Latex paints which are free of volatile coalescents and freeze-thaw
additives
    23.
    发明授权
    Latex paints which are free of volatile coalescents and freeze-thaw additives 失效
    不含挥发性聚结剂和冻融添加剂的乳胶漆

    公开(公告)号:US5610225A

    公开(公告)日:1997-03-11

    申请号:US434098

    申请日:1995-05-03

    CPC classification number: C09D133/066 C09D155/005

    Abstract: Freeze-thaw stable latex binders and latex paint compositions are prepared without the use of volatile freeze-thaw additives. The latex binder contains a polymer which is the emulsion polymerization product of a polymerizable polyethylene glycol (PPEG) monomer, wherein the molecular weight of the ethylene oxide moiety in the PPEG monomer is from about 175 to 1,100, at least one acrylic monomer and, optionally, one or more styrenic, ionic or wet adhesion monomers. Methods for preparing the freeze-thaw stable latex compositions are also disclosed.

    Abstract translation: 在不使用挥发性冻融添加剂的情况下制备冻融稳定的胶乳粘合剂和乳胶漆组合物。 胶乳粘合剂含有聚合物,聚合物是可聚合聚乙二醇(PPEG)单体的乳液聚合产物,其中PPEG单体中环氧乙烷部分的分子量为约175至1100,至少一种丙烯酸单体, ,一种或多种苯乙烯,离子或湿粘附单体。 还公开了制备冻融稳定胶乳组合物的方法。

    Vinyl acetate polymer with wet adhesion
    24.
    发明授权
    Vinyl acetate polymer with wet adhesion 失效
    具有湿粘合性的乙酸乙烯酯聚合物

    公开(公告)号:US5208285A

    公开(公告)日:1993-05-04

    申请号:US749613

    申请日:1991-08-16

    CPC classification number: C09D133/06 C09D131/04 C09D157/12 C08L33/062

    Abstract: Wet adhesion properties comparable or superior to all-acrylic latexes for vinyl acetate copolymers and other low cost polymers, such as EVA-vinyl chloride copolymers, is achieved by blending a minor proportion, usually about 5 to 15%, of a small particle size copolymer containing copolymerized wet adhesion monomer which is a cyclic ureido. Very low quantities of the wet adhesion monomer, less than 0.25 wt% of total monomers, only are required to achieve excellent results.

    Abstract translation: 通过将较小比例(通常为约5至15%)的小粒径共聚物(例如乙烯 - 乙烯共聚物)与乙烯基乙酸酯共聚物和其它低成本聚合物(例如EVA-氯乙烯共聚物)的全丙烯酸胶乳相当或优于湿粘合性能, 含有共聚合的湿粘合性单体,其为环状脲基。 非常少量的湿粘合单体,小于总单体的0.25重量%,仅需要达到优异的结果。

    AQUEOUS LATEX COATING COMPOSITIONS
    26.
    发明申请
    AQUEOUS LATEX COATING COMPOSITIONS 有权
    AQUEOUS LATEX涂料组合物

    公开(公告)号:US20140018473A1

    公开(公告)日:2014-01-16

    申请号:US13990550

    申请日:2010-12-17

    Abstract: Disclosed are aqueous latex-based coating compositions which comprise a blend of an ethylene-vinyl acetate emulsion copolymer component and a selected type of acrylic emulsion copolymer component. The acrylic copolymer component comprises primarily acrylate ester co-monomers or acrylic ester co-monomers and vinyl aromatic, e.g., styrene, co-monomers. The blend of these two emulsion copolymer types also contains a specific type of hydrazine-based, water-soluble cross-linking agent which can eventually react with the acrylic emulsion copolymer component. The acrylic emulsion copolymer is one which contains minor amounts of both 1) carboxy functional co-monomers such as itaconic and/or (meth)acrylic acids, and 2) keto- or aldehyde-containing co-monomers such as diacetone acrylamide. Such latex-based coating compositions can be formulated in the form of water-based paint compositions. These paint products provide paint coatings that exhibit desirable dry and wet adhesion characteristics and desirable resistance to blocking.

