-soluble polyester. The invention also relates to a process for the production of a color test image using the recording material described.

Abstract translation: 本发明涉及一种用于生产彩色试验图像的正色彩色光敏记录材料，由临时层载体，含有染料或颜料的感光层，粘合剂和醌二叠氮化合物组成，粘合剂层可通过手段 的热量，其中基于聚乙烯醇的剥离层存在于临时层载体的表面上，感光层包含作为醌二叠氮化合物的含有一个或多个酚羟基的化合物和邻醌二叠氮化物的酯化产物， 磺酰氯，作为粘合剂，不含酚醛清漆的酚醛聚合物树脂和/或酚醛聚合物树脂与单异氰酸酯的反应产物，并且粘合剂层压制碱不溶性有机聚合物和碱溶性聚酯。 本发明还涉及使用所述记录材料生产彩色测试图像的方法。