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21.发明授权Supported palladium-gold catalyst, its manufacture and use in reactions for the selective hydrogenation of diolefinic and/or acetylenic hydrocarbons 失效负载钯 - 金催化剂，其制备和用于二烯烃和/或炔烃的选择性氢化反应
公开(公告)号：US4533779A
公开(公告)日：1985-08-06
申请号：US672754
申请日：1984-11-20
申请人： Jean-Paul Boitiaux , Jean Oosyns
发明人： Jean-Paul Boitiaux , Jean Oosyns
IPC分类号： C07C5/05 , B01J23/44 , B01J23/52 , C07B61/00 , C07C1/00 , C07C5/09 , C07C7/167 , C07C11/02 , C07C67/00 , C10G45/50 , C07C7/163 , C07C5/03
摘要： Supported palladium-gold catalyst of high resistance to poisoning by sulfur compounds, not subject to elution by vinylacetylene and not inducing a substantial formation of oligomers, for use in hydrogenation reactions wherein acetylenics and diolefins are selectively hydrogenated, said catalyst being obtained by the steps of: admixing a palladium compound with an inorganic carrier, roasting in the presence of an oxygen-containing gas, treating with a reducing agent, admixing a halogenated gold compound with the resulting composition, treating with a reducing agent, treating with a compound having a basic reaction so as to lower the halogen content of the catalyst below 10 ppm by weight, and roasting, in the presence of an oxygen-containing gas, the palladium and gold compounds being used in convenient proportions so that the catalyst contains 0.03 to 1% palladium and 0.003 to 0.3% gold by weight.
摘要翻译： 所述催化剂是通过以下步骤获得的，所述钯 - 金催化剂具有高耐硫化合物中毒的乙烯基乙炔中和，不会被乙烯基乙炔洗脱并且不引起大量的低聚物形成，用于氢化反应，其中乙炔基化合物和二烯烃被选择性氢化， ：将钯化合物与无机载体混合，在含氧气体存在下焙烧，用还原剂处理，将卤化金化合物与所得组合物混合，用还原剂处理，用具有碱性的化合物 反应，以使催化剂的卤素含量降低至10重量ppm以下，并且在含氧气体存在下，以适当比例使用钯和金化合物焙烧，使得催化剂含有0.03至1％的钯 和0.003至0.3重量％的金。
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公开(公告)号：US06315892B1
公开(公告)日：2001-11-13
申请号：US09688167
申请日：2000-10-16
IPC分类号： C10G35085
CPC分类号： B01J23/622 , B01J23/62 , B01J37/0205 , C10G35/09 , Y10S502/506 , Y10S502/513 , Y10S502/514
摘要： A process of hydroreforming in the presence of a catalyst containing at least one refractory inorganic carrier, platinum, possibly at least one metal from Group VIII (palladium, nickel, and ruthenium), a halogen or compound thereof, and at least one additional metal M selected from among germanium, tin, lead, gallium, indium, and thallium, process in which said metal M, in the form of at least one organic compound, is introduced in situ into the reactor where the hydrocarbon charge will then be treated or into a prereactor that is connected to said reactor.
摘要翻译： 在含有至少一种难熔性无机载体的铂的催化剂存在下进行加氢反应的方法，铂，可能的至少一种来自第VIII族（钯，镍和钌）的金属，卤素或其化合物，以及至少一种另外的金属M 选自锗，锡，铅，镓，铟和铊的方法，其中将至少一种有机化合物形式的所述金属M原位引入反应器中，其中烃装料将被处理或进入 连接到所述反应器的预反应器。
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23.发明授权Process for the isomerization of external olefins to internal olefins concomitantly with diolefin hydrogenation 失效将外部烯烃异构化为内烯烃同时进行二烯烃氢化的方法
公开(公告)号：US5502269A
公开(公告)日：1996-03-26
申请号：US282474
申请日：1994-07-29
摘要： The present invention concerns a process for the isomerization of external olefins to internal olefins, the feedstock also containing diolefins, using a palladium based catalyst which contains 0.05% to 10% by weight of sulphur, said catalyst being treated before loading into the reactor with at least one organic sulphur-containing compound dissolved in a solvent, then activated in a neutral or reducing atmosphere at a temperature of between 20.degree. C. and 300.degree. C., before being brought into contact with the feedstock.