    Abstract translation: 公开了含有乙烯 - 乙酸乙烯酯乳液共聚物组分和所选类型的丙烯酸乳液共聚物组分的共混物的水性胶乳基涂料组合物。 丙烯酸共聚物组分主要包括丙烯酸酯共聚单体或丙烯酸酯共聚单体和乙烯基芳族化合物,例如苯乙烯共聚单体。 这两种乳液共聚物类型的共混物也含有特定类型的肼类水溶性交联剂,其可以最终与丙烯酸乳液共聚物组分反应。 丙烯酸乳液共聚物是含有少量两种1)羧基官能共聚单体如衣康酸和/或(甲基)丙烯酸的共聚物,和2)含有酮或醛的共聚单体如双丙酮丙烯酰胺。 这种胶乳基涂料组合物可以以水基涂料组合物的形式配制。 这些涂料产品提供涂料涂料,其表现出所需的干和湿粘合特性和所需的阻断性。

    Salt-sensitive binders for nonwoven webs and method of making same
    27.
    发明授权
    Salt-sensitive binders for nonwoven webs and method of making same 失效
    用于非织造纤维网的盐敏感粘合剂及其制造方法

    公开(公告)号:US07989545B2

    公开(公告)日:2011-08-02

    申请号:US11339216

    申请日:2006-01-25

    Abstract: A solution with a salt-sensitive polymer binder for use in fibrous webs, where the binder contains a copolymer of carboxylic acid monomer units and ethylenically unsaturated monomer units. The binder solution is prepared by emulsion-polymerizing a copolymer and then neutralizing the copolymer with base to make it water soluble. The binders provide a higher wet strength in concentrated salt solutions than in deionized water, and are particularly suitable for strengthening nonwoven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like.

    Abstract translation: 具有用于纤维网的盐敏聚合物粘合剂的溶液,其中粘合剂含有羧酸单体单元和烯属不饱和单体单元的共聚物。 通过将共聚物乳液聚合,然后用碱中和共聚物使其成为水溶性,制备粘合剂溶液。 粘合剂在浓缩盐溶液中比在去离子水中提供更高的湿强度,并且特别适合于加强一次性制品如湿巾,个人护理产品,尿布等中的非织造纤维网。

    Salt-sensitive cationic polymeric binders for nonwoven webs and method of making the same
    29.
    发明申请
    Salt-sensitive cationic polymeric binders for nonwoven webs and method of making the same 失效
    用于非织造纤维网的盐敏阳离子聚合物粘合剂及其制备方法

    公开(公告)号:US20090218059A1

    公开(公告)日:2009-09-03

    申请号:US12380631

    申请日:2009-03-02

    Abstract: A solution with a salt-sensitive polymer binder for use in fibrous webs, where the binder contains a copolymer comprising repeat units derived from butyl acrylate, methyl methacrylate and amino functionalized alkyl acrylate or methacrylate or amino functionalized alkyl acrylamide or methacrylamide optionally including monomers such as vinyl acetate and/or vinyl acetate/ethylene. The binder solution is prepared by emulsion-polymerizing a copolymer and then neutralizing the copolymer with acid to make it water soluble. The binders are particularly suitable for strengthening nonwoven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like and retain their salt-sensitivity with or without divalent metal scavengers.

    Abstract translation: 具有用于纤维网的盐敏聚合物粘合剂的溶液,其中粘合剂含有包含衍生自丙烯酸丁酯,甲基丙烯酸甲酯和氨基官能化烷基丙烯酸酯或甲基丙烯酸酯或氨基官能化烷基丙烯酰胺或甲基丙烯酰胺的重复单元的共聚物,任选地包括单体如 乙酸乙烯酯和/或乙酸乙烯酯/乙烯。 粘合剂溶液通过乳液聚合共聚物然后用酸中和共聚物来制备,使其具有水溶性。 粘合剂特别适合于加强一次性制品如湿巾,个人护理产品,尿布等中的非织造纤维网,并且保持其具有或不具有二价金属清除剂的盐敏感性。

    Salt-sensitive vinyl acetate binder compositions and fibrous article incorporating same
    30.
    发明授权
    Salt-sensitive vinyl acetate binder compositions and fibrous article incorporating same 失效
    盐敏乙酸乙烯酯粘合剂组合物和掺入其的纤维制品

    公开(公告)号:US07320831B2

    公开(公告)日:2008-01-22

    申请号:US11120372

    申请日:2005-05-03

    Abstract: A salt sensitive polymeric binder for use in fibrous webs, where the binder contains a copolymer incorporating the residue of vinyl acetate, a carboxylic acid, and a vinyl ester of a saturated aliphatic monocarboxylic acid having between 6 and 18 carbon atoms in the carboxylic acid moiety. The copolymer is neutralized at least to the extent that it is water soluble. The binders are particularly suitable for strengthening non-woven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like.

    Abstract translation: 用于纤维网的盐敏聚合物粘合剂,其中粘合剂含有在羧酸部分中含有6-18个碳原子的饱和脂族一元羧酸的残基的羧酸和羧酸残基的共聚物 。 至少将共聚物中和到水溶性的程度。 粘合剂特别适用于在一次性制品如湿巾,个人护理产品,尿布等中加强非织造纤维网。

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