公开(公告)号：US10351544B2

公开(公告)日：2019-07-16

申请号：US15579257

申请日：2016-06-06

Applicant: Synvina C.V.

Inventor： Ana Rita Martins Guerreiro Rocha Almeida ,  Martinus Mathilda Pieter Zieverink ,  Ana Sofia Vagueiro De Sousa Dias

IPC: B01J23/34 ,  B01J23/75 ,  B01J27/08 ,  C07B31/00 ,  C07B33/00 ,  C07B41/02 ,  C07B63/02 ,  C07D307/68

Abstract: A purified acid composition including 2,5-furandicarboxylic acid is prepared by a process including a) providing an acid composition solution of a crude acid composition in a polar solvent, the crude acid composition including 2,5-furandicarboxylic acid (FDCA) and 2-formyl-furan-5-carboxylic acid (FFCA); b) contacting the acid composition solution with hydrogen in the presence of a hydrogenation catalyst to hydrogenate FFCA to hydrogenation products, such that the hydrogenation products contain a minor amount of 2-methyl-furan-5-carboxylic acid (MFA) or no MFA, yielding a hydrogenated solution; c) separating at least a portion of the FDCA from the hydrogenated solution by crystallization.

公开(公告)号：US20180258558A1

公开(公告)日：2018-09-13

申请号：US15757556

申请日：2016-09-07

Applicant: BRIDGESTONE CORPORATION ,  SYNVINA C.V.

Inventor： Yuji IKEDA ,  Kenichi SUGIMOTO ,  Hajime NAKAJIMA

IPC: D01F6/62 ,  D01D5/08 ,  D02G3/48 ,  D02J1/22 ,  B60C9/00

CPC classification number: D01F6/62 ,  B60C9/0042 ,  D01D5/08 ,  D01D5/098 ,  D02G3/48 ,  D02J1/225 ,  D07B2201/2009 ,  D10B2331/042 ,  D10B2401/063 ,  D10B2505/02

Abstract: Disclosed is a method for producing a polyethylene-2,5-furandicarboxylate (PEF) raw yarn including a spinning/drawing process wherein an undrawn yarn, obtained by melt-spinning of a PEF-containing resin composition, is continuously drawn into a PEF raw yarn without being recovered and the PEF raw yarn is taken up, wherein the ratio of a rate (T) of taking up the PEF raw yarn to a rate (E) of extrusion of the resin composition into filaments during the melt-spinning (T/E) is 700 to 2,000.

公开(公告)号：US10053442B2

公开(公告)日：2018-08-21

申请号：US15525424

申请日：2015-11-10

Applicant: Synvina C.V.

Inventor： Ana Sofia Vagueiro De Sousa Dias ,  Benjamin McKay ,  Victor Peter Charles Vreeken ,  Johannes Maria Franciscus Sijben

IPC: C07D307/02 ,  C07D307/68

CPC classification number: C07D307/68

Abstract: Dialkyl esters of 2,5-furandicarboxylic acid are prepared from a 2,5-furandicarboxylic acid-containing starting material in a process, which includes: contacting a vaporous stream of an alkanol countercurrently with the at least partially liquid starting material having the 2,5-furandicarboxylic acid, in a reaction zone to conduct an esterification reaction to yield the dialkyl ester of 2,5-furandicarboxylic acid and water; withdrawing a reaction vapor comprising the alkanol and water from the reaction zone; and discharging a liquid phase having at least the dialkyl ester of 2,5-furandicarboxylic acid, from the bottom part of the reaction zone, to obtain the dialkyl ester of 2,5-furandicarboxylic acid.

公开(公告)号：US20180170890A1

公开(公告)日：2018-06-21

申请号：US15736033

申请日：2016-07-01

Applicant: Synvina C.V.

Inventor： Johannes Maria Franciscus Sijben ,  Etienne Mazoyer ,  Ana Sofia Vagueiro De Sousa Dias ,  Gerardus Johannes Maria Gruter

IPC: C07D307/50

CPC classification number: C07D307/50

Abstract: A furfural derivative having the chemical formula (1) wherein R represents hydrogen, an alkyl group or an acyl group, is prepared in a process, which process includes reacting a fructose- and/or glucose-containing starting material with a liquid hydroxyl group-containing compound of formula R—OH in the presence of an acid catalyst at a reaction temperature in the range of 150 to 300° C. to produce an acid reaction mixture including the furfural derivative of chemical formula (1), which acid reaction mixture has a pH-value of smaller than 3; neutralizing the acid reaction mixture to a pH-value in the range of 3 to 6.5 to provide a partially neutralized reaction mixture; and purifying the partially neutralized reaction mixture to recover the furfural derivative of chemical formula (1).

公开(公告)号：US20180142362A1

公开(公告)日：2018-05-24

申请号：US15575783

申请日：2016-05-20

Applicant: Avantium Knowledge Centre B.V. ,  Synvina C.V.

Inventor： Klaas Jan Pieter Schouten ,  Jan Cornelis Van Der Waal ,  Maria Varini ,  Gerardus Johannes Maria Gruter

IPC: C25B3/02 ,  C25B11/12 ,  C25B11/04

Abstract: An aromatic dicarboxylic acid of chemical formula HOOC—Ar1—COOH is prepared in a process wherein a feedstock comprising at least an aromatic aldehyde compound of chemical formula (1): OHC—Ar1—COOH, wherein Ar1 represents an arylene or heteroarylene moiety, and an aqueous electrolyte are provided; the feedstock and the aqueous electrolyte are introduced into an electrolytic cell comprising electrodes, wherein at least one of the electrodes comprises a non-noble metal and/or an oxide and/or a hydroxide thereof and/or carbon; and the aromatic aldehyde compound of formula (1) is oxidized electrochemically to yield the aromatic dicarboxylic acid.