摘要翻译： 本发明涉及使用含有0.05重量％至10重量％硫的钯基催化剂将外部烯烃异构化成内部烯烃的方法，所述原料还含有二烯烃，所述催化剂在装载到反应器中之前被处理 将至少一种有机含硫化合物溶解在溶剂中，然后在中性或还原性气氛中在20℃至300℃的温度下活化，然后与原料接触。
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24.发明授权Process for the selective hydrogenation of compounds comprising endo and exocyclic unsaturations 失效用于选择性氢化包含内环和外环不饱和化合物的方法
公开(公告)号：US5475174A
公开(公告)日：1995-12-12
申请号：US156777
申请日：1993-11-24
CPC分类号： C07C5/05 , B01J23/622 , C07C2101/14 , C07C2523/14 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/62 , C07C2523/755 , C07C2523/835
摘要： The invention concerns a process for the selective hydrogenation of polyunsaturated cyclic compounds comprising at least one endocyclic carbon-carbon double bond and at least one terminal exocyclic carbon-carbon double bond, said double bonds not being conjugated, to form a mixture essentially containing the saturated ring compound and comprising at least one terminal exocyclic double bond, the process being carried out in the presence of hydrogen under a pressure of from 1 to 10 MPa and at a temperature of from 0.degree. to 200.degree. C., and in the presence of a catalyst including a support and (a) from 0.1 to 5% by weight of at least one metal from group VIII (iridium, osmium, nickel, palladium, platinum and rhodium) and (b) from 0.01 to 15% by weight of at least one metal from group IVa (tin, germanium and lead), the molar ratio between metals of group VIII and group IVa being between 0.3 and 3. The process is used for the hydrogenation of 4-vinylcylcohexene to vinylcyclohexane.
摘要翻译： 本发明涉及包含至少一个内环碳 - 碳双键和至少一个末端环外碳 - 碳双键的多不饱和环状化合物的选择性氢化的方法，所述双键不是共轭的，以形成基本上含有饱和的 环化合物并且包含至少一个末端环外双键，该方法在氢气存在下，在1至10MPa的压力和0至200℃的温度下进行，并且在 包含载体的催化剂和（a）0.1至5重量％的至少一种第VIII族金属（铱，锇，镍，钯，铂和铑）和（b）0.01至15重量％ 来自IVa族（锡，锗和铅）的至少一种金属，VIII族和IVa族金属之间的摩尔比在0.3和3之间。该方法用于将4-乙烯基环己烯氢化成乙烯基环己烷。
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25.发明授权
公开(公告)号：US5336829A
公开(公告)日：1994-08-09
申请号：US37117
申请日：1993-03-25
申请人： Jean-Paul Boitiaux , Jean De Bonneville , Jean-Pierre Burzynski , Gerard Leger , Fabienne Le Peltier , Germain Martino
发明人： Jean-Paul Boitiaux , Jean De Bonneville , Jean-Pierre Burzynski , Gerard Leger , Fabienne Le Peltier , Germain Martino
CPC分类号： B01J38/44 , B01J23/90 , B01J29/90 , C07C5/3337 , C07C2523/04 , C07C2523/14 , C07C2523/40 , C07C2523/42 , C07C2529/06 , Y02P20/584
摘要： A continuous process for the dehydrogenation of paraffinic and olefinic hydrocarbons in the presence of a catalyst comprises circulating a charge containing said paraffinic hydrocarbons through at least two reactions zones of the moving bed type which are arranged in series, the catalyst flowing successively in each reaction zone. The catalyst which is drawn off from the last reaction zone is sent to a regeneration zone at the exit from which it is reintroduced close to the first reaction zone. The process comprises the injection of sulphur and/or at least one sulphur compound before or simultaneously to the introduction of the charge into the first reaction zone. In accordance with the process, the catalyst which is drawn off from the last reaction zone is sent into a stripping zone wherein the sulphur which it contains is removed before the catalyst is sent to the regeneration zone.