公开(公告)号：US20180142313A1

公开(公告)日：2018-05-24

申请号：US15570429

申请日：2016-05-27

Applicant: Synvina C.V.

Inventor： Benjamin McKay ,  Gerardus Johannes Maria Gruter ,  Ilona Van Zandvoort

IPC: C13K11/00 ,  C13K3/00 ,  C07D307/20 ,  B01D11/02

CPC classification number: C13K11/00 ,  B01D11/02 ,  C07D307/20 ,  C13K3/00

Abstract: A fructose-rich solution is prepared from a solid composition including fructose and glucose, in a process including i) admixing the solid composition including fructose and glucose with a selective solvent that consist for at least 80% wt of methanol to obtain a slurry of glucose-rich solids in a methanolic fructose-rich solution; and ii) separating the methanolic fructose-rich solution from the glucose-rich solids.

公开(公告)号：US20170313670A1

公开(公告)日：2017-11-02

申请号：US15525424

申请日：2015-11-10

Applicant: Synvina C.V.

Inventor： Ana Sofia Vagueiro De Sousa Dias ,  Benjamin McKay ,  Victor Peter Charles Vreeken ,  Johannes Maria Franciscus Sijben

IPC: C07D307/68

CPC classification number: C07D307/68

Abstract: Dialkyl esters of 2,5-furandicarboxylic acid are prepared from a 2,5-furandicarboxylic acid-containing starting material in a process, which includes: contacting a vaporous stream of an alkanol countercurrently with the at least partially liquid starting material having the 2,5-furandicarboxylic acid, in a reaction zone to conduct an esterification reaction to yield the dialkyl ester of 2,5-furandicarboxylic acid and water; withdrawing a reaction vapor comprising the alkanol and water from the reaction zone; and discharging a liquid phase having at least the dialkyl ester of 2,5-furandicarboxylic acid, from the bottom part of the reaction zone, to obtain the dialkyl ester of 2,5-furandicarboxylic acid.

公开(公告)号：US20170297256A1

公开(公告)日：2017-10-19

申请号：US15505664

申请日：2015-08-25

Applicant: Synvina C.V.

Inventor： Jeffrey John Kolstad ,  Jesper Gabriël Van Berkel

IPC: B29C55/04 ,  C08J5/18 ,  B32B27/32 ,  B29C55/00 ,  B29K67/00

CPC classification number: B29C55/04 ,  B29C55/005 ,  B29K2067/00 ,  B29K2995/0053 ,  B29K2995/0077 ,  B32B27/32 ,  B32B27/36 ,  B32B2309/105 ,  B32B2439/70 ,  C08J5/18 ,  C08J2300/00 ,  C08J2367/02

Abstract: An oriented film including poly(ethylene-2,5-furandicarboxylate) is produced in a process by preparing a sheet from a poly(ethylene-2,5-furandicarboxylate) resin by heat processing, which sheet has a thickness of at most 2.5 mm; allowing the sheet to cool; and stretching the cooled sheet in at least one direction with a stretch ratio of at least 4/1 at a temperature in the range of 90 to 130° C., yielding an oriented film. The oriented film has a thickness of 1 to 400 μm and a tensile strength at break of at least 100 MPa.

公开(公告)号：US11305910B2

公开(公告)日：2022-04-19

申请号：US16807711

申请日：2020-03-03

Applicant: Synvina C.V.

Inventor： Jesper Gabriël van Berkel ,  Jeffrey John Kolstad

IPC: B65D1/02 ,  B32B1/02 ,  B32B27/26 ,  B29C49/00 ,  B29C49/08 ,  C08J5/00 ,  B32B27/36 ,  B29K67/00 ,  B29L31/00

Abstract: A container includes an outer layer defining an exterior surface and including poly (ethylene terephthalate) and an inner barrier layer including semi-crystalline poly(ethylene furanoate) including semi-crystalline poly(ethylene furanoate) where the poly(ethylene furanoate) has a crystallinity Xc of 3 to 40%.

公开(公告)号：US10974439B2

公开(公告)日：2021-04-13

申请号：US15505664

申请日：2015-08-25

Applicant: Synvina C.V.

Inventor： Jeffrey John Kolstad ,  Jesper Gabriël Van Berkel

IPC: B29C55/12 ,  B32B27/32 ,  B29C55/00 ,  C08J5/18 ,  B32B27/36 ,  B29C55/04 ,  B29K67/00

Abstract: An oriented film including poly(ethylene-2,5-furandicarboxylate) is produced in a process by preparing a sheet from a poly(ethylene-2,5-furandicarboxylate) resin by heat processing, which sheet has a thickness of at most 2.5 mm; allowing the sheet to cool; and stretching the cooled sheet in at least one direction with a stretch ratio of at least 4/1 at a temperature in the range of 90 to 130° C., yielding an oriented film. The oriented film has a thickness of 1 to 400 μm and a tensile strength at break of at least 100 MPa.