摘要翻译： 在催化剂存在下，链烷烃和烯烃的脱氢的连续方法包括使包含所述链烷烃的进料通过串联排列的移动床型的至少两个反应区循环，催化剂在每个反应区中依次流动 。 从最后一个反应区抽出的催化剂被送到出口处的再生区，在该再生区再次引入靠近第一反应区的再生区。 该方法包括在将电荷引入第一反应区之前或同时注入硫和/或至少一种硫化合物。 根据该方法，将从最后反应区抽出的催化剂送入汽提区，其中在将催化剂送至再生区之前将其所含的硫除去。
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26.发明授权Process for selective hydrogenation, in particular of diolefins in steam cracking volatiles, with a catalyst in the form of beds which are used successively 失效用于选择性氢化的方法，特别是蒸汽裂解挥发物中的二烯烃与催化剂以床形式连续使用的方法
公开(公告)号：US5306852A
公开(公告)日：1994-04-26
申请号：US10386
申请日：1993-01-28
摘要： The invention concerns a hydrogenation process, in particular for the selective hydrogenation of diolefins in volatiles produced by steam cracking or other cracking processes, in which the catalyst is distributed in a plurality of beds. It is characterized in that the different catalyst beds are not used at the same time, but successively and in accordance with a given order.
摘要翻译： 本发明涉及氢化方法，特别是用于通过蒸汽裂化或其它裂化方法制备的挥发物中二烯烃的选择性氢化，其中催化剂分布在多个床中。 其特征在于不同的催化剂床不是同时使用，而是依次按照给定的顺序使用。
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公开(公告)号：US5304693A
公开(公告)日：1994-04-19
申请号：US751008
申请日：1991-08-28
CPC分类号： B01D53/02 , B01D53/8665
摘要： A process for the elimination of mercury from an overall steam cracking installation, characterized in that regeneration is terminated by the injection of regeneration gas onto an active demercurizing mass, such that there is substantially no trace of mercury in the air or liquids leaving the installation. The process involves the use of three demercurizing masses, namely two upstream of the installation which are in series and one downstream, which latter is demercurized by at least one of the upstream masses. The use more particularly applies to the depollution of steam cracking installations which are already polluted by mercury.
摘要翻译： 一种从整体蒸汽裂解装置中消除汞的方法，其特征在于再生通过将再生气体注入到活性脱水剂块而终止，使得离开设备的空气或液体基本上没有痕量的汞。 该过程涉及使用三个脱水质量块，即串联的两个上游设备和一个下游管道，后者由至少一个上游质量块排出。 这种用途更特别适用于已经被汞污染的蒸汽裂解装置的污染。
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28.发明授权Process for selectively hydrogenating acetylene in a mixture of acetylene and ethylene 失效在乙炔和乙烯的混合物中选择性氢化乙炔的方法
公开(公告)号：US4571442A
公开(公告)日：1986-02-18
申请号：US652035
申请日：1984-09-19
申请人： Jean Cosyns , Jean-Paul Boitiaux
发明人： Jean Cosyns , Jean-Paul Boitiaux
CPC分类号： C07C5/08 , C07C7/167 , C07C2521/04 , C07C2523/44 , Y02P20/52
摘要： Acetylene is selectively hydrogenated by passing a mixture of acetylene and ethylene with a hydrocarbon liquid phase through a bed of a palladium-on-alumina catalyst. The liquid phase comprises an aromatic hydrocarbon and a primary or secondary amine.
摘要翻译： 通过使乙炔和乙烯的混合物与烃液相通过钯 - 氧化铝催化剂床来选择性氢化乙炔。 液相包含芳烃和伯胺或仲胺。
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